Dual Function Additives: A Small Molecule Crosslinker for Enhanced Efficiency and Stability in Organic Solar Cells

A bis‐azide‐based small molecule crosslinker is synthesized and evaluated as both a stabilizing and efficiency‐boosting additive in bulk heterojunction organic photovoltaic cells. Activated by a noninvasive and scalable solution processing technique, polymer:fullerene blends exhibit improved therm...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Advanced energy materials 2015-05, Vol.5 (9), p.np-n/a
Hauptverfasser:	Rumer, Joseph W., Ashraf, Raja S., Eisenmenger, Nancy D., Huang, Zhenggang, Meager, Iain, Nielsen, Christian B., Schroeder, Bob C., Chabinyc, Michael L., McCulloch, Iain
Format:	Artikel
Sprache:	eng
Schlagworte:	Additives Agglomeration Aging Crosslinking Heterojunctions morphology organic photovoltaic Photovoltaic cells Polymer blends semiconducting polymer Solar cells stability
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	n/a
container_issue	9
container_start_page	np
container_title	Advanced energy materials
container_volume	5
creator	Rumer, Joseph W. Ashraf, Raja S. Eisenmenger, Nancy D. Huang, Zhenggang Meager, Iain Nielsen, Christian B. Schroeder, Bob C. Chabinyc, Michael L. McCulloch, Iain
description	A bis‐azide‐based small molecule crosslinker is synthesized and evaluated as both a stabilizing and efficiency‐boosting additive in bulk heterojunction organic photovoltaic cells. Activated by a noninvasive and scalable solution processing technique, polymer:fullerene blends exhibit improved thermal stability with suppressed polymer skin formation at the cathode and frustrated fullerene aggregation on ageing, with initial efficiency increased from 6% to 7%.
doi_str_mv	10.1002/aenm.201401426
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1770367797</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1770367797</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5356-e729f4499d06658339a834f49839e582a84b42cf0ae2f41595daa2e81c8b2153</originalsourceid><addsrcrecordid>eNqFkUtrGzEURoeSQkOabdeCbLoZV6_Rozvj2G4gThYOtDsha64aJbImkWbS-t9njIsJ2fQiuFqcIz70VdUXgicEY_rNQtpOKCZ8PFR8qE6JILwWiuOT453RT9V5KQ94HK4JZuy0ypeDjWgxJNeHLqFp24Y-vED5jqZovbUxolUXwQ0R0Cx3pcSQHiEj32U0T_c2OWjR3PvgAiS3Qza1aN3bTYih36GQ0G3-bVNwaN1Fm9EMYiyfq4_exgLn__ZZdbeY381-1Ne3y6vZ9Lp2DWtEDZJqz7nWLRaiUYxpqxj3XCumoVHUKr7h1HlsgXpOGt201lJQxKkNJQ07q74enn3K3fMApTfbUNwYwCbohmKIlJgJKbUc0Yt36EM35DSGM0RIJaXAgo_U5EC5_Udk8OYph63NO0Ow2Zdg9iWYYwmjoA_CnxBh9x_aTOc3q7dufXBD6eHv0bX50QjJZGN-3iwNvVTLX3y1MIy9ApkOmIU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1678776064</pqid></control><display><type>article</type><title>Dual Function Additives: A Small Molecule Crosslinker for Enhanced Efficiency and Stability in Organic Solar Cells</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Rumer, Joseph W. ; Ashraf, Raja S. ; Eisenmenger, Nancy D. ; Huang, Zhenggang ; Meager, Iain ; Nielsen, Christian B. ; Schroeder, Bob C. ; Chabinyc, Michael L. ; McCulloch, Iain</creator><creatorcontrib>Rumer, Joseph W. ; Ashraf, Raja S. ; Eisenmenger, Nancy D. ; Huang, Zhenggang ; Meager, Iain ; Nielsen, Christian B. ; Schroeder, Bob C. ; Chabinyc, Michael L. ; McCulloch, Iain</creatorcontrib><description>A bis‐azide‐based small molecule crosslinker is synthesized and evaluated as both a stabilizing and efficiency‐boosting additive in bulk heterojunction organic photovoltaic cells. Activated by a noninvasive and scalable solution processing technique, polymer:fullerene blends exhibit improved thermal stability with suppressed polymer skin formation at the cathode and frustrated fullerene aggregation on ageing, with initial efficiency increased from 6% to 7%.