Role of Tunable Acid Catalysis in Decomposition of α‑Hydroxyalkyl Hydroperoxides and Mechanistic Implications for Tropospheric Chemistry

Electronic structure calculations have been used to investigate possible gas-phase decomposition pathways of α-hydroxyalkyl hydroperoxides (HHPs), an important source of tropospheric hydrogen peroxide and carbonyl compounds. The uncatalyzed as well as water- and acid-catalyzed decomposition of multi...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2014-10, Vol.118 (41), p.9701-9711
Hauptverfasser:	Kumar, Manoj, Busch, Daryle H, Subramaniam, Bala, Thompson, Ward H
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemistry Atmosphere Carboxylic Acids - chemistry Catalysis Catalysts Decomposition Decomposition reactions Formates - chemistry Gases - chemistry Hydrogen - chemistry Hydrogen peroxide Hydrogen Peroxide - chemistry Hydroxyl Radical - chemistry Hydroxyl radicals Ketones - chemistry Kinetics Mathematical analysis Models, Chemical Pathways Peroxides - chemistry Water - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!