Synthesis of ultrafine refractory oxides zirconia-hafnia-yttria by sol-gel technology
A transparent gel was prepared using a hydrolytically active solution of zirconium, hafnium, and yttrium alkoxoacetylacetonates. This gel served to synthesize ultrafine zirconia-hafnia-yttria complex oxide. The product dispersity was studied as affected by the parameters of xerogel heat treatment. T...
Gespeichert in:
| Veröffentlicht in: | Russian journal of inorganic chemistry 2012-03, Vol.57 (3), p.307-312 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 312 |
|---|---|
| container_issue | 3 |
| container_start_page | 307 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 57 |
| creator | Sevast’yanov, V. G. Simonenko, E. P. Simonenko, N. P. Kuznetsov, N. T. |
| description | A transparent gel was prepared using a hydrolytically active solution of zirconium, hafnium, and yttrium alkoxoacetylacetonates. This gel served to synthesize ultrafine zirconia-hafnia-yttria complex oxide. The product dispersity was studied as affected by the parameters of xerogel heat treatment. The thermal behavior of the xerogel was studied by DSC-TGA. Elemental analysis (laser mass spectrometry) and phase analysis of the synthesized materials were carried out. Average crystallite sizes were calculated by the Scherrer relationship. The particle morphology was studied by TEM. Specific surface areas were determined. Sintering of ultrafine oxide powders was studied at 1000, 1200, and 1400°C. |
| doi_str_mv | 10.1134/S0036023612030278 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1762128930</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1020840088</sourcerecordid><originalsourceid>FETCH-LOGICAL-c354t-4e71c18e2413299b338be75cc3664d8813b957dba04c3d8c46f5cee02872da023</originalsourceid><addsrcrecordid>eNqFkD1PwzAYhC0EEqXwA9g8sgRefyRxRlQBRarEUDpHjvOmdZXGxXYkwq8nUdmQYLrhnjvpjpBbBveMCfmwBhAZcJExDgJ4rs7IjKWCJSpj4pzMJjuZ_EtyFcIeQErI1Yxs1kMXdxhsoK6hfRu9bmyH1GPjtYnOD9R92hoD_bLeuM7qZKebSYYYvdW0GmhwbbLFlkY0u861bjtck4tGtwFvfnRONs9P74tlsnp7eV08rhIjUhkTiTkzTCGXTPCiqIRQFeapMSLLZK0UE1WR5nWlQRpRKyOzJjWIwFXOaz2umZO7U-_Ru48eQywPNhhsW92h60PJ8owzrgoB_6PAQUkApUaUnVDjXQjjE-XR24P2wwiV09vlr7fHDD9lwsh2W_Tl3vW-G8f_EfoGpxKA-Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1020840088</pqid></control><display><type>article</type><title>Synthesis of ultrafine refractory oxides zirconia-hafnia-yttria by sol-gel technology</title><source>Springer Nature - Complete Springer Journals</source><creator>Sevast’yanov, V. G. ; Simonenko, E. P. ; Simonenko, N. P. ; Kuznetsov, N. T.</creator><creatorcontrib>Sevast’yanov, V. G. ; Simonenko, E. P. ; Simonenko, N. P. ; Kuznetsov, N. T.</creatorcontrib><description>A transparent gel was prepared using a hydrolytically active solution of zirconium, hafnium, and yttrium alkoxoacetylacetonates. This gel served to synthesize ultrafine zirconia-hafnia-yttria complex oxide. The product dispersity was studied as affected by the parameters of xerogel heat treatment. The thermal behavior of the xerogel was studied by DSC-TGA. Elemental analysis (laser mass spectrometry) and phase analysis of the synthesized materials were carried out. Average crystallite sizes were calculated by the Scherrer relationship. The particle morphology was studied by TEM. Specific surface areas were determined. Sintering of ultrafine oxide powders was studied at 1000, 1200, and 1400°C.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023612030278</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Crystallites ; Inorganic Chemistry ; Lasers ; Mathematical analysis ; Oxides ; Synthesis and Properties of Inorganic Compounds ; Transmission electron microscopy ; Xerogels ; Yttrium ; Zirconium</subject><ispartof>Russian journal of inorganic chemistry, 2012-03, Vol.57 (3), p.307-312</ispartof><rights>Pleiades Publishing, Ltd. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c354t-4e71c18e2413299b338be75cc3664d8813b957dba04c3d8c46f5cee02872da023</citedby><cites>FETCH-LOGICAL-c354t-4e71c18e2413299b338be75cc3664d8813b957dba04c3d8c46f5cee02872da023</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023612030278$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023612030278$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sevast’yanov, V. G.</creatorcontrib><creatorcontrib>Simonenko, E. P.</creatorcontrib><creatorcontrib>Simonenko, N. P.</creatorcontrib><creatorcontrib>Kuznetsov, N. T.</creatorcontrib><title>Synthesis of ultrafine refractory oxides zirconia-hafnia-yttria by sol-gel technology</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>A transparent gel was prepared using a hydrolytically active solution of zirconium, hafnium, and yttrium alkoxoacetylacetonates. This gel served to synthesize ultrafine zirconia-hafnia-yttria complex oxide. The product dispersity was studied as affected by the parameters of xerogel heat treatment. The thermal behavior of the xerogel was studied by DSC-TGA. Elemental analysis (laser mass spectrometry) and phase analysis of the synthesized materials were carried out. Average crystallite sizes were calculated by the Scherrer relationship. The particle morphology was studied by TEM. Specific surface areas were determined. Sintering of ultrafine oxide powders was studied at 1000, 1200, and 1400°C.