Design of Leaving Groups in Radical CC Fragmentations: Through-Bond 2c-3e Interactions in Self-Terminating Radical Cascades

Radical cascades terminated by β‐scission of exocyclic CC bonds allow for the formation of aromatic products. Whereas β‐scission is common for weaker bonds, achieving this reactivity for carbon–carbon bonds requires careful design of radical leaving groups. It has now been found that the energetic...

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Veröffentlicht in:	Chemistry : a European journal 2014-07, Vol.20 (28), p.8664-8669
Hauptverfasser:	Mondal, Sayantan, Gold, Brian, Mohamed, Rana K., Alabugin, Igor V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Aromaticity Breaking Cascades cyclization domino reactions Equivalence Fragmentation Gain radical reactions Radicals through-bond interactions
Online-Zugang:	Volltext
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