Organic-coated nanoparticulate zero valent iron for remediation of chemical oxygen demand (COD) and dissolved metals from tropical landfill leachate
The use of nanoparticulate zero valent iron (NZVI) in the treatment of inorganic contaminants in landfill leachate and polluted plumes has been the subject of many studies, especially in temperate, developed countries. However, NZVI’s potential for reduction of chemical oxygen demand (COD) and treat...
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| Veröffentlicht in: | Environmental science and pollution research international 2014, Vol.21 (11), p.7075-7087 |
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| creator | Wijesekara, S. S. R. M. D. H. R Basnayake, B. F. A Vithanage, Meththika |
| description | The use of nanoparticulate zero valent iron (NZVI) in the treatment of inorganic contaminants in landfill leachate and polluted plumes has been the subject of many studies, especially in temperate, developed countries. However, NZVI’s potential for reduction of chemical oxygen demand (COD) and treatment of metal ion mixtures has not been explored in detail. We investigated the efficiency of NZVI synthesized in the presence of starch, mercaptoacetic, mercaptosuccinic, or mercaptopropenoic acid for the reduction of COD, nutrients, and metal ions from landfill leachate in tropical Sri Lanka. Synthesized NZVI were characterized with X-ray diffraction (XRD), transmission electron microscopy, X-ray photoelectron spectroscopy, scanning electron microscopy (SEM), thermal gravimetric analysis, Fourier transform infrared spectroscopy (FTIR) and Brunauer–Emmett–Teller. Of the samples tested, Starch-NZVI (S-NZVI) and mercaptoacetic-NZVI (MA-NZVI) performed well for treatment both COD and metal mixture. The removal percentages for COD, nitrate-nitrogen, and phosphate from S-NZVI were 50, 88, and 99 %, respectively. Heavy metal removal was higher in S-NZVI (>95 %) than others. MA-NZVI, its oxidation products, and functional groups of its coating showed the maximum removal amounts for both Cu (56.27 mg g⁻¹) and Zn (28.38 mg g⁻¹). All mercapto-NZVI showed well-stabilized nature under FTIR and XRD investigations. Therefore, we suggest mercapto acids as better agents to enhance the air stability for NZVI since chemically bonded thiol and carbonyl groups actively participation for stabilization process. |
| doi_str_mv | 10.1007/s11356-014-2625-1 |
| format | Article |
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S. R. M. D. H. R ; Basnayake, B. F. A ; Vithanage, Meththika</creator><creatorcontrib>Wijesekara, S. S. R. M. D. H. R ; Basnayake, B. F. A ; Vithanage, Meththika</creatorcontrib><description>The use of nanoparticulate zero valent iron (NZVI) in the treatment of inorganic contaminants in landfill leachate and polluted plumes has been the subject of many studies, especially in temperate, developed countries. However, NZVI’s potential for reduction of chemical oxygen demand (COD) and treatment of metal ion mixtures has not been explored in detail. We investigated the efficiency of NZVI synthesized in the presence of starch, mercaptoacetic, mercaptosuccinic, or mercaptopropenoic acid for the reduction of COD, nutrients, and metal ions from landfill leachate in tropical Sri Lanka. Synthesized NZVI were characterized with X-ray diffraction (XRD), transmission electron microscopy, X-ray photoelectron spectroscopy, scanning electron microscopy (SEM), thermal gravimetric analysis, Fourier transform infrared spectroscopy (FTIR) and Brunauer–Emmett–Teller. Of the samples tested, Starch-NZVI (S-NZVI) and mercaptoacetic-NZVI (MA-NZVI) performed well for treatment both COD and metal mixture. The removal percentages for COD, nitrate-nitrogen, and phosphate from S-NZVI were 50, 88, and 99 %, respectively. Heavy metal removal was higher in S-NZVI (>95 %) than others. MA-NZVI, its oxidation products, and functional groups of its coating showed the maximum removal amounts for both Cu (56.27 mg g⁻¹) and Zn (28.38 mg g⁻¹). All mercapto-NZVI showed well-stabilized nature under FTIR and XRD investigations. Therefore, we suggest mercapto acids as better agents to enhance the air stability for NZVI since chemically bonded thiol and carbonyl groups actively participation for stabilization process.