Polycyclic aromatic hydrocarbon adsorption on selected solid particulate matter fractions
This article is directed to evaluating the proportion of polycyclic aromatic hydrocarbons (PAHs) captured on particulate matter (PM) classified as PM2.5–10 and PM2.5, i.e. particulate matter of aerodynamic diameter 2.5–10 μm and 2.5 μm. During three week-long and one 2-day campaigns, 22 paired air s...
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Veröffentlicht in: | Atmospheric environment (1994) 2016-02, Vol.126, p.128-135 |
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container_title | Atmospheric environment (1994) |
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creator | Bozek, Frantisek Huzlik, Jiri Pawelczyk, Adam Hoza, Ignac Naplavova, Magdalena Jedlicka, Jiri |
description | This article is directed to evaluating the proportion of polycyclic aromatic hydrocarbons (PAHs) captured on particulate matter (PM) classified as PM2.5–10 and PM2.5, i.e. particulate matter of aerodynamic diameter 2.5–10 μm and 2.5 μm. During three week-long and one 2-day campaigns, 22 paired air samples were taken in parallel of PM10 and PM2.5 fractions inside the Mrázovka tunnel in Prague, Czech Republic. Following sample preparation, concentrations of individual PAHs were determined using gas chromatography combined with mass spectrometry. Concentrations of individual pairs of each PAH were tested by the nonparametric method using Spearman's rank correlation coefficient. At significance level p |
doi_str_mv | 10.1016/j.atmosenv.2015.11.018 |
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•We measured the concentrations of polycyclic aromatic hydrocarbons (PAHs).•The concentrations were measured on the particulate matter (PM10, PM2.5).•For determination of PAHs distribution on PM was used statistical Spearman's test.•It was found that almost all PAHs determined are to be found on PM2.5.</description><identifier>ISSN: 1352-2310</identifier><identifier>EISSN: 1873-2844</identifier><identifier>DOI: 10.1016/j.atmosenv.2015.11.018</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Concentration distribution ; Gas chromatography ; Mass spectrometry ; Particulate matter ; Polycyclic aromatic hydrocarbons ; Spearman's statistical method</subject><ispartof>Atmospheric environment (1994), 2016-02, Vol.126, p.128-135</ispartof><rights>2015 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c411t-e775e9f002bb09c351f69fb6a9b31877d7087adcfe9d260066929c78e76e1ad83</citedby><cites>FETCH-LOGICAL-c411t-e775e9f002bb09c351f69fb6a9b31877d7087adcfe9d260066929c78e76e1ad83</cites><orcidid>0000-0002-5025-6122</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.atmosenv.2015.11.018$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Bozek, Frantisek</creatorcontrib><creatorcontrib>Huzlik, Jiri</creatorcontrib><creatorcontrib>Pawelczyk, Adam</creatorcontrib><creatorcontrib>Hoza, Ignac</creatorcontrib><creatorcontrib>Naplavova, Magdalena</creatorcontrib><creatorcontrib>Jedlicka, Jiri</creatorcontrib><title>Polycyclic aromatic hydrocarbon adsorption on selected solid particulate matter fractions</title><title>Atmospheric environment (1994)</title><description>This article is directed to evaluating the proportion of polycyclic aromatic hydrocarbons (PAHs) captured on particulate matter (PM) classified as PM2.5–10 and PM2.5, i.e. particulate matter of aerodynamic diameter 2.5–10 μm and 2.5 μm. During three week-long and one 2-day campaigns, 22 paired air samples were taken in parallel of PM10 and PM2.5 fractions inside the Mrázovka tunnel in Prague, Czech Republic. Following sample preparation, concentrations of individual PAHs were determined using gas chromatography combined with mass spectrometry. Concentrations of individual pairs of each PAH were tested by the nonparametric method using Spearman's rank correlation coefficient. At significance level p < 0.01, it was demonstrated that all individual PAHs, including their totals, were bound to the PM2.5 fraction. Exceptions were seen in the cases of acenaphthylene, acenaphthene, and indeno[1,2,3-cd]pyrene, the concentrations of which fluctuated around the detection limit, where increased measurement error can be expected.
