Oligomerization of 1-decene under the action of catalytic systems based on Al-aluminum activator-RCl and Al-RCl
Novel catalytic systems for the cationic oligomerization of 1-decene into synthetic poly(α-olefin) oils have been worked out; these systems include a highly disperse (0.1–40 μm) aluminum, an aluminum activator [I 2 , Mg, (C 2 H 5 ) n AlCl 3 − n , (CH 3 ) 3 CCl and some other RX, HCl, benzene, and to...
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| Veröffentlicht in: | Polymer science. Series A, Chemistry, physics Chemistry, physics, 2008-11, Vol.50 (11), p.1175-1186 |
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| container_issue | 11 |
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| container_title | Polymer science. Series A, Chemistry, physics |
| container_volume | 50 |
| creator | Matkovskii, P. E. Startseva, G. P. Churkina, V. Ya Knerel’man, E. I. Davydova, G. I. Vasil’eva, L. P. Yarullin, R. S. |
| description | Novel catalytic systems for the cationic oligomerization of 1-decene into synthetic poly(α-olefin) oils have been worked out; these systems include a highly disperse (0.1–40 μm) aluminum, an aluminum activator [I
2
, Mg, (C
2
H
5
)
n
AlCl
3 −
n
, (CH
3
)
3
CCl and some other RX, HCl, benzene, and toluene], and a cocatalyst based on organic halide compounds RX (R is primary, secondary, or tertiary alkyl, allyl, or benzyl; X is Cl, Br, or I). We study the effect of various factors (characteristics of Al, nature of aluminum activator, RCl: Al molar ratio in the catalyst, concentration of Al, temperature, benzene additives, reaction duration) on the conversion of 1-decene into poly(α-olefins), the fractional composition of oligomerization products, the content of chlorine in poly(α-olefins), and the structure and physicochemical characteristics of fractions. |
| doi_str_mv | 10.1134/S0965545X08110072 |
| format | Article |
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2
, Mg, (C
2
H
5
)
n
AlCl
3 −
n
, (CH
3
)
3
CCl and some other RX, HCl, benzene, and toluene], and a cocatalyst based on organic halide compounds RX (R is primary, secondary, or tertiary alkyl, allyl, or benzyl; X is Cl, Br, or I). We study the effect of various factors (characteristics of Al, nature of aluminum activator, RCl: Al molar ratio in the catalyst, concentration of Al, temperature, benzene additives, reaction duration) on the conversion of 1-decene into poly(α-olefins), the fractional composition of oligomerization products, the content of chlorine in poly(α-olefins), and the structure and physicochemical characteristics of fractions.</description><identifier>ISSN: 0965-545X</identifier><identifier>EISSN: 1555-6107</identifier><identifier>DOI: 10.1134/S0965545X08110072</identifier><language>eng</language><publisher>Moscow: Nauka/Interperiodica</publisher><subject>Aluminum ; Benzene ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Composition effects ; Concentration (composition) ; Conversion ; Oligomerization ; Polymer Sciences ; Toluene</subject><ispartof>Polymer science. Series A, Chemistry, physics, 2008-11, Vol.50 (11), p.1175-1186</ispartof><rights>Pleiades Publishing, Ltd. 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-2eac70d13b3d515fbc36388ce5ce78820bdff2acec2cdcb53f5e091bf866b8353</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0965545X08110072$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0965545X08110072$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Matkovskii, P. E.</creatorcontrib><creatorcontrib>Startseva, G. P.</creatorcontrib><creatorcontrib>Churkina, V. Ya</creatorcontrib><creatorcontrib>Knerel’man, E. I.</creatorcontrib><creatorcontrib>Davydova, G. I.</creatorcontrib><creatorcontrib>Vasil’eva, L. P.</creatorcontrib><creatorcontrib>Yarullin, R. S.</creatorcontrib><title>Oligomerization of 1-decene under the action of catalytic systems based on Al-aluminum activator-RCl and Al-RCl</title><title>Polymer science. Series A, Chemistry, physics</title><addtitle>Polym. Sci. Ser. A</addtitle><description>Novel catalytic systems for the cationic oligomerization of 1-decene into synthetic poly(α-olefin) oils have been worked out; these systems include a highly disperse (0.1–40 μm) aluminum, an aluminum activator [I
2
, Mg, (C
2
H
5
)
n
AlCl
3 −
n
, (CH
3
)
3
