Development and validation of a GC/MS method for determination of phenolic xenoestrogens in aquatic samples
A simple and sensitive GC/MS method for the quantitative determination of the estrogenic phenolic compounds 4-nonylphenol, 4-t-octylphenol, bisphenol A, 3-t-butyl-4-hydroxyanisole, 2-t-butyl-4-methylphenol, 4-hydroxybiphenyl, 2-hydroxybiphenyl, 4-chloro-3-methylphenol, and 4-chloro-2-methylphenol in...
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| Veröffentlicht in: | Chemosphere (Oxford) 2000-05, Vol.40 (9-11), p.929-935 |
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| container_issue | 9-11 |
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| container_title | Chemosphere (Oxford) |
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| creator | BOLZ, U KÖRNER, W HAGENMAIER, H |
| description | A simple and sensitive GC/MS method for the quantitative determination of the estrogenic phenolic compounds 4-nonylphenol, 4-t-octylphenol, bisphenol A, 3-t-butyl-4-hydroxyanisole, 2-t-butyl-4-methylphenol, 4-hydroxybiphenyl, 2-hydroxybiphenyl, 4-chloro-3-methylphenol, and 4-chloro-2-methylphenol in aquatic samples was developed. The method for assessing their occurrence in sewage, surface and drinking waters consists of solid phase extraction (SPE) using a polystyrene copolymer phase. After methylation of the extract HRGC/LRMS analysis was possible without any clean up, even in raw sewage samples. Limits of detection and determination were between |
| doi_str_mv | 10.1016/s0045-6535(99)00335-5 |
| format | Article |
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The method for assessing their occurrence in sewage, surface and drinking waters consists of solid phase extraction (SPE) using a polystyrene copolymer phase. After methylation of the extract HRGC/LRMS analysis was possible without any clean up, even in raw sewage samples. Limits of detection and determination were between <0.01 and 0.05 ng/l and 0.01 and 0.05 ng/l, respectively. 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The method for assessing their occurrence in sewage, surface and drinking waters consists of solid phase extraction (SPE) using a polystyrene copolymer phase. After methylation of the extract HRGC/LRMS analysis was possible without any clean up, even in raw sewage samples. Limits of detection and determination were between <0.01 and 0.05 ng/l and 0.01 and 0.05 ng/l, respectively. 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| source | MEDLINE; ScienceDirect Journals (5 years ago - present) |
| subjects | Analysis methods Applied sciences estrogens Estrogens - analysis Exact sciences and technology Gas Chromatography-Mass Spectrometry - methods Natural water pollution Phenols - analysis Pollution Sensitivity and Specificity Sewage - analysis Water - chemistry Water treatment and pollution Xenobiotics - analysis |
| title | Development and validation of a GC/MS method for determination of phenolic xenoestrogens in aquatic samples |
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