Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in "Click Chemistry"

The synthesis and characterization of abnormal N‐heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper ox...

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Veröffentlicht in:	Advanced synthesis & catalysis 2015-10, Vol.357 (14-15), p.3155-3161
Hauptverfasser:	Bidal, Yannick D., Lesieur, Mathieu, Melaimi, Mohand, Nahra, Fady, Cordes, David B., Athukorala Arachchige, Kasun S., Slawin, Alexandra M. Z., Bertrand, Guy, Cazin, Catherine S. J.
Format:	Artikel
Sprache:	eng
Schlagworte:	[3+2] cycloaddition abnormal carbenes ACTIVITY Alkynes Bearing BEARINGS Carbenes Catalysis Catalytic activity click chemistry copper COPPER COMPOUNDS COPPER OXIDE FABRICATION Metalorganic compounds N-heterocyclic carbenes remote carbenes Synthesis Synthesis (chemistry)
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