Bifunctional Nano Lycurgus Cup Array Plasmonic Sensor for Colorimetric Sensing and Surface‐Enhanced Raman Spectroscopy

A bifunctional ultrasensitive nanoplasmonic sensor is demonstrated with combined surface plasmon resonance (SPR) and surface‐enhanced Raman spectroscopy (SERS) sensing capabilities. Unlike traditional extraordinary transmission (EOT) devices, nano Lycurgus cup array (nanoLCA) contains a hybrid confi...

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Veröffentlicht in:Advanced optical materials 2015-10, Vol.3 (10), p.1397-1404
Hauptverfasser: Chang, Te‐Wei, Wang, Xinhao, Hsiao, Austin, Xu, Zhida, Lin, Guohong, Gartia, Manas Ranjan, Liu, Xiangrong, Liu, Gang Logan
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container_end_page 1404
container_issue 10
container_start_page 1397
container_title Advanced optical materials
container_volume 3
creator Chang, Te‐Wei
Wang, Xinhao
Hsiao, Austin
Xu, Zhida
Lin, Guohong
Gartia, Manas Ranjan
Liu, Xiangrong
Liu, Gang Logan
description A bifunctional ultrasensitive nanoplasmonic sensor is demonstrated with combined surface plasmon resonance (SPR) and surface‐enhanced Raman spectroscopy (SERS) sensing capabilities. Unlike traditional extraordinary transmission (EOT) devices, nano Lycurgus cup array (nanoLCA) contains a hybrid configuration of periodic quasi‐3D nanostructure array and dense sidewall metal nanoparticles within each nanostructure, which enables both refractive index sensing and SERS chemical identification on the same device with high sensitivity. The visible plasmon resonance sensitivity of nanoLCA is measured to be as high as 796 nm/RIU with the figure of merit (FOM) of 12.7 so that the device is applied for colorimetric liquid sensing with an ordinary microscopic system. Moreover, the SERS enhancement of the very same nanoLCA for liquid sample is calculated to be 2.8 × 107, which is the highest among all reported EOT‐based SERS devices. The urea concentration detection has been demonstrated to show the complementary rapid colorimetric screening and precise SERS identification functions provided by nanoLCA plasmonic sensor for chemical analysis or biological diagnostics in a resource‐limited environment. A bifunctional nano Lycurgus cup array (nanoLCA) plasmonic sensor is demon­strated. NanoLCA contains a hybrid configuration of periodic quasi‐3D nanostructure and dense sidewall metal nanoparticles, which enable to perform high‐sensitivity colorimetric sensing and surface‐enhanced Raman spectroscopy (SERS) at the same device. The SERS enhancement under the solution‐based environment is the highest among all the reported extraordinary transmission devices.
doi_str_mv 10.1002/adom.201500092
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Unlike traditional extraordinary transmission (EOT) devices, nano Lycurgus cup array (nanoLCA) contains a hybrid configuration of periodic quasi‐3D nanostructure array and dense sidewall metal nanoparticles within each nanostructure, which enables both refractive index sensing and SERS chemical identification on the same device with high sensitivity. The visible plasmon resonance sensitivity of nanoLCA is measured to be as high as 796 nm/RIU with the figure of merit (FOM) of 12.7 so that the device is applied for colorimetric liquid sensing with an ordinary microscopic system. Moreover, the SERS enhancement of the very same nanoLCA for liquid sample is calculated to be 2.8 × 107, which is the highest among all reported EOT‐based SERS devices. The urea concentration detection has been demonstrated to show the complementary rapid colorimetric screening and precise SERS identification functions provided by nanoLCA plasmonic sensor for chemical analysis or biological diagnostics in a resource‐limited environment. A bifunctional nano Lycurgus cup array (nanoLCA) plasmonic sensor is demon­strated. NanoLCA contains a hybrid configuration of periodic quasi‐3D nanostructure and dense sidewall metal nanoparticles, which enable to perform high‐sensitivity colorimetric sensing and surface‐enhanced Raman spectroscopy (SERS) at the same device. 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source Wiley Online Library Journals Frontfile Complete
subjects Arrays
Colorimetry
Detection
Devices
extraordinary transmission
Lycurgus cup array
nanoplasmonics
Nanostructure
Optics
Plasmonics
Raman spectroscopy
Sensors
SERS
title Bifunctional Nano Lycurgus Cup Array Plasmonic Sensor for Colorimetric Sensing and Surface‐Enhanced Raman Spectroscopy
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