High Mobility Field Effect Transistors Based on Macroscopically Oriented Regioregular Copolymers
Field-effect transistors fabricated from semiconducting conjugated polymers are candidates for flexible and low-cost electronic applications. Here, we demonstrate that the mobility of high molecular weight (300 kDa) regioregular, poly[4-(4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b′]dithiophen-2-yl)-al...
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| Veröffentlicht in: | Nano letters 2012-12, Vol.12 (12), p.6353-6357 |
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| container_title | Nano letters |
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| creator | Tseng, Hsin-Rong Ying, Lei Hsu, Ben B. Y Perez, Louis A Takacs, Christopher J Bazan, Guillermo C Heeger, Alan J |
| description | Field-effect transistors fabricated from semiconducting conjugated polymers are candidates for flexible and low-cost electronic applications. Here, we demonstrate that the mobility of high molecular weight (300 kDa) regioregular, poly[4-(4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b′]dithiophen-2-yl)-alt-[1,2,5]thiadiazolo[3,4-c]pyridine] can be significantly improved by introducing long-range orientation of the polymer chains. By annealing for short periods, hole mobilities of 6.7 cm2/(V s) have been demonstrated. The transport is anisotropic, with a higher mobility (approximately 6:1) parallel to the polymer backbone than that perpendicular to the polymer backbone. |
| doi_str_mv | 10.1021/nl303612z |
| format | Article |
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The transport is anisotropic, with a higher mobility (approximately 6:1) parallel to the polymer backbone than that perpendicular to the polymer backbone.</description><subject>Annealing</subject><subject>Applied sciences</subject><subject>Backbone</subject><subject>Copolymers</subject><subject>Electronics</subject><subject>Exact sciences and technology</subject><subject>Field effect transistors</subject><subject>Molecular weight</subject><subject>Polymers</subject><subject>Semiconductor devices</subject><subject>Semiconductor electronics. Microelectronics. Optoelectronics. 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| source | ACS Publications |
| subjects | Annealing Applied sciences Backbone Copolymers Electronics Exact sciences and technology Field effect transistors Molecular weight Polymers Semiconductor devices Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices Transistors Transport |
| title | High Mobility Field Effect Transistors Based on Macroscopically Oriented Regioregular Copolymers |
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