Bifunctional Nano Lycurgus Cup Array Plasmonic Sensor for Colorimetric Sensing and Surface‐Enhanced Raman Spectroscopy
A bifunctional ultrasensitive nanoplasmonic sensor is demonstrated with combined surface plasmon resonance (SPR) and surface‐enhanced Raman spectroscopy (SERS) sensing capabilities. Unlike traditional extraordinary transmission (EOT) devices, nano Lycurgus cup array (nanoLCA) contains a hybrid confi...
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Veröffentlicht in: | Advanced optical materials 2015-10, Vol.3 (10), p.1397-1404 |
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creator | Chang, Te‐Wei Wang, Xinhao Hsiao, Austin Xu, Zhida Lin, Guohong Gartia, Manas Ranjan Liu, Xiangrong Liu, Gang Logan |
description | A bifunctional ultrasensitive nanoplasmonic sensor is demonstrated with combined surface plasmon resonance (SPR) and surface‐enhanced Raman spectroscopy (SERS) sensing capabilities. Unlike traditional extraordinary transmission (EOT) devices, nano Lycurgus cup array (nanoLCA) contains a hybrid configuration of periodic quasi‐3D nanostructure array and dense sidewall metal nanoparticles within each nanostructure, which enables both refractive index sensing and SERS chemical identification on the same device with high sensitivity. The visible plasmon resonance sensitivity of nanoLCA is measured to be as high as 796 nm/RIU with the figure of merit (FOM) of 12.7 so that the device is applied for colorimetric liquid sensing with an ordinary microscopic system. Moreover, the SERS enhancement of the very same nanoLCA for liquid sample is calculated to be 2.8 × 107, which is the highest among all reported EOT‐based SERS devices. The urea concentration detection has been demonstrated to show the complementary rapid colorimetric screening and precise SERS identification functions provided by nanoLCA plasmonic sensor for chemical analysis or biological diagnostics in a resource‐limited environment.
A bifunctional nano Lycurgus cup array (nanoLCA) plasmonic sensor is demonstrated. NanoLCA contains a hybrid configuration of periodic quasi‐3D nanostructure and dense sidewall metal nanoparticles, which enable to perform high‐sensitivity colorimetric sensing and surface‐enhanced Raman spectroscopy (SERS) at the same device. The SERS enhancement under the solution‐based environment is the highest among all the reported extraordinary transmission devices. |
doi_str_mv | 10.1002/adom.201500092 |
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A bifunctional nano Lycurgus cup array (nanoLCA) plasmonic sensor is demonstrated. NanoLCA contains a hybrid configuration of periodic quasi‐3D nanostructure and dense sidewall metal nanoparticles, which enable to perform high‐sensitivity colorimetric sensing and surface‐enhanced Raman spectroscopy (SERS) at the same device. The SERS enhancement under the solution‐based environment is the highest among all the reported extraordinary transmission devices.</description><identifier>ISSN: 2195-1071</identifier><identifier>EISSN: 2195-1071</identifier><identifier>DOI: 10.1002/adom.201500092</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Arrays ; Colorimetry ; Detection ; Devices ; extraordinary transmission ; Lycurgus cup array ; nanoplasmonics ; Nanostructure ; Optics ; Plasmonics ; Raman spectroscopy ; Sensors ; SERS</subject><ispartof>Advanced optical materials, 2015-10, Vol.3 (10), p.1397-1404</ispartof><rights>2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4202-fc8a4da48ecf3b3d844f02f65d42de2c3ee0791b2e358a4680118a3d963e7b3f3</citedby><cites>FETCH-LOGICAL-c4202-fc8a4da48ecf3b3d844f02f65d42de2c3ee0791b2e358a4680118a3d963e7b3f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadom.201500092$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadom.201500092$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27922,27923,45572,45573</link.rule.ids></links><search><creatorcontrib>Chang, Te‐Wei</creatorcontrib><creatorcontrib>Wang, Xinhao</creatorcontrib><creatorcontrib>Hsiao, Austin</creatorcontrib><creatorcontrib>Xu, Zhida</creatorcontrib><creatorcontrib>Lin, Guohong</creatorcontrib><creatorcontrib>Gartia, Manas