Kinetic Studies of the Reduction of [Co(dmgH)2(py)(Cl)] Revisited: Mechanisms, Products, and Implications

We report on a mechanistic investigation regarding the reduction of [CoIII(dmgH)2­(py)(Cl)] (dmg = dimethylglyoxime) by several complementary techniques. The reduction of [CoIII(dmgH)2­(py)(Cl)] was initiated by either electrochemical, photochemical, or pulse radiolytical techniques, and the corresp...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2014-06, Vol.118 (25), p.4382-4391
Hauptverfasser:	Kahnt, Axel, Peuntinger, Katrin, Dammann, Claudia, Drewello, Thomas, Hermann, Ralf, Naumov, Sergej, Abel, Bernd, Guldi, Dirk M
Format:	Artikel
Sprache:	eng
Schlagworte:	Dimerization Mass spectrometry Photochemical Physical chemistry Rate constants Reduction Spectroscopy
Online-Zugang:	Volltext
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