Interacting Carbon Nitride and Titanium Carbide Nanosheets for High-Performance Oxygen Evolution
Free‐standing flexible films, constructed from two‐dimensional graphitic carbon nitride and titanium carbide (with MXene phase) nanosheets, display outstanding activity and stability in catalyzing the oxygen‐evolution reaction in alkaline aqueous system, which originates from the Ti–Nx motifs acting...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2016-01, Vol.55 (3), p.1138-1142 |
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| creator | Ma, Tian Yi Cao, Jian Liang Jaroniec, Mietek Qiao, Shi Zhang |
| description | Free‐standing flexible films, constructed from two‐dimensional graphitic carbon nitride and titanium carbide (with MXene phase) nanosheets, display outstanding activity and stability in catalyzing the oxygen‐evolution reaction in alkaline aqueous system, which originates from the Ti–Nx motifs acting as electroactive sites, and the hierarchically porous structure with highly hydrophilic surface. With this excellent electrocatalytic ability, comparable to that of the state‐of‐the‐art precious‐/transition‐metal catalysts and superior to that of most free‐standing films reported to date, they are directly used as efficient cathodes in rechargeable zinc–air batteries. Our findings reveal that the rational interaction between different two‐dimensional materials can remarkably promote the oxygen electrochemistry, thus boosting the entire clean energy system.
A fascinating catalyst structure: Free‐standing flexible films composed of strongly coupled carbon nitride and titanium carbide nanosheets through Ti–Nx interactions (see picture) exhibited outstanding electrocatalytic activity and stability towards the oxygen‐evolution reaction (OER). The films could be directly used as efficient cathodes in rechargeable Zn–air batteries. |
| doi_str_mv | 10.1002/anie.201509758 |
| format | Article |
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A fascinating catalyst structure: Free‐standing flexible films composed of strongly coupled carbon nitride and titanium carbide nanosheets through Ti–Nx interactions (see picture) exhibited outstanding electrocatalytic activity and stability towards the oxygen‐evolution reaction (OER). The films could be directly used as efficient cathodes in rechargeable Zn–air batteries.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201509758</identifier><identifier>PMID: 26629779</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Batteries ; Carbon nitride ; Catalysts ; Cathodes ; Clean energy ; electrocatalysis ; Electrochemistry ; Evolution ; Metal air batteries ; Nanosheets ; Oxygen ; oxygen-evolution reaction ; porous materials ; Rechargeable batteries ; Titanium ; Titanium carbide ; Zinc ; Zinc-oxygen batteries</subject><ispartof>Angewandte Chemie International Edition, 2016-01, Vol.55 (3), p.1138-1142</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5428-6971a4f676aaa4ad96a54bac1f2df83f20b08a96ce8f4f5b3d7ea7c4592511553</citedby><cites>FETCH-LOGICAL-c5428-6971a4f676aaa4ad96a54bac1f2df83f20b08a96ce8f4f5b3d7ea7c4592511553</cites><orcidid>0000-0002-1042-8700 ; 0000-0002-1178-5611 ; 0000-0003-3570-5185 ; 0000-0002-4568-8422</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201509758$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201509758$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26629779$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ma, Tian Yi</creatorcontrib><creatorcontrib>Cao, Jian Liang</creatorcontrib><creatorcontrib>Jaroniec, Mietek</creatorcontrib><creatorcontrib>Qiao, Shi Zhang</creatorcontrib><title>Interacting Carbon Nitride and Titanium Carbide Nanosheets for High-Performance Oxygen Evolution</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Free‐standing flexible films, constructed from two‐dimensional graphitic carbon nitride and titanium carbide (with MXene phase) nanosheets, display outstanding activity and stability in catalyzing the oxygen‐evolution reaction in alkaline aqueous system, which originates from the Ti–Nx motifs acting as electroactive sites, and the hierarchically porous structure with highly hydrophilic surface. With this excellent electrocatalytic ability, comparable to that of the state‐of‐the‐art precious‐/transition‐metal catalysts and superior to that of most free‐standing films reported to date, they are directly used as efficient cathodes in rechargeable zinc–air batteries. Our findings reveal that the rational interaction between different two‐dimensional materials can remarkably promote the oxygen electrochemistry, thus boosting the entire clean energy system.
