Effect of magnetic and thermal properties of iron oxide nanoparticles (IONs) in nitrile butadiene rubber (NBR) latex
Nitrile butadiene rubber (NBR) gloves are one of the most important personal protective equipments but they are possible to tear off and contaminate food or pharmaceutical and healthcare products during manufacturing and packaging process. High tendency of torn glove remaining in food or products du...
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| Veröffentlicht in: | Journal of magnetism and magnetic materials 2015-12, Vol.395, p.173-179 |
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| creator | Ong, Hun Tiar Julkapli, Nurhidayatullaili Muhd Hamid, Sharifah Bee Abd Boondamnoen, O. Tai, Mun Foong |
| description | Nitrile butadiene rubber (NBR) gloves are one of the most important personal protective equipments but they are possible to tear off and contaminate food or pharmaceutical and healthcare products during manufacturing and packaging process. High tendency of torn glove remaining in food or products due to white or light flesh-coloured glove is not easy to be detected by naked eyes. In this paper, iron oxide nanoparticles (IONs) selected as additive for NBR to improve its detectability by mean of magnetic properties. IONs synthesized via precipitation method and compounded with NBR latex before casting on petri dish. The properties of IONs were investigated by X-ray Diffractometry (XRD), Transmission Electron Microscope (TEM), Raman Spectroscopy and Vibrating Sample Magnetometer (VSM). Meanwhile NBR/IONs composites were studied by Thermogravimetry Analysis (TGA), Differential Scanning Calorimetry (DSC) and Vibrating Sample Magnetometer (VSM). It observed that, synthesized IONs shows of 25.28nm crystallite with 25.86nm semipherical (changed as) shape. Meanwhile, Magnetite and maghemite phase are found in range of 670cm−1 and 700cm−1 respectively, which it contributes magnetization saturation of 73.96emu/g at 10,000G by VSM. Thermal stability and magnetic properties were increased with incorporating IONs into NBR latex up to 20phr. NBR/IONs 5phr has the optimum thermal stability, lowest glass transition temperature (−14.83°C) and acceptable range of magnetization saturation (3.83emu/g at 10,000G) to form NBR gloves with magnetic detectability.
•We synthesized IONs with high magnetization saturation (Ms).•High Ms of IONs were incorporated into NBR latex in order to induce magnetic properties in the NBR composite.•Introduction of IONs into NBR latex would improve thermal properties.•The produced NBR/IONs 5phr composite exceeded the minimum magnetic moment sensor of the detector.•They have high potential for the pharmaceutical, food, medicine and laboratories industries. |
| doi_str_mv | 10.1016/j.jmmm.2015.07.028 |
| format | Article |
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•We synthesized IONs with high magnetization saturation (Ms).•High Ms of IONs were incorporated into NBR latex in order to induce magnetic properties in the NBR composite.•Introduction of IONs into NBR latex would improve thermal properties.•The produced NBR/IONs 5phr composite exceeded the minimum magnetic moment sensor of the detector.•They have high potential for the pharmaceutical, food, medicine and laboratories industries.</description><identifier>ISSN: 0304-8853</identifier><identifier>DOI: 10.1016/j.jmmm.2015.07.028</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Differential scanning calorimetry ; Gloves ; Iron oxide nanoparticles ; Iron oxides ; Latex ; magnetic detectability ; Magnetic properties ; magnetization ; Nitrile butadiene composite ; Nitriles ; Rubber ; Saturation ; thermal stability</subject><ispartof>Journal of magnetism and magnetic materials, 2015-12, Vol.395, p.173-179</ispartof><rights>2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c333t-ea3e40e71ca558ca92b3186d01d265d73e26e9cf83abffa51c7ae33540471a373</citedby><cites>FETCH-LOGICAL-c333t-ea3e40e71ca558ca92b3186d01d265d73e26e9cf83abffa51c7ae33540471a373</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0304885315303358$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Ong, Hun Tiar</creatorcontrib><creatorcontrib>Julkapli, Nurhidayatullaili Muhd</creatorcontrib><creatorcontrib>Hamid, Sharifah Bee Abd</creatorcontrib><creatorcontrib>Boondamnoen, O.