The Mössbauer study of atmospheric iron-containing aerosol in the coarse and PM2.5 fractions measured in rural site
•Mössbauer spectroscopy used to study of aerosol in PM2.5 and coarse fraction.•Monomer and polymeric aquated iron species observed in the Mössbauer spectra.•Superparamagnetic behavior of iron-containing atmospheric aerosol.•Ultra fine hematite particles were observed mostly in PM2.5 fraction. The si...
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| Veröffentlicht in: | Chemosphere (Oxford) 2015-07, Vol.131, p.9-16 |
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| creator | Kopcewicz, Barbara Kopcewicz, Michał Pietruczuk, Aleksander |
| description | •Mössbauer spectroscopy used to study of aerosol in PM2.5 and coarse fraction.•Monomer and polymeric aquated iron species observed in the Mössbauer spectra.•Superparamagnetic behavior of iron-containing atmospheric aerosol.•Ultra fine hematite particles were observed mostly in PM2.5 fraction.
The size-resolved iron-containing atmospheric aerosol was measured by Mössbauer spectroscopy. The particulate matter (PM) was size-segregated into aerosol 2.5μm (coarse fraction).
The Mössbauer spectra at room temperature show components assigned to mono- and polymeric species which are products related to hydrolysis of ferric solutions in the atmosphere. In order to extract reliable information regarding the quadrupole splittings necessary for identification of iron-containing compounds, the histogram method was used for evaluation of the Mössbauer spectra. The value and distribution of quadrupole splitting (QS) parameters obtained by this method suggests that the ultra fine particles ( |
| doi_str_mv | 10.1016/j.chemosphere.2015.02.038 |
| format | Article |
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The size-resolved iron-containing atmospheric aerosol was measured by Mössbauer spectroscopy. The particulate matter (PM) was size-segregated into aerosol <2.5μm in diameter (fine fraction, PM2.5) and aerosol >2.5μm (coarse fraction).
The Mössbauer spectra at room temperature show components assigned to mono- and polymeric species which are products related to hydrolysis of ferric solutions in the atmosphere. In order to extract reliable information regarding the quadrupole splittings necessary for identification of iron-containing compounds, the histogram method was used for evaluation of the Mössbauer spectra. The value and distribution of quadrupole splitting (QS) parameters obtained by this method suggests that the ultra fine particles (<10nm) identified as a ferrihydrite, hematite and goethite were observed in the spectra both in fine and coarse fraction of the collected aerosol. However, the content of the individual chemical components was different for each fraction. The least crystalline form of ferrihydrite (QS≅0.85mm) was observed in PM2.5 fraction more frequently than in the coarse fraction. The content of the ultra fine hematite particles which presence was confirmed in low temperature measurements was also larger in PM2.5 fraction than in the coarse fraction. Superparamagnetic behavior of iron-containing atmospheric aerosol was observed in low temperature Mössbauer spectra.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/j.chemosphere.2015.02.038</identifier><identifier>PMID: 25765259</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>Aerosols ; Air Pollutants - analysis ; Air Pollutants - chemistry ; Atmospheric iron ; Atmospherics ; Crystal structure ; Environmental Monitoring - instrumentation ; Environmental Monitoring - methods ; Ferric Compounds - analysis ; Ferric Compounds - chemistry ; Hematite ; Iron - analysis ; Iron - chemistry ; Mossbauer effect ; Mössbauer spectroscopy ; Particle Size ; Particulate Matter - analysis ; Particulate Matter - chemistry ; Poland ; Quadrupoles ; Spectra ; Spectroscopy, Mossbauer ; Splitting ; Superparamagnetic particles ; Temperature ; Ultra fine particles</subject><ispartof>Chemosphere (Oxford), 2015-07, Vol.131, p.9-16</ispartof><rights>2015 Elsevier Ltd</rights><rights>Copyright © 2015 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c509t-93f09cd1bd00f0ded1d48f0f63dbb1df34a125086594f695a6f90d348a33f44d3</citedby><cites>FETCH-LOGICAL-c509t-93f09cd1bd00f0ded1d48f0f63dbb1df34a125086594f695a6f90d348a33f44d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.chemosphere.2015.02.038$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25765259$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kopcewicz, Barbara</creatorcontrib><creatorcontrib>Kopcewicz, Michał</creatorcontrib><creatorcontrib>Pietruczuk, Aleksander</creatorcontrib><title>The Mössbauer study of atmospheric iron-containing aerosol in the coarse and PM2.5 fractions measured in rural site</title><title>Chemosphere (Oxford)</title><addtitle>Chemosphere</addtitle><description>•Mössbauer spectroscopy used to study of aerosol in PM2.5 and coarse fraction.•Monomer and polymeric aquated iron species observed in the Mössbauer spectra.•Superparamagnetic behavior of iron-containing atmospheric aerosol.•Ultra fine hematite particles were observed mostly in PM2.5 fraction.
