Hydrogenation of Aldehydes Catalyzed by an Available Ruthenium Complex
A readily available ruthenium(II) catalyst was developed for the catalytic hydrogenation of aldehydes with a TON (turnover number) up to 340000. It can be performed without base and solvent, showing highly industrial potential. High chemoselectivity can be achieved in the presence of alkenyl and ke...
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| Veröffentlicht in: | Organic letters 2016-04, Vol.18 (7), p.1518-1521 |
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| container_title | Organic letters |
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| creator | Tan, Xuefeng Wang, Guozhen Zhu, Ziyue Ren, Conghui Zhou, Jinping Lv, Hui Zhang, Xiaoyong Chung, Lung Wa Zhang, Lina Zhang, Xumu |
| description | A readily available ruthenium(II) catalyst was developed for the catalytic hydrogenation of aldehydes with a TON (turnover number) up to 340000. It can be performed without base and solvent, showing highly industrial potential. High chemoselectivity can be achieved in the presence of alkenyl and ketone groups. Further application of this protocol in glucose reduction showed good efficiency. Theoretical studies revealed that the rate-determining step is the hydrogenation step, not the carboxylate-assisted H2 activation step. |
| doi_str_mv | 10.1021/acs.orglett.6b00060 |
| format | Article |
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It can be performed without base and solvent, showing highly industrial potential. High chemoselectivity can be achieved in the presence of alkenyl and ketone groups. Further application of this protocol in glucose reduction showed good efficiency. Theoretical studies revealed that the rate-determining step is the hydrogenation step, not the carboxylate-assisted H2 activation step.</description><identifier>ISSN: 1523-7060</identifier><identifier>EISSN: 1523-7052</identifier><identifier>DOI: 10.1021/acs.orglett.6b00060</identifier><identifier>PMID: 26974348</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Organic letters, 2016-04, Vol.18 (7), p.1518-1521</ispartof><rights>Copyright © 2016 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a345t-6a3e6095545a303e84c62d0542d99852af66042957428eb41ba705c45c9026ae3</citedby><cites>FETCH-LOGICAL-a345t-6a3e6095545a303e84c62d0542d99852af66042957428eb41ba705c45c9026ae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.orglett.6b00060$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.orglett.6b00060$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27074,27922,27923,56736,56786</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26974348$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tan, Xuefeng</creatorcontrib><creatorcontrib>Wang, Guozhen</creatorcontrib><creatorcontrib>Zhu, Ziyue</creatorcontrib><creatorcontrib>Ren, Conghui</creatorcontrib><creatorcontrib>Zhou, Jinping</creatorcontrib><creatorcontrib>Lv, Hui</creatorcontrib><creatorcontrib>Zhang, Xiaoyong</creatorcontrib><creatorcontrib>Chung, Lung Wa</creatorcontrib><creatorcontrib>Zhang, Lina</creatorcontrib><creatorcontrib>Zhang, Xumu</creatorcontrib><title>Hydrogenation of Aldehydes Catalyzed by an Available Ruthenium Complex</title><title>Organic letters</title><addtitle>Org. 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| source | ACS Publications |
| title | Hydrogenation of Aldehydes Catalyzed by an Available Ruthenium Complex |
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