Excitonic splitting and vibronic coupling in 1,2-diphenoxyethane: conformation-specific effects in the weak coupling limit

Vibrationally and rotationally resolved electronic spectra of 1,2-diphenoxyethane (C6H5-O-CH2-CH2-O-C6H5, DPOE) are reported for the isolated molecule under jet-cooled conditions. The spectra demonstrate that the two excited surfaces are within a few cm(-1) of one another over significant regions of...

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Veröffentlicht in:	The Journal of chemical physics 2013-05, Vol.138 (20), p.204313-204313
Hauptverfasser:	Buchanan, Evan G, Walsh, Patrick S, Plusquellic, David F, Zwier, Timothy S
Format:	Artikel
Sprache:	eng
Schlagworte:	Biphenyl Compounds - chemistry Electronics Emission Ethane - analogs & derivatives Ethane - chemistry Excitation Excitation spectra Joining Molecular Conformation Origins Quantum Theory Rotation Spectra Symmetry Vibration
Online-Zugang:	Volltext
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