Conjugation in and Optical Properties of 1‑R‑1,2-Diphospholes and 1‑R‑Phospholes

The strength of conjugation between the diene moieties of 1-R-1,2-diphospholes and 1-R-phospholes and exocyclic phenyl groups of these P-heteroles has been quantitatively characterized by the use of Raman activities of the bands of the phenyl substituents. It is shown that conjugation in both types...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2014-12, Vol.118 (51), p.12168-12177
Hauptverfasser:	Katsyuba, Sergey A, Burganov, Timur I, Zvereva, Elena E, Zagidullin, Almaz A, Miluykov, Vasily A, Lönnecke, Peter, Hey-Hawkins, Evamarie, Sinyashin, Oleg G
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectra Bands Centre of gravity Conjugation Dienes Electronic systems Electronics Phenyls
Online-Zugang:	Volltext
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