A Qualitative Analysis of a “Bora-Brook Rearrangement”: The Ambident Reactivity of Boryl-Substituted Alkoxide Including the Carbon-to-Oxygen Migration of a Boryl Group

A bora-Brook rearrangement, i.e., the migration of boryl group from a carbon to an oxygen atom in an isolated α-boryl-substituted alkoxide, was examined, and decisive factors for the acceleration of this reaction are disclosed. In this rearrangement, the boryl-substituted alkoxide exhibited ambiphil...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-03, Vol.138 (10), p.3548-3552
Hauptverfasser:	Kisu, Haruki, Sakaino, Hirotoshi, Ito, Fumihiro, Yamashita, Makoto, Nozaki, Kyoko
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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