Rhodium(III)-Catalyzed Selective ortho-Olefinations of N-Acyl and N-Aroyl Sulfoximines by CH Bond Activation

Two new rhodium‐catalyzed oxidative couplings between sulfoximine derivatives and alkenes by regioselective CH activation, affording ortho‐olefinated (Heck‐type) products, are reported. A synthetic application of the ortho‐alkenylated products into the corresponding cyclic derivatives has been demo...

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Veröffentlicht in:	Chemistry : a European journal 2014-04, Vol.20 (17), p.4896-4900
Hauptverfasser:	Parthasarathy, Kanniyappan, Bolm, Carsten
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Alkenes Aromatic compounds Bonding Catalysis Couplings CH bond activation Derivatives olefination ortho-alkenylation Rhodium rhodium catalysis
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