Catalase-like activity of the polyoxovanadate anion [Mn super(IV)V sub(13)O sub(38)] super(7-): a mechanistic study
The anion [Mn super(IV)V sub(13)O sub(38)] super(7-), 1, in aqueous acetate buffer catalyses the disproportionation of hydrogen peroxide into oxygen and water (TON > 200) by a Mn super(IV/II) cycle, which operates viaquick formation of diperoxovanadate at the surface of 1.
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Veröffentlicht in: | Catalysis science & technology 2012-01, Vol.2 (11), p.2224-2226 |
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creator | Chakrabarty, Sanchita Banerjee, Rupendranath |
description | The anion [Mn super(IV)V sub(13)O sub(38)] super(7-), 1, in aqueous acetate buffer catalyses the disproportionation of hydrogen peroxide into oxygen and water (TON > 200) by a Mn super(IV/II) cycle, which operates viaquick formation of diperoxovanadate at the surface of 1. |
doi_str_mv | 10.1039/c2cy20163a |
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source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Acetates Anions Buffers Catalysis Disproportionation Formations Hydrogen peroxide Surface chemistry |
title | Catalase-like activity of the polyoxovanadate anion [Mn super(IV)V sub(13)O sub(38)] super(7-): a mechanistic study |
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