Cerium Tetrafluoride: Sublimation, Thermolysis, and Atomic Fluorine Migration

Saturated vapor pressure p° and enthalpy of sublimation (Δs H°) of cerium tetrafluoride CeF4 were determined by means of Knudsen effusion mass spectrometry in the range of 750–920 K. It was discovered that sublimation of cerium tetrafluoride from a platinum effusion cell competes with thermal decomp...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2015-08, Vol.119 (31), p.8452-8460
Hauptverfasser:	Chilingarov, N.S, Knot’ko, A.V, Shlyapnikov, I.M, Mazej, Z, Kristl, M, Sidorov, L.N
Format:	Artikel
Sprache:	eng
Schlagworte:	Cerium Depletion Fluorine Migration Platinum Sublimation Surface layer Thermal decomposition
Online-Zugang:	Volltext
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