Valent states of Cu, Ag, and Au atoms in molecules and solids are the same

Ratios between the distances, energies, and force constants of molecules (M₂) and corresponding solids (M) were shown to be approximately equal for elements of Groups 1a and 1b of the Periodic Table. It follows from elementary calculations that the different physical properties of these elements are...

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Veröffentlicht in:Russian journal of inorganic chemistry 2010, Vol.55 (6), p.913-914
Hauptverfasser: Batsanov, S. S, Batsanov, A. S
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description Ratios between the distances, energies, and force constants of molecules (M₂) and corresponding solids (M) were shown to be approximately equal for elements of Groups 1a and 1b of the Periodic Table. It follows from elementary calculations that the different physical properties of these elements are determined by the electronic structure of isolated atoms, and there is no need to introduce the concepts and values of “metal” valences for Cu, Ag, and Au in solid state.
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source Springer Nature - Complete Springer Journals
subjects Atomic structure
Chemistry
Chemistry and Materials Science
Constants
Copper
Gold
Heoretical Inorganic Chemistry
Inorganic Chemistry
Mathematical analysis
Periodic table
Physical properties
Silver
title Valent states of Cu, Ag, and Au atoms in molecules and solids are the same
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