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-014-2625-1</identifier><identifier>PMID: 24535668</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Acids ; air ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Biological Oxygen Demand Analysis ; Carbonyl compounds ; Cellulose acetate ; Chemical oxygen demand ; coatings ; Contaminants ; Contamination ; copper ; Developed countries ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental cleanup ; Environmental Health ; Environmental Restoration and Remediation - methods ; Environmental science ; Environmental studies ; Experiments ; Fourier analysis ; Fourier transform infrared spectroscopy ; Fourier transforms ; Gravimetric analysis ; Heavy metals ; Hydrocarbons ; Infrared spectroscopy ; Investigations ; iron ; Iron - chemistry ; Landfill ; Landfills ; Leachates ; Metal ions ; Metal Nanoparticles - chemistry ; Metals ; Metals, Heavy - analysis ; Microscopy ; Microscopy, Electron, Scanning ; Microscopy, Electron, Transmission ; Nanoparticles ; Nanostructure ; nitrate nitrogen ; Nitrates ; Nitrates - analysis ; nutrients ; Oxidation ; Oxidation-Reduction ; Oxygen demand ; Pesticides ; Phosphates - analysis ; Photoelectron Spectroscopy ; Plumes ; Pollutants ; Reduction ; remediation ; Research Article ; Scanning electron microscopy ; Spectrum analysis ; Sri Lanka ; Starch ; Thioglycolates ; Thiomalates ; Transmission electron microscopy ; Tropical Climate ; Waste disposal sites ; Waste Water Technology ; Water Management ; Water Pollutants, Chemical - chemistry ; Water Pollution Control ; X-Ray Diffraction ; X-ray photoelectron spectroscopy ; zinc</subject><ispartof>Environmental science and pollution research international, 2014, Vol.21 (11), p.7075-7087</ispartof><rights>Springer-Verlag Berlin Heidelberg 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c499t-4e3f62cc136d8b1ff6e9efb3cf0789ae7541dc007e04b9475c8fed0d467cda523</citedby><cites>FETCH-LOGICAL-c499t-4e3f62cc136d8b1ff6e9efb3cf0789ae7541dc007e04b9475c8fed0d467cda523</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-014-2625-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-014-2625-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24535668$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wijesekara, S. S. R. M. D. H. R</creatorcontrib><creatorcontrib>Basnayake, B. F. A</creatorcontrib><creatorcontrib>Vithanage, Meththika</creatorcontrib><title>Organic-coated nanoparticulate zero valent iron for remediation of chemical oxygen demand (COD) and dissolved metals from tropical landfill leachate</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>The use of nanoparticulate zero valent iron (NZVI) in the treatment of inorganic contaminants in landfill leachate and polluted plumes has been the subject of many studies, especially in temperate, developed countries. However, NZVI’s potential for reduction of chemical oxygen demand (COD) and treatment of metal ion mixtures has not been explored in detail. We investigated the efficiency of NZVI synthesized in the presence of starch, mercaptoacetic, mercaptosuccinic, or mercaptopropenoic acid for the reduction of COD, nutrients, and metal ions from landfill leachate in tropical Sri Lanka. Synthesized NZVI were characterized with X-ray diffraction (XRD), transmission electron microscopy, X-ray photoelectron spectroscopy, scanning electron microscopy (SEM), thermal gravimetric analysis, Fourier transform infrared spectroscopy (FTIR) and Brunauer–Emmett–Teller. Of the samples tested, Starch-NZVI (S-NZVI) and mercaptoacetic-NZVI (MA-NZVI) performed well for treatment both COD and metal mixture. The removal percentages for COD, nitrate-nitrogen, and phosphate from S-NZVI were 50, 88, and 99 %, respectively. Heavy metal removal was higher in S-NZVI (>95 %) than others. MA-NZVI, its oxidation products, and functional groups of its coating showed the maximum removal amounts for both Cu (56.27 mg g⁻¹) and Zn (28.38 mg g⁻¹). All mercapto-NZVI showed well-stabilized nature under FTIR and XRD investigations. Therefore, we suggest mercapto acids as better agents to enhance the air stability for NZVI since chemically bonded thiol and carbonyl groups actively participation for stabilization process.</description><subject>Acids</subject><subject>air</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Biological Oxygen Demand Analysis</subject><subject>Carbonyl compounds</subject><subject>Cellulose acetate</subject><subject>Chemical oxygen demand</subject><subject>coatings</subject><subject>Contaminants</subject><subject>Contamination</subject><subject>copper</subject><subject>Developed countries</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental cleanup</subject><subject>Environmental Health</subject><subject>Environmental Restoration and Remediation - methods</subject><subject>Environmental science</subject><subject>Environmental studies</subject><subject>Experiments</subject><subject>Fourier analysis</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Fourier transforms</subject><subject>Gravimetric analysis</subject><subject>Heavy metals</subject><subject>Hydrocarbons</subject><subject>Infrared spectroscopy</subject><subject>Investigations</subject><subject>iron</subject><subject>Iron - chemistry</subject><subject>Landfill</subject><subject>Landfills</subject><subject>Leachates</subject><subject>Metal ions</subject><subject>Metal Nanoparticles - chemistry</subject><subject>Metals</subject><subject>Metals, Heavy - analysis</subject><subject>Microscopy</subject><subject>Microscopy, Electron, Scanning</subject><subject>Microscopy, Electron, Transmission</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>nitrate nitrogen</subject><subject>Nitrates</subject><subject>Nitrates - analysis</subject><subject>nutrients</subject><subject>Oxidation</subject><subject>Oxidation-Reduction</subject><subject>Oxygen demand</subject><subject>Pesticides</subject><subject>Phosphates - analysis</subject><subject>Photoelectron Spectroscopy</subject><subject>Plumes</subject><subject>Pollutants</subject><subject>Reduction</subject><subject>remediation</subject><subject>Research Article</subject><subject>Scanning electron microscopy</subject><subject>Spectrum analysis</subject><subject>Sri Lanka</subject><subject>Starch</subject><subject>Thioglycolates</subject><subject>Thiomalates</subject><subject>Transmission electron microscopy</subject><subject>Tropical Climate</subject><subject>Waste disposal sites</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water Pollution Control</subject><subject>X-Ray Diffraction</subject><subject>X-ray photoelectron spectroscopy</subject><subject>zinc</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqFkc9u1DAQxi0EokvhAbiAJS7lEBg7Tpwcq-WvVGkP0LPltcdbV0m82NmK8hw8MLOkIMQBTh7bv-8bjz_Gngp4JQD06yJE3bQVCFXJVjaVuMdWoqWdVn1_n62gV6oStVIn7FEp1wASeqkfshOpGhK23Yp93-SdnaKrXLIzej7ZKe1tnqM7DHTAv2FO_MYOOM085jTxkDLPOKKPdo60T4G7KxyjswNPX293OHGPo508P1tv3rzkx8rHUtJwQ_YjznYoPOQ08jmn_U_ZQEyIAxVo3RV1fcweBMLwyd16yi7fvf28_lBdbN5_XJ9fVI7mmyuFdWilc6JufbcVIbTYY9jWLoDueou6UcI7-igEte2VblwX0INXrXbeNrI-ZWeL7z6nLwcssxljcTjQgzAdihFaQy2lBP1_tKlVp2oNHaEv_kKv0yFPNAhRstG6AwVEiYVyOZWSMZh9jqPNt0aAOaZrlnQNpWuO6RpBmmd3zoctJfBb8StOAuQCFLqadpj_aP0P1-eLKNhk7C7HYi4_SQIABNBUXf0DIwG6cg</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Wijesekara, S. 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S. R. M. D. H. R ; Basnayake, B. F. A ; Vithanage, Meththika</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c499t-4e3f62cc136d8b1ff6e9efb3cf0789ae7541dc007e04b9475c8fed0d467cda523</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Acids</topic><topic>air</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Biological Oxygen Demand Analysis</topic><topic>Carbonyl compounds</topic><topic>Cellulose acetate</topic><topic>Chemical oxygen demand</topic><topic>coatings</topic><topic>Contaminants</topic><topic>Contamination</topic><topic>copper</topic><topic>Developed countries</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental cleanup</topic><topic>Environmental Health</topic><topic>Environmental Restoration and Remediation - methods</topic><topic>Environmental science</topic><topic>Environmental studies</topic><topic>Experiments</topic><topic>Fourier analysis</topic><topic>Fourier transform infrared spectroscopy</topic><topic>Fourier transforms</topic><topic>Gravimetric analysis</topic><topic>Heavy metals</topic><topic>Hydrocarbons</topic><topic>Infrared spectroscopy</topic><topic>Investigations</topic><topic>iron</topic><topic>Iron - chemistry</topic><topic>Landfill</topic><topic>Landfills</topic><topic>Leachates</topic><topic>Metal ions</topic><topic>Metal Nanoparticles - chemistry</topic><topic>Metals</topic><topic>Metals, Heavy - analysis</topic><topic>Microscopy</topic><topic>Microscopy, Electron, Scanning</topic><topic>Microscopy, Electron, Transmission</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>nitrate nitrogen</topic><topic>Nitrates</topic><topic>Nitrates - analysis</topic><topic>nutrients</topic><topic>Oxidation</topic><topic>Oxidation-Reduction</topic><topic>Oxygen demand</topic><topic>Pesticides</topic><topic>Phosphates - analysis</topic><topic>Photoelectron Spectroscopy</topic><topic>Plumes</topic><topic>Pollutants</topic><topic>Reduction</topic><topic>remediation</topic><topic>Research Article</topic><topic>Scanning electron microscopy</topic><topic>Spectrum analysis</topic><topic>Sri Lanka</topic><topic>Starch</topic><topic>Thioglycolates</topic><topic>Thiomalates</topic><topic>Transmission electron microscopy</topic><topic>Tropical Climate</topic><topic>Waste disposal sites</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollutants, Chemical - chemistry</topic><topic>Water Pollution Control</topic><topic>X-Ray Diffraction</topic><topic>X-ray photoelectron spectroscopy</topic><topic>zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wijesekara, S. 