Towards Structural-Functional Mimics of Acetylene Hydratase: Reversible Activation of Acetylene using a Biomimetic Tungsten Complex

The synthesis and characterization of a biomimetic system that can reversibly bind acetylene (ethyne) is reported. The system has been designed to mimic catalytic intermediates of the tungstoenzyme acetylene hydratase. The thiophenyloxazoline ligand S‐Phoz (2‐(4′,4′‐dimethyloxazolin‐2′‐yl)thiophenol...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-10, Vol.54 (44), p.13018-13021
Hauptverfasser:	Peschel, Lydia M., Belaj, Ferdinand, Mösch-Zanetti, Nadia C.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene Acetylene - chemistry Acetylene - metabolism acetylene hydratase Activation Adducts bioinorganic chemistry Biomimetic Materials - chemistry Biomimetic Materials - metabolism Biomimetics Coordination Complexes - chemistry Coordination Complexes - metabolism Hydro-Lyases - chemistry Hydro-Lyases - metabolism Intermediates Ligands Molecular Conformation S ligands small-molecule activation Stabilization Structure-function relationships Synthesis Tungsten Tungsten - chemistry Tungsten - metabolism
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