Phase formation in the InPO4-Na3PO4-Li3PO4 ternary system
The 950°C isothermal section of the InPO 4 -Na 3 PO 4 -Li 3 PO 4 ternary system was studied and constructed; one-, two, and three-phase fields are outlined. Five solid-solution regions exist in the system: solid solutions based on the complex phosphate LiNa 5 (PO 4 ) 2 (olympite structure), the indi...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2011-09, Vol.56 (9), p.1453-1457 |
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| container_title | Russian journal of inorganic chemistry |
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| creator | Potapova, A. M. Zimina, G. V. Smirnova, I. N. Spiridonov, F. M. Fedorov, P. P. |
| description | The 950°C isothermal section of the InPO
4
-Na
3
PO
4
-Li
3
PO
4
ternary system was studied and constructed; one-, two, and three-phase fields are outlined. Five solid-solution regions exist in the system: solid solutions based on the complex phosphate LiNa
5
(PO
4
)
2
(olympite structure), the indium ion stabilized high-temperature Na
3
PO
4
phase (Na
3(1 −
x
)
In
x
(PO
4
); space group
Fm
m
), the complex phosphate Na
3
In
2
(PO
4
)
3
, and the α and β phases of the compound Li
3
In
2
(PO
4
)
3
. A narrow region of melt was found in the vicinity of eutectic equilibria. All the phases detected in the system are derivatives of phases existing in the binary subsystems. Isovalent substitution of lithium for sodium in Na
3
In
2
(PO
4
)
3
leads to a significant increase in the region of a NASICON-like solid solution. |
| doi_str_mv | 10.1134/S0036023611090191 |
| format | Article |
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4
-Na
3
PO
4
-Li
3
PO
4
ternary system was studied and constructed; one-, two, and three-phase fields are outlined. Five solid-solution regions exist in the system: solid solutions based on the complex phosphate LiNa
5
(PO
4
)
2
(olympite structure), the indium ion stabilized high-temperature Na
3
PO
4
phase (Na
3(1 −
x
)
In
x
(PO
4
); space group
Fm
m
), the complex phosphate Na
3
In
2
(PO
4
)
3
, and the α and β phases of the compound Li
3
In
2
(PO
4
)
3
. A narrow region of melt was found in the vicinity of eutectic equilibria. All the phases detected in the system are derivatives of phases existing in the binary subsystems. Isovalent substitution of lithium for sodium in Na
3
In
2
(PO
4
)
3
leads to a significant increase in the region of a NASICON-like solid solution.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023611090191</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Derivatives ; Eutectics ; Indium ; Inorganic Chemistry ; Melts ; Phosphates ; Physicohemical Analysis of Inorganic Systems ; Sodium ; Solid solutions ; Ternary systems</subject><ispartof>Russian journal of inorganic chemistry, 2011-09, Vol.56 (9), p.1453-1457</ispartof><rights>Pleiades Publishing, Ltd. 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c236t-3c3955c4d4a59bdbc9d9bba0551f396938a94f7461240c9a565b7b2d3e09f92e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023611090191$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023611090191$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Potapova, A. M.</creatorcontrib><creatorcontrib>Zimina, G. V.</creatorcontrib><creatorcontrib>Smirnova, I. N.</creatorcontrib><creatorcontrib>Spiridonov, F. M.</creatorcontrib><creatorcontrib>Fedorov, P. P.</creatorcontrib><title>Phase formation in the InPO4-Na3PO4-Li3PO4 ternary system</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The 950°C isothermal section of the InPO
4
-Na
3
PO
4
-Li
3
PO
4
ternary system was studied and constructed; one-, two, and three-phase fields are outlined. Five solid-solution regions exist in the system: solid solutions based on the complex phosphate LiNa
5
(PO
4
)
2
(olympite structure), the indium ion stabilized high-temperature Na
3
PO
4
phase (Na
3(1 −
x
)
In
x
(PO
4
); space group
Fm
m
), the complex phosphate Na
3
In
2
(PO
4
)
3
, and the α and β phases of the compound Li
3
In
2
(PO
4
)
3
. A narrow region of melt was found in the vicinity of eutectic equilibria. All the phases detected in the system are derivatives of phases existing in the binary subsystems. Isovalent substitution of lithium for sodium in Na
