Synthesis and study of hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hexamolybdochromate(III)
Hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hydrogen hexamolybdochromate(III) of compositions [Cd(NH 3 ) 6 ] · H[CoMo 6 O 18 (OH) 6 ] · 6H 2 O ( I ) and [Cd(NH 3 ) 6 ] · H[CrMo 6 O 18 (OH) 6 ] · 6H 2 O ( II ), respectively, were synthesized and studied by mass spectroscopy, thermo-gravi...
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Veröffentlicht in: | Russian journal of inorganic chemistry 2011-04, Vol.56 (4), p.612-615 |
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container_title | Russian journal of inorganic chemistry |
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creator | Oreshkina, A. V. Kaziev, G. Z. Steblevskii, A. V. |
description | Hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hydrogen hexamolybdochromate(III) of compositions [Cd(NH
3
)
6
] · H[CoMo
6
O
18
(OH)
6
] · 6H
2
O (
I
) and [Cd(NH
3
)
6
] · H[CrMo
6
O
18
(OH)
6
] · 6H
2
O (
II
), respectively, were synthesized and studied by mass spectroscopy, thermo-gravimetry, X-ray powder diffraction, and IR spectroscopy. Crystals of
I
and
II
are monoclinic. For
I
:
a
= 10.79 Å,
b
= 3.70 Å,
c
= 11.95 Å, β = 91.05°,
V
= 470.12 Å
3
, ρ
calc
= 2.37 g/cm
3
,
Z
= 2; and for
II
:
a
= 10.80 Å,
b
= 3.68 Å,
c
= 11.97 Å, β = 91.07°,
V
= 468.98 Å
3
, ρ
calc
= 2.36 g/cm
3
,
Z
= 2. |
doi_str_mv | 10.1134/S0036023611040231 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1762120828</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1762120828</sourcerecordid><originalsourceid>FETCH-LOGICAL-c306t-730803a7581980e3e7cab996eb23d8055621febb1a96a81b7fc3667b5847aa353</originalsourceid><addsrcrecordid>eNqFkUtLxDAUhYMoOI7-AHddjotqbtI8upTBR2HAxei6JG067dA0Y9KC_fd2ZhQEQVdn8X3nwOUidA34FoAmd2uMKceEcgCcTAknaAaMQiw50FM02-N4z8_RRQhbjJMECzlD9Xrs-tqEJkSqK6PQD-UYuSqqzYdS1jadKVRpm8FG9Vh6tzHdAVnXjrp0hdOq7VVvFlmW3RwWftLaO_sNL9FZpdpgrr5yjt4eH16Xz_Hq5Slb3q_igmLex4JiiakSTEIqsaFGFEqnKTea0FJixjiBymgNKuVKghZVQTkXmslEKEUZnaPFcXfn3ftgQp_bJhSmbVVn3BByENMCwZLI_1VCQErGqZhUOKqFdyF4U-U731jlxxxwvn9A_usBU4ccO2Fyu43x-dYNvpuO_6P0CYFxhzo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1221885637</pqid></control><display><type>article</type><title>Synthesis and study of hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hexamolybdochromate(III)</title><source>SpringerLink Journals</source><creator>Oreshkina, A. V. ; Kaziev, G. Z. ; Steblevskii, A. V.</creator><creatorcontrib>Oreshkina, A. V. ; Kaziev, G. Z. ; Steblevskii, A. V.</creatorcontrib><description>Hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hydrogen hexamolybdochromate(III) of compositions [Cd(NH
3
)
6
] · H[CoMo
6
O
18
(OH)
6
] · 6H
2
O (
I
) and [Cd(NH
3
)
6
] · H[CrMo
6
O
18
(OH)
6
] · 6H
2
O (
II
), respectively, were synthesized and studied by mass spectroscopy, thermo-gravimetry, X-ray powder diffraction, and IR spectroscopy. Crystals of
I
and
II
are monoclinic. For
I
:
a
= 10.79 Å,
b
= 3.70 Å,
c
= 11.95 Å, β = 91.05°,
V
= 470.12 Å
3
, ρ
calc
= 2.37 g/cm
3
,
Z
= 2; and for
II
:
a
= 10.80 Å,
b
= 3.68 Å,
c
= 11.97 Å, β = 91.07°,
V
= 468.98 Å
3
, ρ
calc
= 2.36 g/cm
3
,
Z
= 2.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023611040231</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Crystals ; Diffraction ; Infrared radiation ; Inorganic Chemistry ; Mass spectroscopy ; Physical Methods of Investigation ; Spectroscopy ; Synthesis ; X-rays</subject><ispartof>Russian journal of inorganic chemistry, 2011-04, Vol.56 (4), p.612-615</ispartof><rights>Pleiades Publishing, Ltd. 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c306t-730803a7581980e3e7cab996eb23d8055621febb1a96a81b7fc3667b5847aa353</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023611040231$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023611040231$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Oreshkina, A. V.</creatorcontrib><creatorcontrib>Kaziev, G. Z.</creatorcontrib><creatorcontrib>Steblevskii, A. V.</creatorcontrib><title>Synthesis and study of hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hexamolybdochromate(III)</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>Hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hydrogen hexamolybdochromate(III) of compositions [Cd(NH
