VOCl as a Cathode for Rechargeable Chloride Ion Batteries
A novel room temperature rechargeable battery with VOCl cathode, lithium anode, and chloride ion transporting liquid electrolyte is described. The cell is based on the reversible transfer of chloride ions between the two electrodes. The VOCl cathode delivered an initial discharge capacity of 189 mAh...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2016-03, Vol.55 (13), p.4285-4290 |
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| creator | Gao, Ping Reddy, M. Anji Mu, Xiaoke Diemant, Thomas Zhang, Le Zhao-Karger, Zhirong Chakravadhanula, Venkata Sai Kiran Clemens, Oliver Behm, R. Jürgen Fichtner, Maximilian |
| description | A novel room temperature rechargeable battery with VOCl cathode, lithium anode, and chloride ion transporting liquid electrolyte is described. The cell is based on the reversible transfer of chloride ions between the two electrodes. The VOCl cathode delivered an initial discharge capacity of 189 mAh g−1. A reversible capacity of 113 mAh g−1 was retained even after 100 cycles when cycled at a high current density of 522 mA g−1. Such high cycling stability was achieved in chloride ion batteries for the first time, demonstrating the practicality of the system beyond a proof of concept model. The electrochemical reaction mechanism of the VOCl electrode in the chloride ion cell was investigated in detail by ex situ X‐ray diffraction (XRD), infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and X‐ray photoelectron spectroscopy (XPS). The results confirm reversible deintercalation–intercalation of chloride ions in the VOCl electrode.
Chloride shuttle: A rechargeable chloride ion battery is based on the reversible transfer of chloride ions between a VOCl cathode and lithium anode. A reversible capacity of 113 mAh g−1 can be retained after 100 cycles even at a high current density rating of 2 C. Key: •(green) Cl−, ▪(blue) MClx (cathode), ▪(green) M′ (anode), →(red) discharging, ←green charging. |
| doi_str_mv | 10.1002/anie.201509564 |
| format | Article |
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Chloride shuttle: A rechargeable chloride ion battery is based on the reversible transfer of chloride ions between a VOCl cathode and lithium anode. A reversible capacity of 113 mAh g−1 can be retained after 100 cycles even at a high current density rating of 2 C. Key: •(green) Cl−, ▪(blue) MClx (cathode), ▪(green) M′ (anode), →(red) discharging, ←green charging.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201509564</identifier><identifier>PMID: 26924132</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Batteries ; Cathodes ; Chloride ; chloride ion batteries ; Chloride ions ; Chlorides ; Discharge capacity ; Electrochemistry ; Electrodes ; Fourier transforms ; Infrared spectroscopy ; Lithium ; Photoelectron spectroscopy ; Reaction mechanisms ; Rechargeable batteries ; Spectroscopy ; Spectrum analysis ; Transmission electron microscopy ; vanadium oxychloride ; X-ray diffraction ; X-rays</subject><ispartof>Angewandte Chemie International Edition, 2016-03, Vol.55 (13), p.4285-4290</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c6124-96d19c011cafe5f95caa82cef34e8deac7483622f9a349ff06bff6e5d44b636d3</citedby><cites>FETCH-LOGICAL-c6124-96d19c011cafe5f95caa82cef34e8deac7483622f9a349ff06bff6e5d44b636d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201509564$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201509564$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26924132$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gao, Ping</creatorcontrib><creatorcontrib>Reddy, M. Anji</creatorcontrib><creatorcontrib>Mu, Xiaoke</creatorcontrib><creatorcontrib>Diemant, Thomas</creatorcontrib><creatorcontrib>Zhang, Le</creatorcontrib><creatorcontrib>Zhao-Karger, Zhirong</creatorcontrib><creatorcontrib>Chakravadhanula, Venkata Sai Kiran</creatorcontrib><creatorcontrib>Clemens, Oliver</creatorcontrib><creatorcontrib>Behm, R. Jürgen</creatorcontrib><creatorcontrib>Fichtner, Maximilian</creatorcontrib><title>VOCl as a Cathode for Rechargeable Chloride Ion Batteries</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>A novel room temperature rechargeable battery with VOCl cathode, lithium anode, and chloride ion transporting liquid electrolyte is described. The cell is based on the reversible transfer of chloride ions between the two electrodes. The VOCl cathode delivered an initial discharge capacity of 189 mAh g−1. A reversible capacity of 113 mAh g−1 was retained even after 100 cycles when cycled at a high current density of 522 mA g−1. Such high cycling stability was achieved in chloride ion batteries for the first time, demonstrating the practicality of the system beyond a proof of concept model. The electrochemical reaction mechanism of the VOCl electrode in the chloride ion cell was investigated in detail by ex situ X‐ray diffraction (XRD), infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and X‐ray photoelectron spectroscopy (XPS). The results confirm reversible deintercalation–intercalation of chloride ions in the VOCl electrode.
