Dodecyl benzene sulfonic acid (DBSA) doped polypyrrole (PPy) films: synthesis, structural, morphological, gas sensing and impedance study
Chemical oxidative polymerization of PPy using APS as an oxidizing agent and mechanical blending were utilized to fabricate PPy-DBSA nanocomposites. DBSA plays a role as both dopant and surfactant in the process of nanocomposite synthesis. In this paper, PPy-DBSA nanocomposites are prepared in m -cr...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2015-11, Vol.26 (11), p.8497-8506 |
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| creator | Mane, A. T. Sartale, S. D. Patil, V. B. |
| description | Chemical oxidative polymerization of PPy using APS as an oxidizing agent and mechanical blending were utilized to fabricate PPy-DBSA nanocomposites. DBSA plays a role as both dopant and surfactant in the process of nanocomposite synthesis. In this paper, PPy-DBSA nanocomposites are prepared in
m
-cresol solvent and deposited on glass substrate with various concentrations of DBSA (10–50 Wt%). It is confirmed using X-ray diffraction analysis and Raman spectroscopy that DBSA actually interacts with the PPy matrix and structural formation of PPy-DBSA nanocomposites. The surface morphology of PPy doped with DBSA (PPy-DBSA) is observed with field emission scanning electron microscopy and atomic force microscopy. The compositional analysis carried by energy dispersive photoelectron spectroscopy and X-ray photoelectron spectroscopy evidenced the successful formation of PPy-DBSA nanocomposite. The 10 % PPy-DBSA nanocomposite sensors are selective and sensitive towards NO
2
gas so gas response measured at low concentration range of 5–100 ppm. The sensor shows high stability, good reproducibility and recovery time for NO
2
gas. The gas sensing mechanism is proposed schematically and is confirmed using impedance analysis. |
| doi_str_mv | 10.1007/s10854-015-3521-2 |
| format | Article |
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m
-cresol solvent and deposited on glass substrate with various concentrations of DBSA (10–50 Wt%). It is confirmed using X-ray diffraction analysis and Raman spectroscopy that DBSA actually interacts with the PPy matrix and structural formation of PPy-DBSA nanocomposites. The surface morphology of PPy doped with DBSA (PPy-DBSA) is observed with field emission scanning electron microscopy and atomic force microscopy. The compositional analysis carried by energy dispersive photoelectron spectroscopy and X-ray photoelectron spectroscopy evidenced the successful formation of PPy-DBSA nanocomposite. The 10 % PPy-DBSA nanocomposite sensors are selective and sensitive towards NO
2
gas so gas response measured at low concentration range of 5–100 ppm. The sensor shows high stability, good reproducibility and recovery time for NO
2
gas. The gas sensing mechanism is proposed schematically and is confirmed using impedance analysis.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-015-3521-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Gas sensors ; Impedance ; Materials Science ; Nanocomposites ; Nitrogen dioxide ; Optical and Electronic Materials ; Photoelectron spectroscopy ; Sensors ; Synthesis ; X-rays</subject><ispartof>Journal of materials science. Materials in electronics, 2015-11, Vol.26 (11), p.8497-8506</ispartof><rights>Springer Science+Business Media New York 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-e0bae8ea246077889482f9b28a0addce20fc2a01f1ad8126a72e1ca9f955f4863</citedby><cites>FETCH-LOGICAL-c349t-e0bae8ea246077889482f9b28a0addce20fc2a01f1ad8126a72e1ca9f955f4863</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-015-3521-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-015-3521-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,41495,42564,51326</link.rule.ids></links><search><creatorcontrib>Mane, A. T.</creatorcontrib><creatorcontrib>Sartale, S. D.</creatorcontrib><creatorcontrib>Patil, V. B.</creatorcontrib><title>Dodecyl benzene sulfonic acid (DBSA) doped polypyrrole (PPy) films: synthesis, structural, morphological, gas sensing and impedance study</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Chemical oxidative polymerization of PPy using APS as an oxidizing agent and mechanical blending were utilized to fabricate PPy-DBSA nanocomposites. DBSA plays a role as both dopant and surfactant in the process of nanocomposite synthesis. In this paper, PPy-DBSA nanocomposites are prepared in
