A Matrix Isolation and Computational Study of Molecular Palladium Fluorides: Does PdF6 Exist?

Palladium atoms generated by thermal evaporation and laser ablation were reacted with and trapped in F2/Ar, F2/Ne, and neat F2 matrices. The products were characterized by electronic absorption and infrared spectroscopy, together with relativistic density functional theory calculations as well as co...

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Veröffentlicht in:Inorganic chemistry 2016-02, Vol.55 (3), p.1108-1123
Hauptverfasser: Wilson, Antony V, Nguyen, Timothy, Brosi, Felix, Wang, Xuefeng, Andrews, Lester, Riedel, Sebastian, Bridgeman, Adam J, Young, Nigel A
Format: Artikel
Sprache:eng
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