Chloride shuttle: A rechargeable chloride ion battery is based on the reversible transfer of chloride ions between a VOCl cathode and lithium anode. A reversible capacity of 113 mAh g−1 can be retained after 100 cycles even at a high current density rating of 2 C. Key: •(green) Cl−, ▪(blue) MClx (cathode), ▪(green) M′ (anode), →(red) discharging, ←green charging.</description><subject>Batteries</subject><subject>Cathodes</subject><subject>Chloride</subject><subject>chloride ion batteries</subject><subject>Chloride ions</subject><subject>Chlorides</subject><subject>Discharge capacity</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Fourier transforms</subject><subject>Infrared spectroscopy</subject><subject>Lithium</subject><subject>Photoelectron spectroscopy</subject><subject>Reaction mechanisms</subject><subject>Rechargeable batteries</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Transmission electron microscopy</subject><subject>vanadium oxychloride</subject><subject>X-ray diffraction</subject><subject>X-rays</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEURoMovrcuZcCNm6l5Z7LU8VUQxfcypJkbOzrtaDJF--9NqRZxoat74Z7vcPkQ2iG4RzCmB3ZcQ49iIrAWki-hdSIoyZlSbDntnLFcFYKsoY0YnxNfFFiuojUqNeWE0XWkH67KJrMxs1lpu2FbQebbkN2AG9rwBHbQQFYOmzbU6dJvx9mR7ToINcQttOJtE2H7a26i-9OTu_I8v7g665eHF7mThPJcy4pohwlx1oPwWjhrC-rAMw5FBdYpXjBJqdeWce09lgPvJYiK84FksmKbaH_ufQ3t2wRiZ0Z1dNA0dgztJBqilGAFw1gldO8X-txOwjh9ZygWClPBFP6LSi4uFWeYJKo3p1xoYwzgzWuoRzZMDcFmVr2ZVW8W1afA7pd2MhhBtcC_u06AngPvdQPTf3Tm8LJ_8lOez7N17OBjkbXhxUjFlDCPl2fm8VZfn1JxbCT7BGOfm-Y</recordid><startdate>20160318</startdate><enddate>20160318</enddate><creator>Gao, Ping</creator><creator>Reddy, M. Anji</creator><creator>Mu, Xiaoke</creator><creator>Diemant, Thomas</creator><creator>Zhang, Le</creator><creator>Zhao-Karger, Zhirong</creator><creator>Chakravadhanula, Venkata Sai Kiran</creator><creator>Clemens, Oliver</creator><creator>Behm, R. Jürgen</creator><creator>Fichtner, Maximilian</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20160318</creationdate><title>VOCl as a Cathode for Rechargeable Chloride Ion Batteries</title><author>Gao, Ping ; Reddy, M. Anji ; Mu, Xiaoke ; Diemant, Thomas ; Zhang, Le ; Zhao-Karger, Zhirong ; Chakravadhanula, Venkata Sai Kiran ; Clemens, Oliver ; Behm, R. Jürgen ; Fichtner, Maximilian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c6124-96d19c011cafe5f95caa82cef34e8deac7483622f9a349ff06bff6e5d44b636d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Batteries</topic><topic>Cathodes</topic><topic>Chloride</topic><topic>chloride ion batteries</topic><topic>Chloride ions</topic><topic>Chlorides</topic><topic>Discharge capacity</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Fourier transforms</topic><topic>Infrared spectroscopy</topic><topic>Lithium</topic><topic>Photoelectron spectroscopy</topic><topic>Reaction mechanisms</topic><topic>Rechargeable batteries</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><topic>Transmission electron microscopy</topic><topic>vanadium oxychloride</topic><topic>X-ray