</description><identifier>ISSN: 1614-6832</identifier><identifier>EISSN: 1614-6840</identifier><identifier>DOI: 10.1002/aenm.201401426</identifier><language>eng</language><publisher>Weinheim: Blackwell Publishing Ltd</publisher><subject>Additives ; Agglomeration ; Aging ; Crosslinking ; Heterojunctions ; morphology ; organic photovoltaic ; Photovoltaic cells ; Polymer blends ; semiconducting polymer ; Solar cells ; stability</subject><ispartof>Advanced energy materials, 2015-05, Vol.5 (9), p.np-n/a</ispartof><rights>2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5356-e729f4499d06658339a834f49839e582a84b42cf0ae2f41595daa2e81c8b2153</citedby><cites>FETCH-LOGICAL-c5356-e729f4499d06658339a834f49839e582a84b42cf0ae2f41595daa2e81c8b2153</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faenm.201401426$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faenm.201401426$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Rumer, Joseph W.</creatorcontrib><creatorcontrib>Ashraf, Raja S.</creatorcontrib><creatorcontrib>Eisenmenger, Nancy D.</creatorcontrib><creatorcontrib>Huang, Zhenggang</creatorcontrib><creatorcontrib>Meager, Iain</creatorcontrib><creatorcontrib>Nielsen, Christian B.</creatorcontrib><creatorcontrib>Schroeder, Bob C.</creatorcontrib><creatorcontrib>Chabinyc, Michael L.</creatorcontrib><creatorcontrib>McCulloch, Iain</creatorcontrib><title>Dual Function Additives: A Small Molecule Crosslinker for Enhanced Efficiency and Stability in Organic Solar Cells</title><title>Advanced energy materials</title><addtitle>Adv. Energy Mater</addtitle><description>A bis‐azide‐based small molecule crosslinker is synthesized and evaluated as both a stabilizing and efficiency‐boosting additive in bulk heterojunction organic photovoltaic cells. Activated by a noninvasive and scalable solution processing technique, polymer:fullerene blends exhibit improved thermal stability with suppressed polymer skin formation at the cathode and frustrated fullerene aggregation on ageing, with initial efficiency increased from 6% to 7%.</description><subject>Additives</subject><subject>Agglomeration</subject><subject>Aging</subject><subject>Crosslinking</subject><subject>Heterojunctions</subject><subject>morphology</subject><subject>organic photovoltaic</subject><subject>Photovoltaic cells</subject><subject>Polymer blends</subject><subject>semiconducting polymer</subject><subject>Solar cells</subject><subject>stability</subject><issn>1614-6832</issn><issn>1614-6840</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><recordid>eNqFkUtrGzEURoeSQkOabdeCbLoZV6_Rozvj2G4gThYOtDsha64aJbImkWbS-t9njIsJ2fQiuFqcIz70VdUXgicEY_rNQtpOKCZ8PFR8qE6JILwWiuOT453RT9V5KQ94HK4JZuy0ypeDjWgxJNeHLqFp24Y-vED5jqZovbUxolUXwQ0R0Cx3pcSQHiEj32U0T_c2OWjR3PvgAiS3Qza1aN3bTYih36GQ0G3-bVNwaN1Fm9EMYiyfq4_exgLn__ZZdbeY381-1Ne3y6vZ9Lp2DWtEDZJqz7nWLRaiUYxpqxj3XCumoVHUKr7h1HlsgXpOGt201lJQxKkNJQ07q74enn3K3fMApTfbUNwYwCbohmKIlJgJKbUc0Yt36EM35DSGM0RIJaXAgo_U5EC5_Udk8OYph63NO0Ow2Zdg9iWYYwmjoA_CnxBh9x_aTOc3q7dufXBD6eHv0bX50QjJZGN-3iwNvVTLX3y1MIy9ApkOmIU</recordid><startdate>20150501</startdate><enddate>20150501</enddate><creator>Rumer, Joseph W.</creator><creator>Ashraf, Raja S.</creator><creator>Eisenmenger, Nancy D.</creator><creator>Huang, Zhenggang</creator><creator>Meager, Iain</creator><creator>Nielsen, Christian B.</creator><creator>Schroeder, Bob C.</creator><creator>Chabinyc, Michael L.