INFRARED STUDIES OF SUWANNEE RIVER HUMIC SUBSTANCES: EVIDENCE OF CHLORINATION OF HUMICS IN SALT WATER

Humic Substance (HS) samples were collected from twenty-five sites along the Suwannee River. These sites included the Okeefenokee Swamp, several springs and tributaries, and the delta where the river empties into the Gulf of Mexico. Fourier Transform Infrared Spectroscopy (FT-IR) is used to categori...

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Veröffentlicht in:Florida scientist 2003-01, Vol.66 (4), p.253-266
Hauptverfasser: Manning, Thomas, Strickland, Stacy, Feldman, Amy, Umberger, Tice, Lovingood, Derek, Coulibay, Mamadou, Elder, John, Noble, Lyn
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container_end_page 266
container_issue 4
container_start_page 253
container_title Florida scientist
container_volume 66
creator Manning, Thomas
Strickland, Stacy
Feldman, Amy
Umberger, Tice
Lovingood, Derek
Coulibay, Mamadou
Elder, John
Noble, Lyn
description Humic Substance (HS) samples were collected from twenty-five sites along the Suwannee River. These sites included the Okeefenokee Swamp, several springs and tributaries, and the delta where the river empties into the Gulf of Mexico. Fourier Transform Infrared Spectroscopy (FT-IR) is used to categorize the relative abundance of the functional groups of these samples. In salt-water samples we identified a relatively intense C-Cl vibration indicating the chlorination of the humic substance. We also measured the vibrational spectra of humic acid with several concentrations of HNO3, KOH and Na4P2O7 over twenty-eight days to optimize our extraction procedure by minimizing condensation reactions.
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subjects Acid soils
Chlorination
Forest soils
Freshwater
Functional groups
Infrared radiation
Infrared spectroscopy
Ketones
River water
Riverbanks
Spring water
title INFRARED STUDIES OF SUWANNEE RIVER HUMIC SUBSTANCES: EVIDENCE OF CHLORINATION OF HUMICS IN SALT WATER
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