diffraction</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gao, Ping</creatorcontrib><creatorcontrib>Reddy, M. Anji</creatorcontrib><creatorcontrib>Mu, Xiaoke</creatorcontrib><creatorcontrib>Diemant, Thomas</creatorcontrib><creatorcontrib>Zhang, Le</creatorcontrib><creatorcontrib>Zhao-Karger, Zhirong</creatorcontrib><creatorcontrib>Chakravadhanula, Venkata Sai Kiran</creatorcontrib><creatorcontrib>Clemens, Oliver</creatorcontrib><creatorcontrib>Behm, R. Jürgen</creatorcontrib><creatorcontrib>Fichtner, Maximilian</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gao, Ping</au><au>Reddy, M. Anji</au><au>Mu, Xiaoke</au><au>Diemant, Thomas</au><au>Zhang, Le</au><au>Zhao-Karger, Zhirong</au><au>Chakravadhanula, Venkata Sai Kiran</au><au>Clemens, Oliver</au><au>Behm, R. Jürgen</au><au>Fichtner, Maximilian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>VOCl as a Cathode for Rechargeable Chloride Ion Batteries</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2016-03-18</date><risdate>2016</risdate><volume>55</volume><issue>13</issue><spage>4285</spage><epage>4290</epage><pages>4285-4290</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>A novel room temperature rechargeable battery with VOCl cathode, lithium anode, and chloride ion transporting liquid electrolyte is described. The cell is based on the reversible transfer of chloride ions between the two electrodes. The VOCl cathode delivered an initial discharge capacity of 189 mAh g−1. A reversible capacity of 113 mAh g−1 was retained even after 100 cycles when cycled at a high current density of 522 mA g−1. Such high cycling stability was achieved in chloride ion batteries for the first time, demonstrating the practicality of the system beyond a proof of concept model. The electrochemical reaction mechanism of the VOCl electrode in the chloride ion cell was investigated in detail by ex situ X‐ray diffraction (XRD), infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and X‐ray photoelectron spectroscopy (XPS). The results confirm reversible deintercalation–intercalation of chloride ions in the VOCl electrode.
Chloride shuttle: A rechargeable chloride ion battery is based on the reversible transfer of chloride ions between a VOCl cathode and lithium anode. A reversible capacity of 113 mAh g−1 can be retained after 100 cycles even at a high current density rating of 2 C. Key: •(green) Cl−, ▪(blue) MClx (cathode), ▪(green) M′ (anode), →(red) discharging, ←green charging.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>26924132</pmid><doi>10.1002/anie.201509564</doi><tpages>6</tpages><edition>International ed. in English</edition><oa>free_for_read</oa></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Batteries Cathodes Chloride chloride ion batteries Chloride ions Chlorides Discharge capacity Electrochemistry Electrodes Fourier transforms Infrared spectroscopy Lithium Photoelectron spectroscopy Reaction mechanisms Rechargeable batteries Spectroscopy Spectrum analysis Transmission electron microscopy vanadium oxychloride X-ray diffraction X-rays |
| title | VOCl as a Cathode for Rechargeable Chloride Ion Batteries |
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