Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal-organic framework containing tetrakis(carboxyphenyl)porphyrin groups

Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal-organic framework containing tetrakis(carboxyphenyl)porphyrin groups

A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this pro...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (89), p.16103-16106
Hauptverfasser: Toyao, Takashi, Ueno, Nana, Miyahara, Kenta, Matsui, Yasunori, Kim, Tae-Ho, Horiuchi, Yu, Ikeda, Hiroshi, Matsuoka, Masaya
Format: Artikel
Sprache:eng
Schlagworte:
Catalysts
Catalytic activity
Displays
Hydroxylation
Light irradiation
Light-emitting diodes
Metal-organic frameworks
Metalorganic compounds
Zirconium
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this process over the corresponding homogeneous catalyst (H4TCPP).
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc06163f