Tris(trimethylsilyl)silane and visible-light irradiation: a new metal- and additive-free photochemical process for the synthesis of indoles and oxindoles

A combined tris(trimethylsilyl)silane and visible-light-promoted intramolecular reductive cyclization protocol for the synthesis of indoles and oxindoles has been developed. This straightforward and efficient method shows tolerance towards a broad spectrum of functional-groups and enables rapid and...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (82), p.15110-15113
Hauptverfasser:	da Silva, Gustavo Piva, Ali, Akbar, da Silva, Rodrigo César, Jiang, Hao, Paixão, Márcio W
Format:	Artikel
Sprache:	eng
Schlagworte:	Additives Cyclization Free Radicals - chemistry Indoles Indoles - chemical synthesis Irradiation Light Models, Chemical Oxidation-Reduction Photochemical Photochemical Processes Silanes - chemistry Synthesis Tolerances
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