Synthesis of a magnetoactive compound based on iron(II) sulfate
The effect of synthesis parameters on properties of a magnetoactive compound (MAC) prepared via condensation of iron(II) sulfate in the presence of sodium nitrite is investigated. It is found that nitrite ions almost completely coprecipitate with the solid phase during the formation of a magnetoacti...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2013, Vol.58 (1), p.14-18 |
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| container_title | Russian journal of inorganic chemistry |
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| creator | Khabarov, Yu. G. Babkin, I. M. Gusakov, L. V. Malkov, A. V. |
| description | The effect of synthesis parameters on properties of a magnetoactive compound (MAC) prepared via condensation of iron(II) sulfate in the presence of sodium nitrite is investigated. It is found that nitrite ions almost completely coprecipitate with the solid phase during the formation of a magnetoactive compound and subsequently participate in the redox conversions to yield magnetite. In order to obtain a magnetoactive compound with high relative magnetic susceptibility, condensation from the initial solutions is to be carried out at least 15 min after it is prepared; sodium nitrite consumption is to be at least 0.12 mol/mol FeSO
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| doi_str_mv | 10.1134/S0036023613010099 |
| format | Article |
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.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensing</subject><subject>Conversion</subject><subject>Inorganic Chemistry</subject><subject>Magnetic permeability</subject><subject>Magnetic properties</subject><subject>Nitrites</subject><subject>Sodium nitrite</subject><subject>Sulfates</subject><subject>Synthesis</subject><subject>Synthesis and Properties of Inorganic Compounds</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKs_wFuO9bCa701OIsWPQsFD9bxks5O6ZZvUZFfov3dLvQl6Gpj3eQbmReiakltKubhbEcIVYVxRTighxpygCZWcFnrcnKLJIS4O-Tm6yHlDiBCk1BN0v9qH_gNym3H02OKtXQfoo3V9-wXYxe0uDqHBtc3Q4Bhwm2KYLRY3OA-dtz1cojNvuwxXP3OK3p8e3-YvxfL1eTF_WBaOS9EXHgwzTalko6ln1mprpAQmqDNaOSaBWmV8wwHK2tW1qLXyzHmiQSrQWvEpmh3v7lL8HCD31bbNDrrOBohDrmipGBWsJOX_qOCmFFSUckTpEXUp5pzAV7vUbm3aV5RUh16rX72ODjs6eWTDGlK1iUMK4_N_SN_2jHh_</recordid><startdate>2013</startdate><enddate>2013</enddate><creator>Khabarov, Yu. G.</creator><creator>Babkin, I. M.</creator><creator>Gusakov, L. V.</creator><creator>Malkov, A. V.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>2013</creationdate><title>Synthesis of a magnetoactive compound based on iron(II) sulfate</title><author>Khabarov, Yu. G. ; Babkin, I. M. ; Gusakov, L. V. ; Malkov, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c354t-fe929d765d81f2aa8a955e241c986c25e1a69fd3ee7bcbb4b86f2cf08e56e8863</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensing</topic><topic>Conversion</topic><topic>Inorganic Chemistry</topic><topic>Magnetic permeability</topic><topic>Magnetic properties</topic><topic>Nitrites</topic><topic>Sodium nitrite</topic><topic>Sulfates</topic><topic>Synthesis</topic><topic>Synthesis and Properties of Inorganic Compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khabarov, Yu. G.</creatorcontrib><creatorcontrib>Babkin, I. M.</creatorcontrib><creatorcontrib>Gusakov, L. V.</creatorcontrib><creatorcontrib>Malkov, A. V.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khabarov, Yu. G.</au><au>Babkin, I. M.</au><au>Gusakov, L. V.</au><au>Malkov, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of a magnetoactive compound based on iron(II) sulfate</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2013</date><risdate>2013</risdate><volume>58</volume><issue>1</issue><spage>14</spage><epage>18</epage><pages>14-18</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The effect of synthesis parameters on properties of a magnetoactive compound (MAC) prepared via condensation of iron(II) sulfate in the presence of sodium nitrite is investigated. It is found that nitrite ions almost completely coprecipitate with the solid phase during the formation of a magnetoactive compound and subsequently participate in the redox conversions to yield magnetite. In order to obtain a magnetoactive compound with high relative magnetic susceptibility, condensation from the initial solutions is to be carried out at least 15 min after it is prepared; sodium nitrite consumption is to be at least 0.12 mol/mol FeSO
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| subjects | Chemistry Chemistry and Materials Science Condensing Conversion Inorganic Chemistry Magnetic permeability Magnetic properties Nitrites Sodium nitrite Sulfates Synthesis Synthesis and Properties of Inorganic Compounds |
| title | Synthesis of a magnetoactive compound based on iron(II) sulfate |
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