Highly ordered alignment of conducting nano-crystallites on organic semiconductor single crystal surfaces
A conducting thin layer of aligned fibrous nano-crystallites of tetrathiafulvalene–7,7,8,8,-tetracyanoquinodimethane (TTF–TCNQ) is fabricated directly on semiconducting organic crystals under ambient conditions. The widths of the crystallites are 50–100nm. Their growth direction is governed by the d...
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| Veröffentlicht in: | Thin solid films 2015-03, Vol.579, p.38-43 |
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| container_title | Thin solid films |
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| creator | Mikasa, Tomohiro Takahasｈi, Yukihiro Hayakawa, Kei Yokokura, Seiya Hasegawa, Hiroyuki Harada, Jun Inabe, Tamotsu |
| description | A conducting thin layer of aligned fibrous nano-crystallites of tetrathiafulvalene–7,7,8,8,-tetracyanoquinodimethane (TTF–TCNQ) is fabricated directly on semiconducting organic crystals under ambient conditions. The widths of the crystallites are 50–100nm. Their growth direction is governed by the direction of the intermolecular charge transfer interactions in the substrate crystal. The carrier transport in the film is metallic between 150K and 300K, reflecting the uniform alignment of the TTF–TCNQ nano-crystallites on the substrate crystal.
•Highly ordered tetrathiafulvalene–tetracyanoquinodimethane thin film is fabricated.•The film grows under ambient conditions.•The carrier transport in the film is metallic between 150K and 300K.•Crystal growth mechanism is investigated. |
| doi_str_mv | 10.1016/j.tsf.2015.02.034 |
| format | Article |
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•Highly ordered tetrathiafulvalene–tetracyanoquinodimethane thin film is fabricated.•The film grows under ambient conditions.•The carrier transport in the film is metallic between 150K and 300K.•Crystal growth mechanism is investigated.</description><subject>Alignment</subject><subject>Carrier transport</subject><subject>Conduction</subject><subject>Crystal surfaces</subject><subject>Crystallites</subject><subject>Crystals</subject><subject>Nano-crystallites</subject><subject>Nanocrystals</subject><subject>Organic crystals</subject><subject>Organic solids</subject><subject>Thin films</subject><subject>TTF–TCNQ</subject><issn>0040-6090</issn><issn>1879-2731</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kLFOwzAQQC0EEqXwAWweWRLunNROxIQqoEiVWGC2UudSXCV2sROk_j2u2pnplvdOd4-xe4QcAeXjLh9jlwvARQ4ih6K8YDOsVJ0JVeAlmwGUkEmo4ZrdxLgDABSimDG7stvv_sB9aClQy5vebt1AbuS-48a7djKjdVvuGuczEw5xbPrejhS5d0naNs4aHmmwZ9YHHhPfEz_DPE6hawzFW3bVNX2ku_Ocs6_Xl8_lKlt_vL0vn9eZKWo5ZmrTCkw3m7KSEusS243ARVcQ1VIJ3NRCqQoWMu0EVCpJHdZUSVUtStliUczZw2nvPvifieKoBxsN9X3jyE9RJwkKkKWUCcUTaoKPMVCn98EOTThoBH3Mqnc6ZdXHrBqETlmT83RyKP3waynoaCw5Q60NZEbdevuP_QdrAoE5</recordid><startdate>20150331</startdate><enddate>20150331</enddate><creator>Mikasa, Tomohiro</creator><creator>Takahasｈi, Yukihiro</creator><creator>Hayakawa, Kei</creator><creator>Yokokura, Seiya</creator><creator>Hasegawa, Hiroyuki</creator><creator>Harada, Jun</creator><creator>Inabe, Tamotsu</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-3252-9502</orcidid></search><sort><creationdate>20150331</creationdate><title>Highly ordered alignment of conducting nano-crystallites on organic semiconductor single crystal surfaces</title><author>Mikasa, Tomohiro ; Takahasｈi, Yukihiro ; Hayakawa, Kei ; Yokokura, Seiya ; Hasegawa, Hiroyuki ; Harada, Jun ; Inabe, Tamotsu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c396t-7bd21731c48661941db215f3ee96721b92778056fac0177c39f19e8678546d133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Alignment</topic><topic>Carrier transport</topic><topic>Conduction</topic><topic>Crystal surfaces</topic><topic>Crystallites</topic><topic>Crystals</topic><topic>Nano-crystallites</topic><topic>Nanocrystals</topic><topic>Organic crystals</topic><topic>Organic solids</topic><topic>Thin films</topic><topic>TTF–TCNQ</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mikasa, Tomohiro</creatorcontrib><creatorcontrib>Takahasｈi, Yukihiro</creatorcontrib><creatorcontrib>Hayakawa, Kei</creatorcontrib><creatorcontrib>Yokokura, Seiya</creatorcontrib><creatorcontrib>Hasegawa, Hiroyuki</creatorcontrib><creatorcontrib>Harada, Jun</creatorcontrib><creatorcontrib>Inabe, Tamotsu</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Thin solid films</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mikasa, Tomohiro</au><au>Takahasｈi, Yukihiro</au><au>Hayakawa, Kei</au><au>Yokokura, Seiya</au><au>Hasegawa, Hiroyuki</au><au>Harada, Jun</au><au>Inabe, Tamotsu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly ordered alignment of conducting nano-crystallites on organic semiconductor single crystal surfaces</atitle><jtitle>Thin solid films</jtitle><date>2015-03-31</date><risdate>2015</risdate><volume>579</volume><spage>38</spage><epage>43</epage><pages>38-43</pages><issn>0040-6090</issn><eissn>1879-2731</eissn><abstract>A conducting thin layer of aligned fibrous nano-crystallites of tetrathiafulvalene–7,7,8,8,-tetracyanoquinodimethane (TTF–TCNQ) is fabricated directly on semiconducting organic crystals under ambient conditions. The widths of the crystallites are 50–100nm. Their growth direction is governed by the direction of the intermolecular charge transfer interactions in the substrate crystal. The carrier transport in the film is metallic between 150K and 300K, reflecting the uniform alignment of the TTF–TCNQ nano-crystallites on the substrate crystal.
•Highly ordered tetrathiafulvalene–tetracyanoquinodimethane thin film is fabricated.•The film grows under ambient conditions.•The carrier transport in the film is metallic between 150K and 300K.•Crystal growth mechanism is investigated.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.tsf.2015.02.034</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-3252-9502</orcidid></addata></record> |
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| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Alignment Carrier transport Conduction Crystal surfaces Crystallites Crystals Nano-crystallites Nanocrystals Organic crystals Organic solids Thin films TTF–TCNQ |
| title | Highly ordered alignment of conducting nano-crystallites on organic semiconductor single crystal surfaces |
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