Intrinsically stretchable transparent electrodes based on silver-nanowire-crosslinked-polyacrylate composites
Stretchable transparent composites have been synthesized consisting of a silver nanowire (AgNW) network embedded in the surface layer of a crosslinked poly(acrylate) matrix. The interpenetrating networks of AgNWs and the crosslinked polymer matrix lead to high surface conductivity, high transparency...
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Veröffentlicht in: | Nanotechnology 2012-08, Vol.23 (34), p.344002-1-9 |
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container_issue | 34 |
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container_title | Nanotechnology |
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creator | Hu, Weili Niu, Xiaofan Li, Lu Yun, Sungryul Yu, Zhibin Pei, Qibing |
description | Stretchable transparent composites have been synthesized consisting of a silver nanowire (AgNW) network embedded in the surface layer of a crosslinked poly(acrylate) matrix. The interpenetrating networks of AgNWs and the crosslinked polymer matrix lead to high surface conductivity, high transparency, and rubbery elasticity. The presence of carboxylic acid groups on the polymer chains enhances the bonding between AgNWs and the polymer matrix, and further increases the stretchability of the composites. The sheet resistance of the composite electrode increases by only 2.3 times at 50% strain. Repeated stretching to 50% strain and relaxation only causes a small increase of the sheet resistance after 600 cycles. The morphology of the composites during reversible stretching and relaxation has been investigated to expound the conductivity changes. |
doi_str_mv | 10.1088/0957-4484/23/34/344002 |
format | Article |
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The interpenetrating networks of AgNWs and the crosslinked polymer matrix lead to high surface conductivity, high transparency, and rubbery elasticity. The presence of carboxylic acid groups on the polymer chains enhances the bonding between AgNWs and the polymer matrix, and further increases the stretchability of the composites. The sheet resistance of the composite electrode increases by only 2.3 times at 50% strain. Repeated stretching to 50% strain and relaxation only causes a small increase of the sheet resistance after 600 cycles. The morphology of the composites during reversible stretching and relaxation has been investigated to expound the conductivity changes.</description><identifier>ISSN: 0957-4484</identifier><identifier>EISSN: 1361-6528</identifier><identifier>DOI: 10.1088/0957-4484/23/34/344002</identifier><identifier>PMID: 22885805</identifier><identifier>CODEN: NNOTER</identifier><language>eng</language><publisher>England: IOP Publishing</publisher><subject>Crosslinking ; Electrical resistivity ; Electrodes ; Nanostructure ; Nanowires ; Networks ; Silver ; Strain ; Stretching</subject><ispartof>Nanotechnology, 2012-08, Vol.23 (34), p.344002-1-9</ispartof><rights>2012 IOP Publishing Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c486t-7ccde3d8daec051ca9656d73d1d4244fbc25cb5180614567a7e6f1813ec28ba93</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1088/0957-4484/23/34/344002/pdf$$EPDF$$P50$$Giop$$H</linktopdf><link.rule.ids>314,776,780,27903,27904,53824,53871</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22885805$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hu, Weili</creatorcontrib><creatorcontrib>Niu, Xiaofan</creatorcontrib><creatorcontrib>Li, Lu</creatorcontrib><creatorcontrib>Yun, Sungryul</creatorcontrib><creatorcontrib>Yu, Zhibin</creatorcontrib><creatorcontrib>Pei, Qibing</creatorcontrib><title>Intrinsically stretchable transparent electrodes based on silver-nanowire-crosslinked-polyacrylate composites</title><title>Nanotechnology</title><addtitle>Nano</addtitle><addtitle>Nanotechnology</addtitle><description>Stretchable transparent composites have been synthesized consisting of a silver nanowire (AgNW) network embedded in the surface layer of a crosslinked poly(acrylate) matrix. 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The morphology of the composites during reversible stretching and relaxation has been investigated to expound the conductivity changes.