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S. R. M. D. H. R</au><au>Basnayake, B. F. A</au><au>Vithanage, Meththika</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Organic-coated nanoparticulate zero valent iron for remediation of chemical oxygen demand (COD) and dissolved metals from tropical landfill leachate</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2014</date><risdate>2014</risdate><volume>21</volume><issue>11</issue><spage>7075</spage><epage>7087</epage><pages>7075-7087</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>The use of nanoparticulate zero valent iron (NZVI) in the treatment of inorganic contaminants in landfill leachate and polluted plumes has been the subject of many studies, especially in temperate, developed countries. However, NZVI’s potential for reduction of chemical oxygen demand (COD) and treatment of metal ion mixtures has not been explored in detail. We investigated the efficiency of NZVI synthesized in the presence of starch, mercaptoacetic, mercaptosuccinic, or mercaptopropenoic acid for the reduction of COD, nutrients, and metal ions from landfill leachate in tropical Sri Lanka. Synthesized NZVI were characterized with X-ray diffraction (XRD), transmission electron microscopy, X-ray photoelectron spectroscopy, scanning electron microscopy (SEM), thermal gravimetric analysis, Fourier transform infrared spectroscopy (FTIR) and Brunauer–Emmett–Teller. Of the samples tested, Starch-NZVI (S-NZVI) and mercaptoacetic-NZVI (MA-NZVI) performed well for treatment both COD and metal mixture. The removal percentages for COD, nitrate-nitrogen, and phosphate from S-NZVI were 50, 88, and 99 %, respectively. Heavy metal removal was higher in S-NZVI (>95 %) than others. MA-NZVI, its oxidation products, and functional groups of its coating showed the maximum removal amounts for both Cu (56.27 mg g⁻¹) and Zn (28.38 mg g⁻¹). All mercapto-NZVI showed well-stabilized nature under FTIR and XRD investigations. Therefore, we suggest mercapto acids as better agents to enhance the air stability for NZVI since chemically bonded thiol and carbonyl groups actively participation for stabilization process.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><pmid>24535668</pmid><doi>10.1007/s11356-014-2625-1</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0944-1344 |
| ispartof | Environmental science and pollution research international, 2014, Vol.21 (11), p.7075-7087 |
| issn | 0944-1344 1614-7499 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1770322207 |
| source | MEDLINE; SpringerLink Journals - AutoHoldings |
| subjects | Acids air Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Biological Oxygen Demand Analysis Carbonyl compounds Cellulose acetate Chemical oxygen demand coatings Contaminants Contamination copper Developed countries Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental cleanup Environmental Health Environmental Restoration and Remediation - methods Environmental science Environmental studies Experiments Fourier analysis Fourier transform infrared spectroscopy Fourier transforms Gravimetric analysis Heavy metals Hydrocarbons Infrared spectroscopy Investigations iron Iron - chemistry Landfill Landfills Leachates Metal ions Metal Nanoparticles - chemistry Metals Metals, Heavy - analysis Microscopy Microscopy, Electron, Scanning Microscopy, Electron, Transmission Nanoparticles Nanostructure nitrate nitrogen Nitrates Nitrates - analysis nutrients Oxidation Oxidation-Reduction Oxygen demand Pesticides Phosphates - analysis Photoelectron Spectroscopy Plumes Pollutants Reduction remediation Research Article Scanning electron microscopy Spectrum analysis Sri Lanka Starch Thioglycolates Thiomalates Transmission electron microscopy Tropical Climate Waste disposal sites Waste Water Technology Water Management Water Pollutants, Chemical - chemistry Water Pollution Control X-Ray Diffraction X-ray photoelectron spectroscopy zinc |
| title | Organic-coated nanoparticulate zero valent iron for remediation of chemical oxygen demand (COD) and dissolved metals from tropical landfill leachate |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T09%3A53%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Organic-coated%20nanoparticulate%20zero%20valent%20iron%20for%20remediation%20of%20chemical%20oxygen%20demand%20(COD)%20and%20dissolved%20metals%20from%20tropical%20landfill%20leachate&rft.jtitle=Environmental%20science%20and%20pollution%20research%20international&rft.au=Wijesekara,%20S.%20S.%20R.%20M.%20D.%20H.%20R&rft.date=2014&rft.volume=21&rft.issue=11&rft.spage=7075&rft.epage=7087&rft.pages=7075-7087&rft.issn=0944-1344&rft.eissn=1614-7499&rft_id=info:doi/10.1007/s11356-014-2625-1&rft_dat=%3Cproquest_cross%3E1770322207%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1525778040&rft_id=info:pmid/24535668&rfr_iscdi=true |