Preparation, Crystal Structures, and Behavior in Solution of Cobalt(III) Complexes Containing 2-Cyanoethylphosphines: trans-[Co(Me2dtc)2{P(CH2CH2CN)nPh3−n}]BF4 (n = 1–3; Me2dtc−: N,N-Dimethyldithiocarbamate)

A series of cobalt(III) complexes containing 2-cyanoethylphosphines, [Co(Me2dtc)2{P(CH2CH2CN)nPh3−n}2]BF4 {Me2dtc−: N,N-dimethyldithiocarbamate; n = 1 (1), 2 (2), and 3 (3)} have been prepared, and their molecular structures in the crystals and in solution have been characterized. X-ray analysis rev...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2012-01, Vol.85 (10), p.1160-1166
Hauptverfasser:	Kihara, Keiko, Suzuki, Takayoshi, Kita, Masakazu, Sunatsuki, Yukinari, Kojima, Masaaki, Takagi, Hideo D
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Bonding Crystal structure Crystals Invariants Isomerization Ligands Refluxing
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!