</description><subject>Crosslinking</subject><subject>Electrical resistivity</subject><subject>Electrodes</subject><subject>Nanostructure</subject><subject>Nanowires</subject><subject>Networks</subject><subject>Silver</subject><subject>Strain</subject><subject>Stretching</subject><issn>0957-4484</issn><issn>1361-6528</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqNkctOHDEQRa0oKEwgv4B6yaYZv-1eIkQACSkbWFtuu0YxcduN7QHN36cnA2yJVFJtzq2S7kHojOALgrVe40GonnPN15StGV-GY0y_oBVhkvRSUP0VrT6gY_S91ieMCdGUfEPHlGotNBYrNN2lVkKqwdkYd11tBZr7bccIXSs21dkWSK2DCK6V7KF2o63gu5y6GuILlD7ZlF9Dgd6VXGsM6Q_4fs5xZ13ZRdugc3macw0N6ik62thY4cfbPkGPP68frm77-183d1eX973jWrZeOeeBee0tOCyIs4MU0ivmieeU883oqHCjIBpLwoVUVoHcEE0YOKpHO7ATdH64O5f8vIXazBSqgxhtgrythiiFmZJ6kJ-jS6F8IJL8B4oZk5phJRZUHtB_pRTYmLmEyZbdApm9QLN3Y_ZuDGWGcXMQuATP3n5sxwn8R-zd2ALQAxDybJ7ytqSlyM-u_gV9CKen</recordid><startdate>20120831</startdate><enddate>20120831</enddate><creator>Hu, Weili</creator><creator>Niu, Xiaofan</creator><creator>Li, Lu</creator><creator>Yun, Sungryul</creator><creator>Yu, Zhibin</creator><creator>Pei, Qibing</creator><general>IOP Publishing</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20120831</creationdate><title>Intrinsically stretchable transparent electrodes based on silver-nanowire-crosslinked-polyacrylate composites</title><author>Hu, Weili ; Niu, Xiaofan ; Li, Lu ; Yun, Sungryul ; Yu, Zhibin ; Pei, Qibing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c486t-7ccde3d8daec051ca9656d73d1d4244fbc25cb5180614567a7e6f1813ec28ba93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Crosslinking</topic><topic>Electrical resistivity</topic><topic>Electrodes</topic><topic>Nanostructure</topic><topic>Nanowires</topic><topic>Networks</topic><topic>Silver</topic><topic>Strain</topic><topic>Stretching</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Weili</creatorcontrib><creatorcontrib>Niu, Xiaofan</creatorcontrib><creatorcontrib>Li, Lu</creatorcontrib><creatorcontrib>Yun, Sungryul</creatorcontrib><creatorcontrib>Yu, Zhibin</creatorcontrib><creatorcontrib>Pei, Qibing</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Nanotechnology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Weili</au><au>Niu, Xiaofan</au><au>Li, Lu</au><au>Yun, Sungryul</au><au>Yu, Zhibin</au><au>Pei, Qibing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Intrinsically stretchable transparent electrodes based on silver-nanowire-crosslinked-polyacrylate composites</atitle><jtitle>Nanotechnology</jtitle><stitle>Nano</stitle><addtitle>Nanotechnology</addtitle><date>2012-08-31</date><risdate>2012</risdate><volume>23</volume><issue>34</issue><spage>344002</spage><epage>1-9</epage><pages>344002-1-9</pages><issn>0957-4484</issn><eissn>1361-6528</eissn><coden>NNOTER</coden><abstract>Stretchable transparent composites have been synthesized consisting of a silver nanowire (AgNW) network embedded in the surface layer of a crosslinked poly(acrylate) matrix. The interpenetrating networks of AgNWs and the crosslinked polymer matrix lead to high surface conductivity, high transparency, and rubbery elasticity. The presence of carboxylic acid groups on the polymer chains enhances the bonding between AgNWs and the polymer matrix, and further increases the stretchability of the composites. The sheet resistance of the composite electrode increases by only 2.3 times at 50% strain. Repeated stretching to 50% strain and relaxation only causes a small increase of the sheet resistance after 600 cycles. The morphology of the composites during reversible stretching and relaxation has been investigated to expound the conductivity changes.</abstract><cop>England</cop><pub>IOP Publishing</pub><pmid>22885805</pmid><doi>10.1088/0957-4484/23/34/344002</doi><tpages>9</tpages></addata></record> |
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subjects | Crosslinking Electrical resistivity Electrodes Nanostructure Nanowires Networks Silver Strain Stretching |
title | Intrinsically stretchable transparent electrodes based on silver-nanowire-crosslinked-polyacrylate composites |
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