Description of intraparticle diffusional sorption and desorption processes in ion-exchange sorbents

All general effects of ion exchange kinetics can be considered within the framework of a nonlinear phenomenological diffusional model. According to the model, the dependence of intraparticle diffusivity D on the concentration of sorbed (desorbed) ion a is unknown beforehand and, in general, it shoul...

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Veröffentlicht in:Protection of metals and physical chemistry of surfaces 2015-11, Vol.51 (6), p.929-933
Hauptverfasser: Gruzdeva, A. N., Khamizov, R. Kh, Zolotarev, P. P.
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container_title Protection of metals and physical chemistry of surfaces
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creator Gruzdeva, A. N.
Khamizov, R. Kh
Zolotarev, P. P.
description All general effects of ion exchange kinetics can be considered within the framework of a nonlinear phenomenological diffusional model. According to the model, the dependence of intraparticle diffusivity D on the concentration of sorbed (desorbed) ion a is unknown beforehand and, in general, it should be determined from the experiments by solving the so-called inverse problem. Hence, the work considered some important features of this model relating to the sorption–desorption processes.
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subjects Characterization and Evaluation of Materials
Chemistry and Materials Science
Corrosion and Coatings
Desorption
Diffusion
Diffusivity
Industrial Chemistry/Chemical Engineering
Inorganic Chemistry
Inverse problems
Ion exchangers
Materials Science
Mathematical models
Metallic Materials
Physical chemistry
Physicochemical Processes at the Interfaces
Sorption
Tribology
title Description of intraparticle diffusional sorption and desorption processes in ion-exchange sorbents
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