In-depth structure–selectivity investigations on asymmetric, copper-catalyzed oxidative biaryl coupling in the presence of 5-cis-substituted prolinamines

Thirteen new and 25 known prolinamines carrying an additional 5- cis substituent were evaluated as the chiral ligands in asymmetric copper-catalyzed, oxidative biaryl coupling of 3-hydroxy-2-naphthoates. Comprehensive structure–selectivity investigations revealed that a phenyl group in the 5- cis po...

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Veröffentlicht in:Catalysis science & technology 2015-01, Vol.5 (4), p.2215-2226
Hauptverfasser: Prause, Felix, Arensmeyer, Benjamin, Fröhlich, Benjamin, Breuning, Matthias
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Sprache:eng
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