Chain-growth copolymerization of functionalized ethynylarenes with 1,4-diethynylbenzene and 4,4′-diethynylbiphenyl into conjugated porous networks

[Display omitted] •Highly functionalized conjugated micro/mesoporous networks were prepared.•The chain-growth copolymerization of substituted ethynylarenes was used.•BET area up to 667m2/g, content of functional groups up to 3.9mmol/g is achieved.•Networks with –NO2 and –CH2OH groups exhibit enhance...

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Veröffentlicht in:	European polymer journal 2015-06, Vol.67, p.252-263
Hauptverfasser:	Stahlová, Sabina, Slováková, Eva, Vaňkátová, Petra, Zukal, Arnošt, Kubů, Martin, Brus, Jiří, Bondarev, Dmitrij, Moučka, Robert, Sedláček, Jan
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Chains (polymeric) Conjugated networks Copolymerization Couplings Crosslinking Diethynylbenzene Diethynylbiphenyl Microporous polymers Networks Polyacetylenes Rh-catalyst Specific surface Synthesis
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