Isotope Dependence and Quantum Effects on Atomic Hydrogen Diffusion in Liquid Water

Relative diffusion coefficients were determined in water for the D, H, and Mu isotopes of atomic hydrogen by measuring their diffusion-limited spin-exchange rate constants with Ni2+ as a function of temperature. H and D atoms were generated by pulse radiolysis of water and measured by time-resolved...

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Veröffentlicht in:	The journal of physical chemistry. B 2016-03, Vol.120 (8), p.1771-1779
Hauptverfasser:	Walker, J. A, Mezyk, S. P, Roduner, E, Bartels, D. M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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