Photoredox Mediated Nickel Catalyzed Cross-Coupling of Thiols With Aryl and Heteroaryl Iodides via Thiyl Radicals

Ni-catalyzed cross-couplings of aryl, benzyl, and alkyl thiols with aryl and heteroaryl iodides were accomplished in the presence of an Ir-photoredox catalyst. Highly chemoselective C–S cross-coupling was achieved versus competitive C–O and C–N cross-couplings. This C–S cross-coupling method exhibit...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-02, Vol.138 (6), p.1760-1763
Hauptverfasser:	Oderinde, Martins S, Frenette, Mathieu, Robbins, Daniel W, Aquila, Brian, Johannes, Jeffrey W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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