</creatorcontrib><creatorcontrib>Tai, Mun Foong</creatorcontrib><title>Effect of magnetic and thermal properties of iron oxide nanoparticles (IONs) in nitrile butadiene rubber (NBR) latex</title><title>Journal of magnetism and magnetic materials</title><description>Nitrile butadiene rubber (NBR) gloves are one of the most important personal protective equipments but they are possible to tear off and contaminate food or pharmaceutical and healthcare products during manufacturing and packaging process. High tendency of torn glove remaining in food or products due to white or light flesh-coloured glove is not easy to be detected by naked eyes. In this paper, iron oxide nanoparticles (IONs) selected as additive for NBR to improve its detectability by mean of magnetic properties. IONs synthesized via precipitation method and compounded with NBR latex before casting on petri dish. The properties of IONs were investigated by X-ray Diffractometry (XRD), Transmission Electron Microscope (TEM), Raman Spectroscopy and Vibrating Sample Magnetometer (VSM). Meanwhile NBR/IONs composites were studied by Thermogravimetry Analysis (TGA), Differential Scanning Calorimetry (DSC) and Vibrating Sample Magnetometer (VSM). It observed that, synthesized IONs shows of 25.28nm crystallite with 25.86nm semipherical (changed as) shape. Meanwhile, Magnetite and maghemite phase are found in range of 670cm−1 and 700cm−1 respectively, which it contributes magnetization saturation of 73.96emu/g at 10,000G by VSM. Thermal stability and magnetic properties were increased with incorporating IONs into NBR latex up to 20phr. NBR/IONs 5phr has the optimum thermal stability, lowest glass transition temperature (−14.83°C) and acceptable range of magnetization saturation (3.83emu/g at 10,000G) to form NBR gloves with magnetic detectability.
•We synthesized IONs with high magnetization saturation (Ms).•High Ms of IONs were incorporated into NBR latex in order to induce magnetic properties in the NBR composite.•Introduction of IONs into NBR latex would improve thermal properties.•The produced NBR/IONs 5phr composite exceeded the minimum magnetic moment sensor of the detector.•They have high potential for the pharmaceutical, food, medicine and laboratories industries.</description><subject>Differential scanning calorimetry</subject><subject>Gloves</subject><subject>Iron oxide nanoparticles</subject><subject>Iron oxides</subject><subject>Latex</subject><subject>magnetic detectability</subject><subject>Magnetic properties</subject><subject>magnetization</subject><subject>Nitrile butadiene composite</subject><subject>Nitriles</subject><subject>Rubber</subject><subject>Saturation</subject><subject>thermal stability</subject><issn>0304-8853</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kLtOwzAUhj2ARCm8AJPHdmiw4yROJRaouFSqWgnBbJ04J-AocYrtoPL2uCoz0xn-y9H_EXLDWcIZL27bpO37PkkZzxMmE5aWZ2TCBMsWZZmLC3LpfcsY41lZTEh4bBrUgQ4N7eHDYjCagq1p-ETXQ0f3btijCwb90WLcYOlwMDVSC3bYQ1R0F7XZerf1c2ostSY40yGtxgC1QYvUjVWFjs62D69z2kHAwxU5b6DzeP13p-T96fFt9bLY7J7Xq_vNQgshwgJBYMZQcg15XmpYppXgZVEzXqdFXkuBaYFL3ZQCqqaBnGsJKESesUxyEFJMyezUG1d8jeiD6o3X2HVgcRi94lIyEb3x25SkJ6t2g_cOG7V3pgf3ozhTR6yqVUes6ohVMaki1hi6O4Uwjvg26JTXcbLG2rgIVdWD-S_-C6NEg6U</recordid><startdate>20151201</startdate><enddate>20151201</enddate><creator>Ong, Hun Tiar</creator><creator>Julkapli, Nurhidayatullaili Muhd</creator><creator>Hamid, Sharifah Bee Abd</creator><creator>Boondamnoen, O.