Probing Stereoselectivity in Ring-Opening Metathesis Polymerization Mediated by Cyclometalated Ruthenium-Based Catalysts: A Combined Experimental and Computational Study

The microstructures of polymers produced by ring-opening metathesis polymerization (ROMP) with cyclometalated Ru-carbene metathesis catalysts were investigated. A strong bias for a cis,syndiotactic microstructure with minimal head-to-tail bias was observed. In instances where trans errors were intro...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-02, Vol.138 (4), p.1394-1405
Hauptverfasser:	Rosebrugh, L. E, Ahmed, T. S, Marx, V. M, Hartung, J, Liu, P, López, J. G, Houk, K. N, Grubbs, R. H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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