Examining the Amine Functionalization in Dicarboxylates: Photoelectron Spectroscopy and Theoretical Studies of Aspartate and Glutamate

Aspartate (Asp2–) and glutamate (Glu2–), two doubly charged conjugate bases of the corresponding amino acids, were investigated using low-temperature negative ion photoelectron spectroscopy (NIPES) and ab initio calculations. The effect of amine functionalization was studied by a direct comparison t...

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Veröffentlicht in:	Journal of Physical Chemistry A, 118(28):5256-5262 118(28):5256-5262, 2014-07, Vol.118 (28), p.5256-5262
Hauptverfasser:	Deng, Shihu H. M, Hou, Gao-Lei, Kong, Xiang-Yu, Valiev, Marat, Wang, Xue-Bin
Format:	Artikel
Sprache:	eng
Schlagworte:	Adiabatic flow Amines Amino acids Aspartates Aspartic Acid - chemistry Computer Simulation Dicarboxylic Acids - chemistry Electrons Environmental Molecular Sciences Laboratory Glutamates Glutamic Acid - chemistry Hydrogen Bonding Mathematical analysis Models, Chemical Photoelectron Spectroscopy Propionates - chemistry Stability Succinic Acid - chemistry
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