Synthesis and Reactivity of New Functionalized Perfluoroalkylfluorophosphates

A new efficient synthesis of functionalized perfluoroalkyl fluorophosphates by oxidative addition of Me2NCH2F to the electron‐deficient phosphanes (C2F5)nPF3−n (n=0–3) is reported. The initially formed zwitterionic, hexacoordinated phosphates [(C2F5)nF5−nP(CH2NMe2−CH2NMe2)] are converted into the co...

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Veröffentlicht in:	Chemistry : a European journal 2014-06, Vol.20 (25), p.7736-7745
Hauptverfasser:	Allefeld, Nadine, Neumann, Beate, Stammler, Hans-Georg, Röschenthaler, Gerd-Volker, Ignat'ev, Nikolai, Hoge, Berthold
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylation Chemistry Diffraction Fluorides - analysis Fluorides - chemical synthesis fluorine Formations iminium Models, Molecular Nucleophiles oxidative addition Perfluoroalkyl & polyfluoroalkyl substances phosphate Phosphates Phosphates - analysis Phosphates - chemical synthesis phosphorus Salts Structural analysis Synthesis Terminals X-rays Zwitterions
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