m
-cresol solvent and deposited on glass substrate with various concentrations of DBSA (10–50 Wt%). It is confirmed using X-ray diffraction analysis and Raman spectroscopy that DBSA actually interacts with the PPy matrix and structural formation of PPy-DBSA nanocomposites. The surface morphology of PPy doped with DBSA (PPy-DBSA) is observed with field emission scanning electron microscopy and atomic force microscopy. The compositional analysis carried by energy dispersive photoelectron spectroscopy and X-ray photoelectron spectroscopy evidenced the successful formation of PPy-DBSA nanocomposite. The 10 % PPy-DBSA nanocomposite sensors are selective and sensitive towards NO
2
gas so gas response measured at low concentration range of 5–100 ppm. The sensor shows high stability, good reproducibility and recovery time for NO
2
gas. The gas sensing mechanism is proposed schematically and is confirmed using impedance analysis.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Gas sensors</subject><subject>Impedance</subject><subject>Materials Science</subject><subject>Nanocomposites</subject><subject>Nitrogen dioxide</subject><subject>Optical and Electronic Materials</subject><subject>Photoelectron spectroscopy</subject><subject>Sensors</subject><subject>Synthesis</subject><subject>X-rays</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kU1r3DAQhk1podu0P6A3QS8biJuRbNlyb_noRyCQQFrozWil0cZBllyNfXD_Qf91tWwPpdCTGHjedzQ8RfGWw3sO0J4TByXrErgsKyl4KZ4VGy7bqqyV-P682EAn27KWQrwsXhE9AUBTV2pT_LqOFs3q2Q7DTwzIaPEuhsEwbQbLtteXDxenzMYJLZuiX6c1peiRbe_v11PmBj_SB0ZrmB-RBjpjNKfFzEvS_oyNMU2P0cf9YA7jXhMjDDSEPdPBsmHMpTqYvHNe7Pq6eOG0J3zz5z0pvn36-PXqS3l79_nm6uK2NFXdzSXCTqNCLeoG2lapLh_oup1QGrS1BgU4IzRwx7VVXDS6FciN7lwnpatVU50U22PvlOKPBWnux4EMeq8DxoV63jYCVCdrldF3_6BPcUkh_y5TAqquAQWZ4kfKpEiU0PVTGkad1p5Df5DTH-X0WU5_kNOLnBHHDGU27DH91fzf0G-M5JLo</recordid><startdate>20151101</startdate><enddate>20151101</enddate><creator>Mane, A. 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Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mane, A. T.</au><au>Sartale, S. D.</au><au>Patil, V. B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dodecyl benzene sulfonic acid (DBSA) doped polypyrrole (PPy) films: synthesis, structural, morphological, gas sensing and impedance study</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2015-11-01</date><risdate>2015</risdate><volume>26</volume><issue>11</issue><spage>8497</spage><epage>8506</epage><pages>8497-8506</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Chemical oxidative polymerization of PPy using APS as an oxidizing agent and mechanical blending were utilized to fabricate PPy-DBSA nanocomposites. DBSA plays a role as both dopant and surfactant in the process of nanocomposite synthesis. In this paper, PPy-DBSA nanocomposites are prepared in
m
-cresol solvent and deposited on glass substrate with various concentrations of DBSA (10–50 Wt%). It is confirmed using X-ray diffraction analysis and Raman spectroscopy that DBSA actually interacts with the PPy matrix and structural formation of PPy-DBSA nanocomposites. The surface morphology of PPy doped with DBSA (PPy-DBSA) is observed with field emission scanning electron microscopy and atomic force microscopy. The compositional analysis carried by energy dispersive photoelectron spectroscopy and X-ray photoelectron spectroscopy evidenced the successful formation of PPy-DBSA nanocomposite. The 10 % PPy-DBSA nanocomposite sensors are selective and sensitive towards NO
2
gas so gas response measured at low concentration range of 5–100 ppm. The sensor shows high stability, good reproducibility and recovery time for NO
2
gas. The gas sensing mechanism is proposed schematically and is confirmed using impedance analysis.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-015-3521-2</doi><tpages>10</tpages></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Gas sensors Impedance Materials Science Nanocomposites Nitrogen dioxide Optical and Electronic Materials Photoelectron spectroscopy Sensors Synthesis X-rays |
| title | Dodecyl benzene sulfonic acid (DBSA) doped polypyrrole (PPy) films: synthesis, structural, morphological, gas sensing and impedance study |
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