Ranjan</creatorcontrib><creatorcontrib>Liu, Xiangrong</creatorcontrib><creatorcontrib>Liu, Gang Logan</creatorcontrib><title>Bifunctional Nano Lycurgus Cup Array Plasmonic Sensor for Colorimetric Sensing and Surface‐Enhanced Raman Spectroscopy</title><title>Advanced optical materials</title><description>A bifunctional ultrasensitive nanoplasmonic sensor is demonstrated with combined surface plasmon resonance (SPR) and surface‐enhanced Raman spectroscopy (SERS) sensing capabilities. Unlike traditional extraordinary transmission (EOT) devices, nano Lycurgus cup array (nanoLCA) contains a hybrid configuration of periodic quasi‐3D nanostructure array and dense sidewall metal nanoparticles within each nanostructure, which enables both refractive index sensing and SERS chemical identification on the same device with high sensitivity. The visible plasmon resonance sensitivity of nanoLCA is measured to be as high as 796 nm/RIU with the figure of merit (FOM) of 12.7 so that the device is applied for colorimetric liquid sensing with an ordinary microscopic system. Moreover, the SERS enhancement of the very same nanoLCA for liquid sample is calculated to be 2.8 × 107, which is the highest among all reported EOT‐based SERS devices. The urea concentration detection has been demonstrated to show the complementary rapid colorimetric screening and precise SERS identification functions provided by nanoLCA plasmonic sensor for chemical analysis or biological diagnostics in a resource‐limited environment.
A bifunctional nano Lycurgus cup array (nanoLCA) plasmonic sensor is demonstrated. NanoLCA contains a hybrid configuration of periodic quasi‐3D nanostructure and dense sidewall metal nanoparticles, which enable to perform high‐sensitivity colorimetric sensing and surface‐enhanced Raman spectroscopy (SERS) at the same device. The SERS enhancement under the solution‐based environment is the highest among all the reported extraordinary transmission devices.</description><subject>Arrays</subject><subject>Colorimetry</subject><subject>Detection</subject><subject>Devices</subject><subject>extraordinary transmission</subject><subject>Lycurgus cup array</subject><subject>nanoplasmonics</subject><subject>Nanostructure</subject><subject>Optics</subject><subject>Plasmonics</subject><subject>Raman spectroscopy</subject><subject>Sensors</subject><subject>SERS</subject><issn>2195-1071</issn><issn>2195-1071</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkctKw0AUhoMoWGq3rgfcuEmdW5pkWWu9QLVidR2mkzM1JZmJMwmanY_gM_okTmlRcePicC58_4Fz_iA4JnhIMKZnIjfVkGISYYxTuhf0KEmjkOCY7P-qD4OBc2uP-IalPO4Fb-eFarVsCqNFie6ENmjWydauWocmbY3G1ooO3ZfCVUYXEi1AO2OR8jExpbFFBY3dzQu9QkLnaNFaJSR8vn9M9bPQEnL0ICqh0aIG2VjjpKm7o-BAidLBYJf7wdPl9HFyHc7mVzeT8SyUnGIaKpkInguegFRsyfKEc4WpGkU5pzlQyQBwnJIlBRZ5cpRgQhLB8nTEIF4yxfrB6XZvbc1LC67JqsJJKEuhwbQuI3GMGWUx5h49-YOuTWv9XzYUZQnlaUQ8NdxS0l_iLKis9l8QtssIzjZeZBsvsm8vvCDdCl6LErp_6Gx8Mb_90X4BuAmPUQ</recordid><startdate>201510</startdate><enddate>201510</enddate><creator>Chang, Te‐Wei</creator><creator>Wang, Xinhao</creator><creator>Hsiao, Austin</creator><creator>Xu, Zhida</creator><creator>Lin, Guohong</creator><creator>Gartia, Manas Ranjan</creator><creator>Liu, Xiangrong</creator><creator>Liu, Gang Logan</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>201510</creationdate><title>Bifunctional Nano Lycurgus Cup Array Plasmonic Sensor for Colorimetric Sensing and Surface‐Enhanced Raman Spectroscopy</title><author>Chang, Te‐Wei ; Wang, Xinhao ; Hsiao, Austin ; Xu, Zhida ; Lin, Guohong ; Gartia, Manas