CCl and some other RX, HCl, benzene, and toluene], and a cocatalyst based on organic halide compounds RX (R is primary, secondary, or tertiary alkyl, allyl, or benzyl; X is Cl, Br, or I). We study the effect of various factors (characteristics of Al, nature of aluminum activator, RCl: Al molar ratio in the catalyst, concentration of Al, temperature, benzene additives, reaction duration) on the conversion of 1-decene into poly(α-olefins), the fractional composition of oligomerization products, the content of chlorine in poly(α-olefins), and the structure and physicochemical characteristics of fractions.</description><subject>Aluminum</subject><subject>Benzene</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composition effects</subject><subject>Concentration (composition)</subject><subject>Conversion</subject><subject>Oligomerization</subject><subject>Polymer Sciences</subject><subject>Toluene</subject><issn>0965-545X</issn><issn>1555-6107</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkU1LxDAQhoMouOj-AG85eqlmmqZJj8viFyws-AHeSpJO10qbrEkrrL_e1tWToKcZeJ53YHgJOQN2AcCzywdW5EJk4pkpAMZkekBmIIRIcmDykMwmnEz8mMxjbAwDyNkoZDPi122z8R2G5kP3jXfU1xSSCi06pIOrMND-Bam2P9DqXre7vrE07mKPXaRGR6zoSBdtotuha9zQfQXede9Dcr9sqXbVRMf1lBzVuo04_54n5On66nF5m6zWN3fLxSqxXOV9kqK2klXADa8EiNpYnnOlLAqLUqmUmaquU23RprayRvBaICvA1CrPjeKCn5Dz_d1t8G8Dxr7smmixbbVDP8QSpJRFoUDy_9WsyHgqBJtU2Ks2-BgD1uU2NJ0OuxJYOVVR_qpizKT7TBxdt8FQvvohuPH5P0KftJmLwg</recordid><startdate>20081101</startdate><enddate>20081101</enddate><creator>Matkovskii, P. E.</creator><creator>Startseva, G. P.</creator><creator>Churkina, V. Ya</creator><creator>Knerel’man, E. I.</creator><creator>Davydova, G. I.</creator><creator>Vasil’eva, L. P.</creator><creator>Yarullin, R. S.</creator><general>Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20081101</creationdate><title>Oligomerization of 1-decene under the action of catalytic systems based on Al-aluminum activator-RCl and Al-RCl</title><author>Matkovskii, P. E. ; Startseva, G. P. ; Churkina, V. Ya ; Knerel’man, E. I. ; Davydova, G. I. ; Vasil’eva, L. P. ; Yarullin, R. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-2eac70d13b3d515fbc36388ce5ce78820bdff2acec2cdcb53f5e091bf866b8353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Aluminum</topic><topic>Benzene</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composition effects</topic><topic>Concentration (composition)</topic><topic>Conversion</topic><topic>Oligomerization</topic><topic>Polymer Sciences</topic><topic>Toluene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matkovskii, P. E.</creatorcontrib><creatorcontrib>Startseva, G. P.</creatorcontrib><creatorcontrib>Churkina, V. Ya</creatorcontrib><creatorcontrib>Knerel’man, E. I.</creatorcontrib><creatorcontrib>Davydova, G. I.</creatorcontrib><creatorcontrib>Vasil’eva, L. P.</creatorcontrib><creatorcontrib>Yarullin, R. S.</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer science. Series A, Chemistry, physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matkovskii, P. E.</au><au>Startseva, G. P.</au><au>Churkina, V. Ya</au><au>Knerel’man, E. I.</au><au>Davydova, G. I.</au><au>Vasil’eva, L. P.</au><au>Yarullin, R. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oligomerization of 1-decene under the action of catalytic systems based on Al-aluminum activator-RCl and Al-RCl</atitle><jtitle>Polymer science. Series A, Chemistry, physics</jtitle><stitle>Polym. Sci. Ser. A</stitle><date>2008-11-01</date><risdate>2008</risdate><volume>50</volume><issue>11</issue><spage>1175</spage><epage>1186</epage><pages>1175-1186</pages><issn>0965-545X</issn><eissn>1555-6107</eissn><abstract>Novel catalytic systems for the cationic oligomerization of 1-decene into synthetic poly(α-olefin) oils have been worked out; these systems include a highly disperse (0.1–40 μm) aluminum, an aluminum activator [I
2
, Mg, (C
2
H
5
)
n
AlCl
3 −
n
, (CH
3
)
3
CCl and some other RX, HCl, benzene, and toluene], and a cocatalyst based on organic halide compounds RX (R is primary, secondary, or tertiary alkyl, allyl, or benzyl; X is Cl, Br, or I). We study the effect of various factors (characteristics of Al, nature of aluminum activator, RCl: Al molar ratio in the catalyst, concentration of Al, temperature, benzene additives, reaction duration) on the conversion of 1-decene into poly(α-olefins), the fractional composition of oligomerization products, the content of chlorine in poly(α-olefins), and the structure and physicochemical characteristics of fractions.</abstract><cop>Moscow</cop><pub>Nauka/Interperiodica</pub><doi>10.1134/S0965545X08110072</doi><tpages>12</tpages></addata></record> |
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| identifier | ISSN: 0965-545X |
| ispartof | Polymer science. Series A, Chemistry, physics, 2008-11, Vol.50 (11), p.1175-1186 |
| issn | 0965-545X 1555-6107 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Aluminum Benzene Catalysis Catalysts Chemistry Chemistry and Materials Science Composition effects Concentration (composition) Conversion Oligomerization Polymer Sciences Toluene |
| title | Oligomerization of 1-decene under the action of catalytic systems based on Al-aluminum activator-RCl and Al-RCl |
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