Electronic Structure and Chemical Bonding of a Highly Stable and Aromatic Auro–Aluminum Oxide Cluster

We have produced an auro–aluminum oxide cluster, Au2(AlO)2 – , as a possible model for an Au–alumina interface and investigated its electronic and structural properties using photoelectron spectroscopy and density functional theory. An extremely large energy gap (3.44 eV) is observed between the low...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2014-07, Vol.118 (28), p.5204-5211
Hauptverfasser:	Lopez, Gary V, Jian, Tian, Li, Wei-Li, Wang, Lai-Sheng
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Bonding Bonding strength Chemical bonds Clusters Electronics Oxides Stability
Online-Zugang:	Volltext
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