Cyano Group Removal from Cyano-Promoted Aza-Diels-Alder Adducts: Synthesis and Structure-Activity Relationship of Phenanthroindolizidines and Phenanthroquinolizidines

Phenanthroindolizidines and phenanthroquinolizidines were concisely synthesized by the reductive decyanization of cyano-promoted intramolecular aza-Diels-Alder cycloadducts followed by aryl-aryl coupling. Cyano groups were removed from α-aminoacrylonitriles via treatment with sodium borohydride in 2...

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Veröffentlicht in:Organic letters 2016-02, Vol.18 (4), p.638-641
Hauptverfasser: Chang, Chi-Fen, Li, Chien-Fu, Tsai, Chia-Chen, Chuang, Ta-Hsien
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Sprache:eng
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