A fascinating catalyst structure: Free‐standing flexible films composed of strongly coupled carbon nitride and titanium carbide nanosheets through Ti–Nx interactions (see picture) exhibited outstanding electrocatalytic activity and stability towards the oxygen‐evolution reaction (OER). The films could be directly used as efficient cathodes in rechargeable Zn–air batteries.</description><subject>Batteries</subject><subject>Carbon nitride</subject><subject>Catalysts</subject><subject>Cathodes</subject><subject>Clean energy</subject><subject>electrocatalysis</subject><subject>Electrochemistry</subject><subject>Evolution</subject><subject>Metal air batteries</subject><subject>Nanosheets</subject><subject>Oxygen</subject><subject>oxygen-evolution reaction</subject><subject>porous materials</subject><subject>Rechargeable batteries</subject><subject>Titanium</subject><subject>Titanium carbide</subject><subject>Zinc</subject><subject>Zinc-oxygen batteries</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkc1v1DAQxSMEoqVw5YgiceGSxR_x17FabdsVVcqhiKOZJPbWJbGLnUD3v6-3W1aIA5w8sn_vzXheUbzFaIERIh_BO7MgCDOkBJPPimPMCK6oEPR5rmtKKyEZPipepXSbeSkRf1kcEc6JEkIdF9_WfjIRusn5TbmE2AZfNm6Krjcl-L68dlNuMY-Pb7vLBnxIN8ZMqbQhlhduc1N9NjHXI_jOlFf3243x5epnGObJBf-6eGFhSObN03lSfDlbXS8vqsur8_Xy9LLqWE1kxZXAUFsuOADU0CsOrG6hw5b0VlJLUIskKN4ZaWvLWtoLA6KrmSIMY8boSfFh73sXw4_ZpEmPLnVmGMCbMCeNBUdS5V-rjL7_C70Nc_R5Oo0V4nl5Mu_vX5RgTHJJya7tYk91MaQUjdV30Y0QtxojvUtI7xLSh4Sy4N2T7dyOpj_gvyPJgNoDv9xgtv-x06fNevWnebXXujSZ-4MW4nfNBRVMf23O9aczgmiDlprTBw28qzQ</recordid><startdate>20160118</startdate><enddate>20160118</enddate><creator>Ma, Tian Yi</creator><creator>Cao, Jian Liang</creator><creator>Jaroniec, Mietek</creator><creator>Qiao, Shi Zhang</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-1042-8700</orcidid><orcidid>https://orcid.org/0000-0002-1178-5611</orcidid><orcidid>https://orcid.org/0000-0003-3570-5185</orcidid><orcidid>https://orcid.org/0000-0002-4568-8422</orcidid></search><sort><creationdate>20160118</creationdate><title>Interacting Carbon Nitride and Titanium Carbide Nanosheets for High-Performance Oxygen Evolution</title><author>Ma, Tian Yi ; Cao, Jian Liang ; Jaroniec, Mietek ; Qiao, Shi Zhang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5428-6971a4f676aaa4ad96a54bac1f2df83f20b08a96ce8f4f5b3d7ea7c4592511553</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Batteries</topic><topic>Carbon nitride</topic><topic>Catalysts</topic><topic>Cathodes</topic><topic>Clean energy</topic><topic>electrocatalysis</topic><topic>Electrochemistry</topic><topic>Evolution</topic><topic>Metal air batteries</topic><topic>Nanosheets</topic><topic>Oxygen</topic><topic>oxygen-evolution reaction</topic><topic>porous materials</topic><topic>Rechargeable batteries</topic><topic>Titanium</topic><topic>Titanium carbide</topic><topic>Zinc</topic><topic>Zinc-oxygen batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Tian Yi</creatorcontrib><creatorcontrib>Cao, Jian Liang</creatorcontrib><creatorcontrib>Jaroniec, Mietek</creatorcontrib><creatorcontrib>Qiao, Shi Zhang</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Tian Yi</au><au>Cao, Jian Liang</au><au>Jaroniec, Mietek</au><au>Qiao, Shi Zhang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interacting Carbon Nitride and Titanium Carbide Nanosheets for High-Performance Oxygen Evolution</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. 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Our findings reveal that the rational interaction between different two‐dimensional materials can remarkably promote the oxygen electrochemistry, thus boosting the entire clean energy system.
A fascinating catalyst structure: Free‐standing flexible films composed of strongly coupled carbon nitride and titanium carbide nanosheets through Ti–Nx interactions (see picture) exhibited outstanding electrocatalytic activity and stability towards the oxygen‐evolution reaction (OER). The films could be directly used as efficient cathodes in rechargeable Zn–air batteries.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>26629779</pmid><doi>10.1002/anie.201509758</doi><tpages>5</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-1042-8700</orcidid><orcidid>https://orcid.org/0000-0002-1178-5611</orcidid><orcidid>https://orcid.org/0000-0003-3570-5185</orcidid><orcidid>https://orcid.org/0000-0002-4568-8422</orcidid></addata></record> |
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| subjects | Batteries Carbon nitride Catalysts Cathodes Clean energy electrocatalysis Electrochemistry Evolution Metal air batteries Nanosheets Oxygen oxygen-evolution reaction porous materials Rechargeable batteries Titanium Titanium carbide Zinc Zinc-oxygen batteries |
| title | Interacting Carbon Nitride and Titanium Carbide Nanosheets for High-Performance Oxygen Evolution |
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