</creator><creator>McCulloch, Iain</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>24P</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20150501</creationdate><title>Dual Function Additives: A Small Molecule Crosslinker for Enhanced Efficiency and Stability in Organic Solar Cells</title><author>Rumer, Joseph W. ; Ashraf, Raja S. ; Eisenmenger, Nancy D. ; Huang, Zhenggang ; Meager, Iain ; Nielsen, Christian B. ; Schroeder, Bob C. ; Chabinyc, Michael L. ; McCulloch, Iain</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5356-e729f4499d06658339a834f49839e582a84b42cf0ae2f41595daa2e81c8b2153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Additives</topic><topic>Agglomeration</topic><topic>Aging</topic><topic>Crosslinking</topic><topic>Heterojunctions</topic><topic>morphology</topic><topic>organic photovoltaic</topic><topic>Photovoltaic cells</topic><topic>Polymer blends</topic><topic>semiconducting polymer</topic><topic>Solar cells</topic><topic>stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rumer, Joseph W.</creatorcontrib><creatorcontrib>Ashraf, Raja S.</creatorcontrib><creatorcontrib>Eisenmenger, Nancy D.</creatorcontrib><creatorcontrib>Huang, Zhenggang</creatorcontrib><creatorcontrib>Meager, Iain</creatorcontrib><creatorcontrib>Nielsen, Christian B.</creatorcontrib><creatorcontrib>Schroeder, Bob C.</creatorcontrib><creatorcontrib>Chabinyc, Michael L.</creatorcontrib><creatorcontrib>McCulloch, Iain</creatorcontrib><collection>Istex</collection><collection>Wiley Online Library Open Access</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced energy materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rumer, Joseph W.</au><au>Ashraf, Raja S.</au><au>Eisenmenger, Nancy D.</au><au>Huang, Zhenggang</au><au>Meager, Iain</au><au>Nielsen, Christian B.</au><au>Schroeder, Bob C.</au><au>Chabinyc, Michael L.</au><au>McCulloch, Iain</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dual Function Additives: A Small Molecule Crosslinker for Enhanced Efficiency and Stability in Organic Solar Cells</atitle><jtitle>Advanced energy materials</jtitle><addtitle>Adv. Energy Mater</addtitle><date>2015-05-01</date><risdate>2015</risdate><volume>5</volume><issue>9</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>1614-6832</issn><eissn>1614-6840</eissn><abstract>A bis‐azide‐based small molecule crosslinker is synthesized and evaluated as both a stabilizing and efficiency‐boosting additive in bulk heterojunction organic photovoltaic cells. Activated by a noninvasive and scalable solution processing technique, polymer:fullerene blends exhibit improved thermal stability with suppressed polymer skin formation at the cathode and frustrated fullerene aggregation on ageing, with initial efficiency increased from 6% to 7%.</abstract><cop>Weinheim</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/aenm.201401426</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record>
fulltext	fulltext
identifier	ISSN: 1614-6832
ispartof	Advanced energy materials, 2015-05, Vol.5 (9), p.np-n/a
issn	1614-6832 1614-6840
language	eng
recordid	cdi_proquest_miscellaneous_1770367797
source	Wiley Online Library Journals Frontfile Complete
subjects	Additives Agglomeration Aging Crosslinking Heterojunctions morphology organic photovoltaic Photovoltaic cells Polymer blends semiconducting polymer Solar cells stability
title	Dual Function Additives: A Small Molecule Crosslinker for Enhanced Efficiency and Stability in Organic Solar Cells
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-14T10%3A31%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Dual%20Function%20Additives:%20A%20Small%20Molecule%20Crosslinker%20for%20Enhanced%20Efficiency%20and%20Stability%20in%20Organic%20Solar%20Cells&rft.jtitle=Advanced%20energy%20materials&rft.au=Rumer,%20Joseph%20W.&rft.date=2015-05-01&rft.volume=5&rft.issue=9&rft.spage=np&rft.epage=n/a&rft.pages=np-n/a&rft.issn=1614-6832&rft.eissn=1614-6840&rft_id=info:doi/10.1002/aenm.201401426&rft_dat=%3Cproquest_cross%3E1770367797%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1678776064&rft_id=info:pmid/&rfr_iscdi=true