</creator><creator>Tai, Mun Foong</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20151201</creationdate><title>Effect of magnetic and thermal properties of iron oxide nanoparticles (IONs) in nitrile butadiene rubber (NBR) latex</title><author>Ong, Hun Tiar ; Julkapli, Nurhidayatullaili Muhd ; Hamid, Sharifah Bee Abd ; Boondamnoen, O. ; Tai, Mun Foong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c333t-ea3e40e71ca558ca92b3186d01d265d73e26e9cf83abffa51c7ae33540471a373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Differential scanning calorimetry</topic><topic>Gloves</topic><topic>Iron oxide nanoparticles</topic><topic>Iron oxides</topic><topic>Latex</topic><topic>magnetic detectability</topic><topic>Magnetic properties</topic><topic>magnetization</topic><topic>Nitrile butadiene composite</topic><topic>Nitriles</topic><topic>Rubber</topic><topic>Saturation</topic><topic>thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ong, Hun Tiar</creatorcontrib><creatorcontrib>Julkapli, Nurhidayatullaili Muhd</creatorcontrib><creatorcontrib>Hamid, Sharifah Bee Abd</creatorcontrib><creatorcontrib>Boondamnoen, O.</creatorcontrib><creatorcontrib>Tai, Mun Foong</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of magnetism and magnetic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ong, Hun Tiar</au><au>Julkapli, Nurhidayatullaili Muhd</au><au>Hamid, Sharifah Bee Abd</au><au>Boondamnoen, O.</au><au>Tai, Mun Foong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of magnetic and thermal properties of iron oxide nanoparticles (IONs) in nitrile butadiene rubber (NBR) latex</atitle><jtitle>Journal of magnetism and magnetic materials</jtitle><date>2015-12-01</date><risdate>2015</risdate><volume>395</volume><spage>173</spage><epage>179</epage><pages>173-179</pages><issn>0304-8853</issn><abstract>Nitrile butadiene rubber (NBR) gloves are one of the most important personal protective equipments but they are possible to tear off and contaminate food or pharmaceutical and healthcare products during manufacturing and packaging process. High tendency of torn glove remaining in food or products due to white or light flesh-coloured glove is not easy to be detected by naked eyes. In this paper, iron oxide nanoparticles (IONs) selected as additive for NBR to improve its detectability by mean of magnetic properties. IONs synthesized via precipitation method and compounded with NBR latex before casting on petri dish. The properties of IONs were investigated by X-ray Diffractometry (XRD), Transmission Electron Microscope (TEM), Raman Spectroscopy and Vibrating Sample Magnetometer (VSM). Meanwhile NBR/IONs composites were studied by Thermogravimetry Analysis (TGA), Differential Scanning Calorimetry (DSC) and Vibrating Sample Magnetometer (VSM). It observed that, synthesized IONs shows of 25.28nm crystallite with 25.86nm semipherical (changed as) shape. Meanwhile, Magnetite and maghemite phase are found in range of 670cm−1 and 700cm−1 respectively, which it contributes magnetization saturation of 73.96emu/g at 10,000G by VSM. Thermal stability and magnetic properties were increased with incorporating IONs into NBR latex up to 20phr. NBR/IONs 5phr has the optimum thermal stability, lowest glass transition temperature (−14.83°C) and acceptable range of magnetization saturation (3.83emu/g at 10,000G) to form NBR gloves with magnetic detectability.
•We synthesized IONs with high magnetization saturation (Ms).•High Ms of IONs were incorporated into NBR latex in order to induce magnetic properties in the NBR composite.•Introduction of IONs into NBR latex would improve thermal properties.•The produced NBR/IONs 5phr composite exceeded the minimum magnetic moment sensor of the detector.•They have high potential for the pharmaceutical, food, medicine and laboratories industries.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jmmm.2015.07.028</doi><tpages>7</tpages></addata></record> |
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| subjects | Differential scanning calorimetry Gloves Iron oxide nanoparticles Iron oxides Latex magnetic detectability Magnetic properties magnetization Nitrile butadiene composite Nitriles Rubber Saturation thermal stability |
| title | Effect of magnetic and thermal properties of iron oxide nanoparticles (IONs) in nitrile butadiene rubber (NBR) latex |
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