The size-resolved iron-containing atmospheric aerosol was measured by Mössbauer spectroscopy. The particulate matter (PM) was size-segregated into aerosol <2.5μm in diameter (fine fraction, PM2.5) and aerosol >2.5μm (coarse fraction).
The Mössbauer spectra at room temperature show components assigned to mono- and polymeric species which are products related to hydrolysis of ferric solutions in the atmosphere. In order to extract reliable information regarding the quadrupole splittings necessary for identification of iron-containing compounds, the histogram method was used for evaluation of the Mössbauer spectra. The value and distribution of quadrupole splitting (QS) parameters obtained by this method suggests that the ultra fine particles (<10nm) identified as a ferrihydrite, hematite and goethite were observed in the spectra both in fine and coarse fraction of the collected aerosol. However, the content of the individual chemical components was different for each fraction. The least crystalline form of ferrihydrite (QS≅0.85mm) was observed in PM2.5 fraction more frequently than in the coarse fraction. The content of the ultra fine hematite particles which presence was confirmed in low temperature measurements was also larger in PM2.5 fraction than in the coarse fraction. Superparamagnetic behavior of iron-containing atmospheric aerosol was observed in low temperature Mössbauer spectra.</description><subject>Aerosols</subject><subject>Air Pollutants - analysis</subject><subject>Air Pollutants - chemistry</subject><subject>Atmospheric iron</subject><subject>Atmospherics</subject><subject>Crystal structure</subject><subject>Environmental Monitoring - instrumentation</subject><subject>Environmental Monitoring - methods</subject><subject>Ferric Compounds - analysis</subject><subject>Ferric Compounds - chemistry</subject><subject>Hematite</subject><subject>Iron - analysis</subject><subject>Iron - chemistry</subject><subject>Mossbauer effect</subject><subject>Mössbauer spectroscopy</subject><subject>Particle Size</subject><subject>Particulate Matter - analysis</subject><subject>Particulate Matter - chemistry</subject><subject>Poland</subject><subject>Quadrupoles</subject><subject>Spectra</subject><subject>Spectroscopy, Mossbauer</subject><subject>Splitting</subject><subject>Superparamagnetic particles</subject><subject>Temperature</subject><subject>Ultra fine particles</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkc9u1DAQhy1ERZeWV0DmxiVhbMdJfEQr_kmt6KE9W449Zr1K4sV2kPpivAAvRla7IG70NJfvNz_NfIS8YVAzYO27fW13OMV82GHCmgOTNfAaRP-MbFjfqYpx1T8nG4BGVq0U8pK8zHkPsIalekEuuexayaXakHK_Q3r762fOg1kw0VwW90ijp6acC4KlIcW5snEuJsxh_kYNppjjSMNMyxq30aSM1MyO3t3yWlKfjC0hzplOaPKS0B3RtCQz0hwKXpMLb8aMr87zijx8_HC__VzdfP30Zfv-prISVKmU8KCsY4MD8ODQMdf0Hnwr3DAw50VjGJfQrzc1vlXStF6BE01vhPBN48QVeXvae0jx-4K56Clki-NoZoxL1qzrQDCpWvYEVPCeSybF_9G260TXdz2sqDqhdn1YTuj1IYXJpEfNQB9V6r3-R6U-qtTA9apyzb4-1yzDhO5v8o-7FdieAFxf-CNg0tkGnC26kNAW7WJ4Qs1vI1-2yQ</recordid><startdate>201507</startdate><enddate>201507</enddate><creator>Kopcewicz, Barbara</creator><creator>Kopcewicz, Michał</creator><creator>Pietruczuk, Aleksander</creator><general>Elsevier Ltd</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7TG</scope><scope>7TV</scope><scope>C1K</scope><scope>KL.</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>201507</creationdate><title>The Mössbauer study of atmospheric iron-containing aerosol in the coarse and PM2.5 fractions measured in rural site</title><author>Kopcewicz, Barbara ; Kopcewicz, Michał ; Pietruczuk, Aleksander</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c509t-93f09cd1bd00f0ded1d48f0f63dbb1df34a125086594f695a6f90d348a33f44d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Aerosols</topic><topic>Air Pollutants - analysis</topic><topic>Air Pollutants - chemistry</topic><topic>Atmospheric iron</topic><topic>Atmospherics</topic><topic>Crystal structure</topic><topic>Environmental Monitoring - instrumentation</topic><topic>Environmental Monitoring - methods</topic><topic>Ferric Compounds - analysis</topic><topic>Ferric Compounds - chemistry</topic><topic>Hematite</topic><topic>Iron - analysis</topic><topic>Iron - chemistry</topic><topic>Mossbauer effect</topic><topic>Mössbauer spectroscopy</topic><topic>Particle Size</topic><topic>Particulate Matter - analysis</topic><topic>Particulate Matter - chemistry</topic><topic>Poland</topic><topic>Quadrupoles</topic><topic>Spectra</topic><topic>Spectroscopy, Mossbauer</topic><topic>Splitting</topic><topic>Superparamagnetic particles</topic><topic>Temperature</topic><topic>Ultra fine particles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kopcewicz, Barbara</creatorcontrib><creatorcontrib>Kopcewicz, Michał</creatorcontrib><creatorcontrib>Pietruczuk, Aleksander</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Pollution Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kopcewicz, Barbara</au><au>Kopcewicz, Michał</au><au>Pietruczuk, Aleksander</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Mössbauer study of atmospheric iron-containing aerosol in the coarse and PM2.5 fractions measured in rural site</atitle><jtitle>Chemosphere (Oxford)</jtitle><addtitle>Chemosphere</addtitle><date>2015-07</date><risdate>2015</risdate><volume>131</volume><spage>9</spage><epage>16</epage><pages>9-16</pages><issn>0045-6535</issn><eissn>1879-1298</eissn><abstract>•Mössbauer spectroscopy used to study of aerosol in PM2.5 and coarse fraction.•Monomer and polymeric aquated iron species observed in the Mössbauer spectra.•Superparamagnetic behavior of iron-containing atmospheric aerosol.•Ultra fine hematite particles were observed mostly in PM2.5 fraction.
The size-resolved iron-containing atmospheric aerosol was measured by Mössbauer spectroscopy. The particulate matter (PM) was size-segregated into aerosol <2.5μm in diameter (fine fraction, PM2.5) and aerosol >2.5μm (coarse fraction).
The Mössbauer spectra at room temperature show components assigned to mono- and polymeric species which are products related to hydrolysis of ferric solutions in the atmosphere. In order to extract reliable information regarding the quadrupole splittings necessary for identification of iron-containing compounds, the histogram method was used for evaluation of the Mössbauer spectra. The value and distribution of quadrupole splitting (QS) parameters obtained by this method suggests that the ultra fine particles (<10nm) identified as a ferrihydrite, hematite and goethite were observed in the spectra both in fine and coarse fraction of the collected aerosol. However, the content of the individual chemical components was different for each fraction. The least crystalline form of ferrihydrite (QS≅0.85mm) was observed in PM2.5 fraction more frequently than in the coarse fraction. The content of the ultra fine hematite particles which presence was confirmed in low temperature measurements was also larger in PM2.5 fraction than in the coarse fraction. Superparamagnetic behavior of iron-containing atmospheric aerosol was observed in low temperature Mössbauer spectra.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>25765259</pmid><doi>10.1016/j.chemosphere.2015.02.038</doi><tpages>8</tpages></addata></record> |
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| subjects | Aerosols Air Pollutants - analysis Air Pollutants - chemistry Atmospheric iron Atmospherics Crystal structure Environmental Monitoring - instrumentation Environmental Monitoring - methods Ferric Compounds - analysis Ferric Compounds - chemistry Hematite Iron - analysis Iron - chemistry Mossbauer effect Mössbauer spectroscopy Particle Size Particulate Matter - analysis Particulate Matter - chemistry Poland Quadrupoles Spectra Spectroscopy, Mossbauer Splitting Superparamagnetic particles Temperature Ultra fine particles |
| title | The Mössbauer study of atmospheric iron-containing aerosol in the coarse and PM2.5 fractions measured in rural site |
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