Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Alkenes

A novel copper‐catalyzed regiodivergent alkylboration of alkenes with bis(pinacolato)diboron and alkyl halides has been developed. The regioselectivity of the alkylboration was controlled by subtle differences in the ligand structure. The reaction thus enables the practical, regiodivergent synthesis...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2015-10, Vol.54 (44), p.12957-12961
Hauptverfasser:	Su, Wei, Gong, Tian-Jun, Lu, Xi, Xu, Meng-Yu, Yu, Chu-Guo, Xu, Zheng-Yang, Yu, Hai-Zhu, Xiao, Bin, Fu, Yao
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Alkenes - chemistry Boron Compounds - chemical synthesis Boron Compounds - chemistry Catalysis Copper Copper - chemistry cross-coupling difunctionalization Esters Halides homogeneous catalysis Ligands Molecular Structure Organometallic Compounds - chemistry Regioselectivity Stereoisomerism Synthesis (chemistry) synthetic methods
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!