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystallites</subject><subject>Inorganic Chemistry</subject><subject>Lasers</subject><subject>Mathematical analysis</subject><subject>Oxides</subject><subject>Synthesis and Properties of Inorganic Compounds</subject><subject>Transmission electron microscopy</subject><subject>Xerogels</subject><subject>Yttrium</subject><subject>Zirconium</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkD1PwzAYhC0EEqXwA9g8sgRefyRxRlQBRarEUDpHjvOmdZXGxXYkwq8nUdmQYLrhnjvpjpBbBveMCfmwBhAZcJExDgJ4rs7IjKWCJSpj4pzMJjuZ_EtyFcIeQErI1Yxs1kMXdxhsoK6hfRu9bmyH1GPjtYnOD9R92hoD_bLeuM7qZKebSYYYvdW0GmhwbbLFlkY0u861bjtck4tGtwFvfnRONs9P74tlsnp7eV08rhIjUhkTiTkzTCGXTPCiqIRQFeapMSLLZK0UE1WR5nWlQRpRKyOzJjWIwFXOaz2umZO7U-_Ru48eQywPNhhsW92h60PJ8owzrgoB_6PAQUkApUaUnVDjXQjjE-XR24P2wwiV09vlr7fHDD9lwsh2W_Tl3vW-G8f_EfoGpxKA-Q</recordid><startdate>20120301</startdate><enddate>20120301</enddate><creator>Sevast’yanov, V. G.</creator><creator>Simonenko, E. P.</creator><creator>Simonenko, N. P.</creator><creator>Kuznetsov, N. T.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QL</scope><scope>7UA</scope><scope>C1K</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20120301</creationdate><title>Synthesis of ultrafine refractory oxides zirconia-hafnia-yttria by sol-gel technology</title><author>Sevast’yanov, V. G. ; Simonenko, E. P. ; Simonenko, N. P. ; Kuznetsov, N. T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c354t-4e71c18e2413299b338be75cc3664d8813b957dba04c3d8c46f5cee02872da023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystallites</topic><topic>Inorganic Chemistry</topic><topic>Lasers</topic><topic>Mathematical analysis</topic><topic>Oxides</topic><topic>Synthesis and Properties of Inorganic Compounds</topic><topic>Transmission electron microscopy</topic><topic>Xerogels</topic><topic>Yttrium</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sevast’yanov, V. G.</creatorcontrib><creatorcontrib>Simonenko, E. P.</creatorcontrib><creatorcontrib>Simonenko, N. P.</creatorcontrib><creatorcontrib>Kuznetsov, N. T.</creatorcontrib><collection>CrossRef</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sevast’yanov, V. G.</au><au>Simonenko, E. P.</au><au>Simonenko, N. P.</au><au>Kuznetsov, N. T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of ultrafine refractory oxides zirconia-hafnia-yttria by sol-gel technology</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2012-03-01</date><risdate>2012</risdate><volume>57</volume><issue>3</issue><spage>307</spage><epage>312</epage><pages>307-312</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>A transparent gel was prepared using a hydrolytically active solution of zirconium, hafnium, and yttrium alkoxoacetylacetonates. This gel served to synthesize ultrafine zirconia-hafnia-yttria complex oxide. The product dispersity was studied as affected by the parameters of xerogel heat treatment. The thermal behavior of the xerogel was studied by DSC-TGA. Elemental analysis (laser mass spectrometry) and phase analysis of the synthesized materials were carried out. Average crystallite sizes were calculated by the Scherrer relationship. The particle morphology was studied by TEM. Specific surface areas were determined. Sintering of ultrafine oxide powders was studied at 1000, 1200, and 1400°C.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0036023612030278</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0236 |
| ispartof | Russian journal of inorganic chemistry, 2012-03, Vol.57 (3), p.307-312 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1762128930 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Crystallites Inorganic Chemistry Lasers Mathematical analysis Oxides Synthesis and Properties of Inorganic Compounds Transmission electron microscopy Xerogels Yttrium Zirconium |
| title | Synthesis of ultrafine refractory oxides zirconia-hafnia-yttria by sol-gel technology |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-14T07%3A34%3A17IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20ultrafine%20refractory%20oxides%20zirconia-hafnia-yttria%20by%20sol-gel%20technology&rft.jtitle=Russian%20journal%20of%20inorganic%20chemistry&rft.au=Sevast%E2%80%99yanov,%20V.%20G.&rft.date=2012-03-01&rft.volume=57&rft.issue=3&rft.spage=307&rft.epage=312&rft.pages=307-312&rft.issn=0036-0236&rft.eissn=1531-8613&rft_id=info:doi/10.1134/S0036023612030278&rft_dat=%3Cproquest_cross%3E1020840088%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1020840088&rft_id=info:pmid/&rfr_iscdi=true |