Coordination Polymer Nanobamboos of {FexIn1−x}-MIL-88B: Induced Formation of a Virtual In-MIL-88B

A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {FexIn1−x}‐MIL‐88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {FexIn1−x}‐MIL‐88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used...

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Veröffentlicht in:Chemistry : a European journal 2014-05, Vol.20 (19), p.5559-5564
Hauptverfasser: Park, Shin Ae, Lee, Hee Jung, Cho, Yea Jin, Choi, Sora, Oh, Moonhyun
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container_issue 19
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Lee, Hee Jung
Cho, Yea Jin
Choi, Sora
Oh, Moonhyun
description A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {FexIn1−x}‐MIL‐88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {FexIn1−x}‐MIL‐88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In‐MIL‐88B (precise structure, {Fe0.06In0.94}‐MIL‐88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe‐MIL‐88B structure. The a and c cell parameters of {Fe0.06In0.94}‐MIL‐88B are calculated at 10.95 and 19.86 Å, respectively. These values of {Fe0.06In0.94}‐MIL‐88B are larger than those of pure Fe‐MIL‐88B owing to the large ionic size of In3+ within the framework. In bamboo: The preparation of nanobamboos of {FexIn1−x}‐MIL‐88B is demonstrated. The compositions of the nanobamboos are regulated by altering the amount of metal ions used during their preparation. In addition, the formation of a virtual In‐MIL‐88B, which is difficult to create in a typical reaction, is induced with the assistance of small amounts of Fe3+ ions.
doi_str_mv 10.1002/chem.201304515
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The compositions of the hybrid coordination polymer nanobamboos of {FexIn1−x}‐MIL‐88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In‐MIL‐88B (precise structure, {Fe0.06In0.94}‐MIL‐88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe‐MIL‐88B structure. The a and c cell parameters of {Fe0.06In0.94}‐MIL‐88B are calculated at 10.95 and 19.86 Å, respectively. These values of {Fe0.06In0.94}‐MIL‐88B are larger than those of pure Fe‐MIL‐88B owing to the large ionic size of In3+ within the framework. In bamboo: The preparation of nanobamboos of {FexIn1−x}‐MIL‐88B is demonstrated. The compositions of the nanobamboos are regulated by altering the amount of metal ions used during their preparation. 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Eur. J</addtitle><description>A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {FexIn1−x}‐MIL‐88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {FexIn1−x}‐MIL‐88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In‐MIL‐88B (precise structure, {Fe0.06In0.94}‐MIL‐88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe‐MIL‐88B structure. The a and c cell parameters of {Fe0.06In0.94}‐MIL‐88B are calculated at 10.95 and 19.86 Å, respectively. These values of {Fe0.06In0.94}‐MIL‐88B are larger than those of pure Fe‐MIL‐88B owing to the large ionic size of In3+ within the framework. In bamboo: The preparation of nanobamboos of {FexIn1−x}‐MIL‐88B is demonstrated. The compositions of the nanobamboos are regulated by altering the amount of metal ions used during their preparation. 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Eur. J</addtitle><date>2014-05-05</date><risdate>2014</risdate><volume>20</volume><issue>19</issue><spage>5559</spage><epage>5564</epage><pages>5559-5564</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {FexIn1−x}‐MIL‐88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {FexIn1−x}‐MIL‐88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In‐MIL‐88B (precise structure, {Fe0.06In0.94}‐MIL‐88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe‐MIL‐88B structure. The a and c cell parameters of {Fe0.06In0.94}‐MIL‐88B are calculated at 10.95 and 19.86 Å, respectively. These values of {Fe0.06In0.94}‐MIL‐88B are larger than those of pure Fe‐MIL‐88B owing to the large ionic size of In3+ within the framework. In bamboo: The preparation of nanobamboos of {FexIn1−x}‐MIL‐88B is demonstrated. The compositions of the nanobamboos are regulated by altering the amount of metal ions used during their preparation. In addition, the formation of a virtual In‐MIL‐88B, which is difficult to create in a typical reaction, is induced with the assistance of small amounts of Fe3+ ions.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>24700481</pmid><doi>10.1002/chem.201304515</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record>
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subjects Bamboo
Chemistry
coordination polymer particles
Coordination polymers
Formations
hybrid nanostructures
Mathematical analysis
Metal ions
metal-organic frameworks
MIL-88B
nanobamboos
Nanostructure
title Coordination Polymer Nanobamboos of {FexIn1−x}-MIL-88B: Induced Formation of a Virtual In-MIL-88B
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