3
)
6
] · H[CoMo
6
O
18
(OH)
6
] · 6H
2
O (
I
) and [Cd(NH
3
)
6
] · H[CrMo
6
O
18
(OH)
6
] · 6H
2
O (
II
), respectively, were synthesized and studied by mass spectroscopy, thermo-gravimetry, X-ray powder diffraction, and IR spectroscopy. Crystals of
I
and
II
are monoclinic. For
I
:
a
= 10.79 Å,
b
= 3.70 Å,
c
= 11.95 Å, β = 91.05°,
V
= 470.12 Å
3
, ρ
calc
= 2.37 g/cm
3
,
Z
= 2; and for
II
:
a
= 10.80 Å,
b
= 3.68 Å,
c
= 11.97 Å, β = 91.07°,
V
= 468.98 Å
3
, ρ
calc
= 2.36 g/cm
3
,
Z
= 2.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystals</subject><subject>Diffraction</subject><subject>Infrared radiation</subject><subject>Inorganic Chemistry</subject><subject>Mass spectroscopy</subject><subject>Physical Methods of Investigation</subject><subject>Spectroscopy</subject><subject>Synthesis</subject><subject>X-rays</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkUtLxDAUhYMoOI7-AHddjotqbtI8upTBR2HAxei6JG067dA0Y9KC_fd2ZhQEQVdn8X3nwOUidA34FoAmd2uMKceEcgCcTAknaAaMQiw50FM02-N4z8_RRQhbjJMECzlD9Xrs-tqEJkSqK6PQD-UYuSqqzYdS1jadKVRpm8FG9Vh6tzHdAVnXjrp0hdOq7VVvFlmW3RwWftLaO_sNL9FZpdpgrr5yjt4eH16Xz_Hq5Slb3q_igmLex4JiiakSTEIqsaFGFEqnKTea0FJixjiBymgNKuVKghZVQTkXmslEKEUZnaPFcXfn3ftgQp_bJhSmbVVn3BByENMCwZLI_1VCQErGqZhUOKqFdyF4U-U731jlxxxwvn9A_usBU4ccO2Fyu43x-dYNvpuO_6P0CYFxhzo</recordid><startdate>20110401</startdate><enddate>20110401</enddate><creator>Oreshkina, A. V.</creator><creator>Kaziev, G. Z.</creator><creator>Steblevskii, A. V.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110401</creationdate><title>Synthesis and study of hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hexamolybdochromate(III)</title><author>Oreshkina, A. V. ; Kaziev, G. Z. ; Steblevskii, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c306t-730803a7581980e3e7cab996eb23d8055621febb1a96a81b7fc3667b5847aa353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystals</topic><topic>Diffraction</topic><topic>Infrared radiation</topic><topic>Inorganic Chemistry</topic><topic>Mass spectroscopy</topic><topic>Physical Methods of Investigation</topic><topic>Spectroscopy</topic><topic>Synthesis</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oreshkina, A. V.</creatorcontrib><creatorcontrib>Kaziev, G. Z.</creatorcontrib><creatorcontrib>Steblevskii, A. V.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oreshkina, A. V.</au><au>Kaziev, G. Z.</au><au>Steblevskii, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and study of hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hexamolybdochromate(III)</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2011-04-01</date><risdate>2011</risdate><volume>56</volume><issue>4</issue><spage>612</spage><epage>615</epage><pages>612-615</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>Hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hydrogen hexamolybdochromate(III) of compositions [Cd(NH
3
)
6
] · H[CoMo
6
O
18
(OH)
6
] · 6H
2
O (
I
) and [Cd(NH
3
)
6
] · H[CrMo
6
O
18
(OH)
6
] · 6H
2
O (
II
), respectively, were synthesized and studied by mass spectroscopy, thermo-gravimetry, X-ray powder diffraction, and IR spectroscopy. Crystals of
I
and
II
are monoclinic. For
I
:
a
= 10.79 Å,
b
= 3.70 Å,
c
= 11.95 Å, β = 91.05°,
V
= 470.12 Å
3
, ρ
calc
= 2.37 g/cm
3
,
Z
= 2; and for
II
:
a
= 10.80 Å,
b
= 3.68 Å,
c
= 11.97 Å, β = 91.07°,
V
= 468.98 Å
3
, ρ
calc
= 2.36 g/cm
3
,
Z
= 2.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0036023611040231</doi><tpages>4</tpages></addata></record> |
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language | eng |
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source | SpringerLink Journals |
subjects | Chemistry Chemistry and Materials Science Crystals Diffraction Infrared radiation Inorganic Chemistry Mass spectroscopy Physical Methods of Investigation Spectroscopy Synthesis X-rays |
title | Synthesis and study of hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hexamolybdochromate(III) |
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