Halogen-Bond-Templated [2+2] Photodimerization in the Solid State: Directed Synthesis and Rare Self-Inclusion of a Halogenated Product

A ditopic halogen‐bond acceptor organizes a diiodooctafluorostilbene for a [2+2] photodimerization reaction to take place between two stilbene molecules in the solid state. The resultant cyclobutane product is functionalized with halogen atoms and undergoes self‐assembly to form a channel‐type host–...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-03, Vol.55 (10), p.3477-3480
Hauptverfasser:	Sinnwell, Michael A., MacGillivray, Leonard R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cyclobutane dimerization halocarbon compounds halogen bonding Halogenation molecular recognition Self-assembly Solid state Stilbene Supramolecular compounds
Online-Zugang:	Volltext
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