3
In
2
(PO
4
)
3
leads to a significant increase in the region of a NASICON-like solid solution.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Derivatives</subject><subject>Eutectics</subject><subject>Indium</subject><subject>Inorganic Chemistry</subject><subject>Melts</subject><subject>Phosphates</subject><subject>Physicohemical Analysis of Inorganic Systems</subject><subject>Sodium</subject><subject>Solid solutions</subject><subject>Ternary systems</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkDtPw0AQhE8IJELgB9C5pDHs3sveEkW8pIhEAurT-XwmjvwId06Rf4-t0CFBNcV8M6sdxq4RbhGFvHsDEBq40IhAgIQnbIZKYJprFKdsNtnp5J-zixi3AFJCls8YrTc2-qTqQ2uHuu-SukuGjU9euvVKpq9WTLKsJ0kGHzobDkk8xMG3l-yssk30Vz86Zx-PD--L53S5enpZ3C9TN14bUuEEKeVkKa2ioiwclVQUFpTCSpAmkVuSVSY1cgmOrNKqyApeCg9UEfdizm6OvbvQf-19HExbR-ebxna-30eDmebIQZP8H-Uc8zxDyUcUj6gLfYzBV2YX6nb8ziCYaVHza9Exw4-ZOLLdpw9m2-_HSZr4R-gbA4tz9w</recordid><startdate>20110901</startdate><enddate>20110901</enddate><creator>Potapova, A. M.</creator><creator>Zimina, G. V.</creator><creator>Smirnova, I. N.</creator><creator>Spiridonov, F. M.</creator><creator>Fedorov, P. P.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110901</creationdate><title>Phase formation in the InPO4-Na3PO4-Li3PO4 ternary system</title><author>Potapova, A. M. ; Zimina, G. V. ; Smirnova, I. N. ; Spiridonov, F. M. ; Fedorov, P. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c236t-3c3955c4d4a59bdbc9d9bba0551f396938a94f7461240c9a565b7b2d3e09f92e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Derivatives</topic><topic>Eutectics</topic><topic>Indium</topic><topic>Inorganic Chemistry</topic><topic>Melts</topic><topic>Phosphates</topic><topic>Physicohemical Analysis of Inorganic Systems</topic><topic>Sodium</topic><topic>Solid solutions</topic><topic>Ternary systems</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Potapova, A. M.</creatorcontrib><creatorcontrib>Zimina, G. V.</creatorcontrib><creatorcontrib>Smirnova, I. N.</creatorcontrib><creatorcontrib>Spiridonov, F. M.</creatorcontrib><creatorcontrib>Fedorov, P. P.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Potapova, A. M.</au><au>Zimina, G. V.</au><au>Smirnova, I. N.</au><au>Spiridonov, F. M.</au><au>Fedorov, P. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phase formation in the InPO4-Na3PO4-Li3PO4 ternary system</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2011-09-01</date><risdate>2011</risdate><volume>56</volume><issue>9</issue><spage>1453</spage><epage>1457</epage><pages>1453-1457</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The 950°C isothermal section of the InPO
4
-Na
3
PO
4
-Li
3
PO
4
ternary system was studied and constructed; one-, two, and three-phase fields are outlined. Five solid-solution regions exist in the system: solid solutions based on the complex phosphate LiNa
5
(PO
4
)
2
(olympite structure), the indium ion stabilized high-temperature Na
3
PO
4
phase (Na
3(1 −
x
)
In
x
(PO
4
); space group
Fm
m
), the complex phosphate Na
3
In
2
(PO
4
)
3
, and the α and β phases of the compound Li
3
In
2
(PO
4
)
3
. A narrow region of melt was found in the vicinity of eutectic equilibria. All the phases detected in the system are derivatives of phases existing in the binary subsystems. Isovalent substitution of lithium for sodium in Na
3
In
2
(PO
4
)
3
leads to a significant increase in the region of a NASICON-like solid solution.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0036023611090191</doi><tpages>5</tpages></addata></record> |
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| ispartof | Russian journal of inorganic chemistry, 2011-09, Vol.56 (9), p.1453-1457 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1762120694 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Derivatives Eutectics Indium Inorganic Chemistry Melts Phosphates Physicohemical Analysis of Inorganic Systems Sodium Solid solutions Ternary systems |
| title | Phase formation in the InPO4-Na3PO4-Li3PO4 ternary system |
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