Rh(III)-Catalyzed Synthesis of N‑Unprotected Indoles from Imidamides and Diazo Ketoesters via C–H Activation and C–C/C–N Bond Cleavage

The synthesis of N-unprotected indoles has been realized via Rh­(III)-catalyzed C–H activation/annulation of imidamides with α-diazo β-ketoesters. The reaction occurs with the release of an amide coproduct, which originates from both the imidamide and the diazo as a result of CN cleavage of the imi...

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Veröffentlicht in:	Organic letters 2016-02, Vol.18 (4), p.700-703
Hauptverfasser:	Qi, Zisong, Yu, Songjie, Li, Xingwei
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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