•We measured the concentrations of polycyclic aromatic hydrocarbons (PAHs).•The concentrations were measured on the particulate matter (PM10, PM2.5).•For determination of PAHs distribution on PM was used statistical Spearman's test.•It was found that almost all PAHs determined are to be found on PM2.5.</description><subject>Concentration distribution</subject><subject>Gas chromatography</subject><subject>Mass spectrometry</subject><subject>Particulate matter</subject><subject>Polycyclic aromatic hydrocarbons</subject><subject>Spearman's statistical method</subject><issn>1352-2310</issn><issn>1873-2844</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LxDAUxIsouK5-BenRS2te0ibtTVn8Bwt60IOnkCavmCVtatJd2G9vltWz8ODNYWZgfll2DaQEAvx2U6p58BHHXUkJ1CVASaA5yRbQCFbQpqpOk2Y1LSgDcp5dxLghhDDRikX2-ebdXu-1szpXwQ9qTuJrb4LXKnR-zJWJPkyzTTJdRId6RpNH76zJJxWSf-vUjHmKzhjyPih9cMfL7KxXLuLV719mH48P76vnYv369LK6Xxe6ApgLFKLGtieEdh1pNauh523fcdV2LA0QRpBGKKN7bA3lhHDe0laLBgVHUKZhy-zm2DsF_73FOMvBRo3OqRH9NkoQnDJBaMWTlR-tOvgYA_ZyCnZQYS-ByANLuZF_LOWBpQSQiWUK3h2DmIbsLAYZtcVRo7Eh8ZDG2_8qfgASGoMR</recordid><startdate>201602</startdate><enddate>201602</enddate><creator>Bozek, Frantisek</creator><creator>Huzlik, Jiri</creator><creator>Pawelczyk, Adam</creator><creator>Hoza, Ignac</creator><creator>Naplavova, Magdalena</creator><creator>Jedlicka, Jiri</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>7TG</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H96</scope><scope>KL.</scope><scope>L.G</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0002-5025-6122</orcidid></search><sort><creationdate>201602</creationdate><title>Polycyclic aromatic hydrocarbon adsorption on selected solid particulate matter fractions</title><author>Bozek, Frantisek ; Huzlik, Jiri ; Pawelczyk, Adam ; Hoza, Ignac ; Naplavova, Magdalena ; Jedlicka, Jiri</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c411t-e775e9f002bb09c351f69fb6a9b31877d7087adcfe9d260066929c78e76e1ad83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Concentration distribution</topic><topic>Gas chromatography</topic><topic>Mass spectrometry</topic><topic>Particulate matter</topic><topic>Polycyclic aromatic hydrocarbons</topic><topic>Spearman's statistical method</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bozek, Frantisek</creatorcontrib><creatorcontrib>Huzlik, Jiri</creatorcontrib><creatorcontrib>Pawelczyk, Adam</creatorcontrib><creatorcontrib>Hoza, Ignac</creatorcontrib><creatorcontrib>Naplavova, Magdalena</creatorcontrib><creatorcontrib>Jedlicka, Jiri</creatorcontrib><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Environment Abstracts</collection><jtitle>Atmospheric environment (1994)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bozek, Frantisek</au><au>Huzlik, Jiri</au><au>Pawelczyk, Adam</au><au>Hoza, Ignac</au><au>Naplavova, Magdalena</au><au>Jedlicka, Jiri</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polycyclic aromatic hydrocarbon adsorption on selected solid particulate matter fractions</atitle><jtitle>Atmospheric environment (1994)</jtitle><date>2016-02</date><risdate>2016</risdate><volume>126</volume><spage>128</spage><epage>135</epage><pages>128-135</pages><issn>1352-2310</issn><eissn>1873-2844</eissn><abstract>This article is directed to evaluating the proportion of polycyclic aromatic hydrocarbons (PAHs) captured on particulate matter (PM) classified as PM2.5–10 and PM2.5, i.e. particulate matter of aerodynamic diameter 2.5–10 μm and 2.5 μm. During three week-long and one 2-day campaigns, 22 paired air samples were taken in parallel of PM10 and PM2.5 fractions inside the Mrázovka tunnel in Prague, Czech Republic. Following sample preparation, concentrations of individual PAHs were determined using gas chromatography combined with mass spectrometry. Concentrations of individual pairs of each PAH were tested by the nonparametric method using Spearman's rank correlation coefficient. At significance level p < 0.01, it was demonstrated that all individual PAHs, including their totals, were bound to the PM2.5 fraction. Exceptions were seen in the cases of acenaphthylene, acenaphthene, and indeno[1,2,3-cd]pyrene, the concentrations of which fluctuated around the detection limit, where increased measurement error can be expected.
•We measured the concentrations of polycyclic aromatic hydrocarbons (PAHs).•The concentrations were measured on the particulate matter (PM10, PM2.5).•For determination of PAHs distribution on PM was used statistical Spearman's test.•It was found that almost all PAHs determined are to be found on PM2.5.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.atmosenv.2015.11.018</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-5025-6122</orcidid></addata></record> |
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subjects | Concentration distribution Gas chromatography Mass spectrometry Particulate matter Polycyclic aromatic hydrocarbons Spearman's statistical method |
title | Polycyclic aromatic hydrocarbon adsorption on selected solid particulate matter fractions |
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