Ranjan ; Liu, Xiangrong ; Liu, Gang Logan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4202-fc8a4da48ecf3b3d844f02f65d42de2c3ee0791b2e358a4680118a3d963e7b3f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Arrays</topic><topic>Colorimetry</topic><topic>Detection</topic><topic>Devices</topic><topic>extraordinary transmission</topic><topic>Lycurgus cup array</topic><topic>nanoplasmonics</topic><topic>Nanostructure</topic><topic>Optics</topic><topic>Plasmonics</topic><topic>Raman spectroscopy</topic><topic>Sensors</topic><topic>SERS</topic><toplevel>online_resources</toplevel><creatorcontrib>Chang, Te‐Wei</creatorcontrib><creatorcontrib>Wang, Xinhao</creatorcontrib><creatorcontrib>Hsiao, Austin</creatorcontrib><creatorcontrib>Xu, Zhida</creatorcontrib><creatorcontrib>Lin, Guohong</creatorcontrib><creatorcontrib>Gartia, Manas Ranjan</creatorcontrib><creatorcontrib>Liu, Xiangrong</creatorcontrib><creatorcontrib>Liu, Gang Logan</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced optical materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chang, Te‐Wei</au><au>Wang, Xinhao</au><au>Hsiao, Austin</au><au>Xu, Zhida</au><au>Lin, Guohong</au><au>Gartia, Manas Ranjan</au><au>Liu, Xiangrong</au><au>Liu, Gang Logan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bifunctional Nano Lycurgus Cup Array Plasmonic Sensor for Colorimetric Sensing and Surface‐Enhanced Raman Spectroscopy</atitle><jtitle>Advanced optical materials</jtitle><date>2015-10</date><risdate>2015</risdate><volume>3</volume><issue>10</issue><spage>1397</spage><epage>1404</epage><pages>1397-1404</pages><issn>2195-1071</issn><eissn>2195-1071</eissn><abstract>A bifunctional ultrasensitive nanoplasmonic sensor is demonstrated with combined surface plasmon resonance (SPR) and surface‐enhanced Raman spectroscopy (SERS) sensing capabilities. Unlike traditional extraordinary transmission (EOT) devices, nano Lycurgus cup array (nanoLCA) contains a hybrid configuration of periodic quasi‐3D nanostructure array and dense sidewall metal nanoparticles within each nanostructure, which enables both refractive index sensing and SERS chemical identification on the same device with high sensitivity. The visible plasmon resonance sensitivity of nanoLCA is measured to be as high as 796 nm/RIU with the figure of merit (FOM) of 12.7 so that the device is applied for colorimetric liquid sensing with an ordinary microscopic system. Moreover, the SERS enhancement of the very same nanoLCA for liquid sample is calculated to be 2.8 × 107, which is the highest among all reported EOT‐based SERS devices. The urea concentration detection has been demonstrated to show the complementary rapid colorimetric screening and precise SERS identification functions provided by nanoLCA plasmonic sensor for chemical analysis or biological diagnostics in a resource‐limited environment.
A bifunctional nano Lycurgus cup array (nanoLCA) plasmonic sensor is demonstrated. NanoLCA contains a hybrid configuration of periodic quasi‐3D nanostructure and dense sidewall metal nanoparticles, which enable to perform high‐sensitivity colorimetric sensing and surface‐enhanced Raman spectroscopy (SERS) at the same device. The SERS enhancement under the solution‐based environment is the highest among all the reported extraordinary transmission devices.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adom.201500092</doi><tpages>8</tpages></addata></record> |
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subjects | Arrays Colorimetry Detection Devices extraordinary transmission Lycurgus cup array nanoplasmonics Nanostructure Optics Plasmonics Raman spectroscopy Sensors SERS |
title | Bifunctional Nano Lycurgus Cup Array Plasmonic Sensor for Colorimetric Sensing and Surface‐Enhanced Raman Spectroscopy |
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